450 °C Isothermal Section of the Zn-Fe-Cu Ternary System

The 450 °C isothermal section of the Zn-Fe-Cu ternary system was experimentally determined by Scanning Electron Microscopy (SEM) coupled with Energy Dispersive X-ray Spectrometer (EDS)/Wave Dispersive X-ray Spectrometer (WDS), and X-ray Diffractometer (XRD). Eight three-phase regions exist in the 450 °C isothermal section of the Zn-Fe-Cu ternary system. No new ternary compound was found in the system. The δ_Fe phase (FeZn₁₀) can be in equilibrium with all phases except the α-Fe, (Cu) and β′ (CuZn) phase. Experimental results indicated that the solubility of Cu in the Γ (Fe₃Zn₁₀) and the δ_Fe phase reaches as high as 17.9 and 15.2 at.%, respectively.     

Electrodeposition-based construction of random arrays of Pt nanoparticles on glassy carbon electrode (GCE) towards methanol oxidation application

An eletrodeposition of random arrays of Pt nanoparticles, supported on glassy carbon electrode (GCE), is reported. It has been shown that such arrays exhibited good catalytic activity with respect to methanol oxidation in an acidic medium and longer deposition time produced more Pt nanoparticles on GCE leading to larger effective catalytic area and higher catalytic current. It was found that the process of methanol oxidation was controlled by the diffusion of methanol and the Pt nanoparticles formed stable film on GCE surface and also exhibited stable catalytic performance towards methanol oxidation.     

Novel nanotextured microelectrodes: Electrodeposition-based fabrication and their application to ultrasensitive nucleic acid detection

Microelectrodes have become well-established tools in a wide range of analytical studies and applications because they exhibit many cardinal advantages bestowed by their micrometer-sized dimensions over conventional large-surface-area electrodes. Nanostructures display quite unique properties different greatly from those of the bulk materials and are widely used in the field of electroanalysis. Nanotextured microelectrodes (NTMEs) are expected to combine attributes of nanostructures with microelectrodes. In this paper, electrodeposition technique, in combination with well-established microfabrication techniques, is used for the first time to the controllable fabrication of novel Pd, Pt, and Au NTMEs. The use of such NTMEs as a novel platform for ultrasensitive nucleic acid detection is also demonstrated.     

4000t／a氯蜡—70技术改造工艺选择

概述了氯蜡－７０产品的市场预测、生产工艺选择,着重从生产技术,环境保护,技术经济角度对沈阳化工股份有限公司４０００ｔ／ａ水相法氯蜡－７０技术改造工程作了详细论证。     

高温电解水蒸气制氢用SOEC微晶玻璃密封材料制备

与高温气冷核反应堆耦合下的高温固体氧化物燃料电解池(SOEC)电解水蒸汽制氢是目前已知效率最高最先进的制氢技术之一,是有效利用核能的一种途径,因此是当前国际能源环保领域的热点课题和首选方案.此方法需要在高温下长期运行,且在系统开启和检修等运行环节中必然会遇到热循环和热疲劳,因此需要高性能的密封材料.选择Ba-Ca-Si-Al-B-La-O体系微晶玻璃作为研究对象,研究其制备和热处理析晶工艺.研究发现通过两步析晶法,获得了整体均匀析晶的微晶玻璃密封材料,在工作温度下热膨胀系数可达到11.5×10~(-6) K~(-1),可与电解质、连接体等材料形成热匹配.该材料的软化温度约为763 ℃,在SOEC堆的工作温度下可实现密封.     

The Zn-rich corner of the 450 °C isothermal section of the Zn–Bi–Fe–Ni quaternary system

Following up on recent studies of the isothermal section of the Zn–Fe–Ni, Zn–Fe–Bi and Zn–Bi–Ni ternary systems at 450 °C, the Zn-rich corner of the 450 °C isothermal section of the Zn–Bi–Fe–Ni quaternary system with the Zn being fixed at 93 at.% was determined experimentally using the equilibrated alloys approach. The specimens were investigated by means of scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD). It was found there exist 4 two-phase regions, 5 three-phase regions and 2 four-phase regions. Two liquid L (Zn) and L (Bi) can coexist with T, ζ and δ-Ni in this isothermal section, no new phase was found in this study.     

欠驱动柔性机器人的动力学建模与耦合特性

运用有限元法,建立具有柔性杆的欠驱动机器人的动力学一般模型。以此模型为基础,分析系统的主动与被动关节的加速度耦合和被动关节与驱动力矩的动力学耦合效应,并针对欠驱动柔性机器人,提出柔性杆弹性变形分别与主动关节、被动关节动力学耦合的新指标。将欠驱动柔性机器人的被动关节加速度耦合和力矩耦合仿真结果与刚性系统相比较,在某个驱动器位置,柔性系统得到较大的耦合值,说明此时柔性系统更加有利于能量的传递,体现了杆件的弹性变形对系统动力学特性的影响。同时,数值仿真还表明这些动力学耦合指标对欠驱动机器人的结构设计、位形设计、驱动装置位置及系统控制都具有重要意义。     

大尺度三维视觉测量中的离焦模糊图像恢复

为了实现大型设备的几何量测量,需要对多幅立体图像进行拼接。由于镜头的焦距固定,当观测不同距离的场景时往往使图像产生离焦模糊,从而丧失图像细节,降低了拼接精度。提出了一种基于维纳滤波的离焦模糊图像恢复算法。利用模糊图像频谱上的暗环半径估计退化函数的参数,并通过对原始图像的边界进行处理消除了图像边界条件的不连续性。实验结果显示该算法可以有效地降低图像恢复过程中产生的振铃现象,对离焦模糊图像的恢复质量良好。     

固溶处理对微弧等离子增材制造Inconel 625构件力学性能的影响

为研究固溶处理对微弧等离子增材制造Inconel 625构件力学性能的影响,本文采用在950℃、1050℃、1150℃和1250℃条件下对增材制造INCONEL 625合金薄壁构件试样进行了固溶处理。研究表明,随着固溶温度升高晶粒回溶程度不断增大,生长取向变得杂乱;位错密度逐渐降低且分布位置集中在晶界区域;析出物逐渐减小,出现回溶过程。随温度升高,结构内部的固溶强化使抗拉强度得到提升,但应变强化减弱导致屈服强度降低,同时Laves相对位错滑移的阻碍作用减弱使薄壁构件的延伸率得到提升。经测试,屈服强度、抗拉强度及延伸率在1150℃固溶处理后达到最优,固溶处理后薄壁结构抗腐蚀能力得到明显提升。这为微弧等离子增材制造INCONEL 625薄壁构件力学性能优化提供了支撑。     

透射式光热透镜技术的原理和应用

透射式光热透镜技术是光热偏转技术的新发展。介绍了透射式光热透镜技术测量光学玻璃、光学薄膜弱吸收的基本原理和装置。用Matlab对透射式光热透射技术的原理进行了模拟,对K9玻璃以及在K9玻璃上镀制的薄膜样品的弱吸收进行了测试。结果表明,透射式光热透镜技术是一种高灵敏度的热波检测技术,其灵敏度最高可以达到0.1ppm,而且可以对膜层中的缺陷进行检测。