Change in the basic thermodynamic characteristics of polymeric sorbents in interaction with inert gases in a wide range of pressures and temperatures

A model for calculating of the change in the basic thermodynamic characteristics of a sorbent (internal energy and entropy) with the phenomenological-thermodynamics method has been developed. Calculations for the systems polycarbonate-carbon dioxide and polymethylmethacrylate-carbon dioxide have been carried out. __________ Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 80, No. 3, pp. 198–200, May–June, 2007.     

Hydrocarbon impurities in SiF<Subscript>4</Subscript> and SiH<Subscript>4</Subscript> prepared from it

Using gas chromatography and high-resolution Fourier-transform IR spectroscopy, we have determined the concentrations of C₁–C₄ hydrocarbon impurities in isotopically unmodified silicon tetrafluoride before and after fine purification and in ²⁸Si-enriched SiF₄. The concentrations of C₁–C₄ hydrocarbon impurities in silicon tetrafluoride for SiH₄ synthesis have been shown to correlate with those in the synthesized silane.     

Methane conversion in a plasma created by a periodic-pulsed electron beam and non-self-sustained discharge

The process of methane conversion in a mixture modeling the natural gas under the action of a periodic nanosecond pulsed electron beam and an electron-beam-induced non-self-sustained discharge has been numerically simulated and studied in experiment. The possibility of methane conversion under the action of electric pulses without significant heating of the processed gas mixture is demonstrated for the first time. The main conversion products in experiment were hydrogen, ethylene, and acetylene.     

Formation and retention of local melted films in AZ91 friction stir spot welds

The formation of local melted films during friction stir spot welding of as-cast AZ91D and thixomolded AZ91 material is investigated. The average temperatures close to the tip of the rotating pin vary from 438 to 454 °C during the dwell period in friction stir spot welding. These measured temperature values are higher than the melting temperature of α-Mg + Mg₁₇Al₁₂ eutectic (437 °C). It is suggested that the temperature in the stir zone during the dwell period is determined by the relative proportions of α-Mg and (α-Mg + Mg₁₇Al₁₂) eutectic material, which are incorporated during friction stir spot welding. Based on the stir zone temperature measurements and a detailed examination of material located at the root of the pin thread it is suggested that material is moved downwards via the pin thread and into the stir zone during the dwell period in friction stir spot welding. Evidence of local melted film formation is observed in the stir zone of AZ91 spot welds. It is suggested that melted films are retained since their dissolution rate is much slower in the high temperature stir zone than it is when melted films is formed in the stir zone during Al 7075-T6 friction stir spot welding. The spontaneous melting temperature, solute diffusion rate and the thermodynamic driving force for droplet dissolution are much higher during Al 7075-T6 friction stir spot welding.     

Air flow through a non-airconditioned bus with open windows

Open window buses without air-conditioning are a major mode of urban and inter-city transport in most countries. High occupancy combined with hot and humid conditions makes travel in these buses quite uncomfortable. In this study air flow through a bus has been studied that could be the basis for low cost and eco-friendly methods of increasing passenger comfort and possibly reduce drag. The aerodynamics of such a road vehicle has not been studied as previous investigations have been confined to vehicles with closed windows that present a smooth exterior to air flow. Using a 1:25 scaled Perspex model of an urban bus in Delhi, flow visualization was performed in a water channel. The Reynolds numbers were one-tenth of a real bus moving at 10 m/s. Smoke and tuft visualizations were also performed on an urban bus at 40 km/h. Numerical simulations were performed at the actual Reynolds number. Even though there were Reynolds number differences, the broad features were similar. Air enters the bus from the rear windows, moves to the front (relative to the bus) and exits from the front windows. Inside air velocity relative to the bus is about one-tenth of the free-stream velocity. The flow is highly three-dimensional and unsteady.     

Unsteady heat transfer in a system of three coaxial finite cylinders

An integral transformation with the aid of which a solution of the problem of unsteady-state heat transfer in a system of three coaxial finite cylinders with different boundary conditions on their surfaces depending on space and time is presented. Each of the cylinders evolves heat of a certain intensity, depending on time and coordinates. A numerical solution of one variant of the boundary conditions is given and illustrated by figures. The method of transforming the solution of the problem with other boundary conditions is shown. __________ Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 80, No. 1, pp. 140–148, January–February, 2007.     

Problem on estimation of the content of <Superscript>131</Superscript>I in milk in the “iodine” period of the Chernobyl accident

Measurements of the beta-activity of milk, serving as the main source of information on the radioactive contamination of the environment by the iodine isotope ¹³¹I, carried out on a DP-100 radiometer in the early post-Chernobyl period (1986) in Belarus, have been mathematically simulated. The results obtained allow the conclusion that the indicated measurements should be analyzed again with consideration for all of the nuclides present in milk. __________ Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 80, No. 6, pp. 102–108, November–December, 2007.     

Realization of high pressures and temperatures in the gas phase of a bubble liquid flowing through a nozzle

A steady flow of a bubble gas-liquid mixture in a nozzle having a circular cross section has been investigated. The possibility of realization of superhigh temperatures and pressures in the gas phase of the mixture in the region near the smallest cross section of the nozzle has been analyzed. The influence of the initial radius of the flow and the volume content of bubbles, determining the volumetric rate of flow of the liquid supplied to the nozzle, on the pattern of the flow has been considered. __________ Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 80, No. 6, pp. 134–137, November–December, 2007.     

Measurement of viscoplastic properties of a liquid in experiments with a torsion viscosimeter

The results of a numerical solution of the problem of vibrations of a torsion viscosimeter filled with an incompressible viscoplastic liquid are presented. It has been shown that in the vicinity of the rotation axis there appears a dead zone, whose boundary changes in the process of vibrations. The influence of plastic properties of the liquid on the characteristics of viscosimeter vibrations has been determined. A method for identifying viscoplastic properties by the observed parameters of vibrations is proposed. __________ Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 80, No. 1, pp. 124–127, January–February, 2007.