Investigation of fibres based on rigid-chain polyamides by the wide-line nmr and ultrasonic acoustics

Conclusions -- A dependence of the second moment of the NMR line on the angle between the fibre axis and the magnetic field has been given; the structural coefficient C ₀, C ₂, and C ₄ have been calculated for fibres based on poly-p-phenyleneterephthalamide and poly-p-benzamide at temperatures of –196 and +20°C and for Kevlar-49, from –196 to +400°C.-- The intramolecular structural coefficients C ₀ ^im, C ₂ ^im, and C ₄ ^im have been calculated theoretically, and the orientation parameters and and the acoustic orientation factor f have been obtained, values for which indicate a high degree of orientation of the macromolecules in fibres.-- The smaller values of the second moment of the NMR line for PABI as compared with fibres based on PPTA in the temperature region 250–380°C indicate a more mobile structure for the PABI.-- In the range from –196 to +20°C thermal action leads to a more important change in the coefficient C ₀ for Kevlar-29 and Kevlar-49 as compared with PABI; this is apparently connected with thermal expansion in planes having a predominant concentration of van der Waals bonds for Kevlar-29 and Kevlar-49.Translated from Khimicheskie Volokna, No. 4, pp. 23–26, July–August, 1990.     

Effect of lecithin on jejunal absorption of micellar lipids in man and on their monomer activity in vitro

The effect of lecithin on jejunal absorption of fatty acids and octadecenoylglycerol was studied in healthy volunteers with a jejunal perfusion system which excluded pancreatic and biliary secretions from the test segment. Lecithin significantly reduced the absorption of oleic acid (P<0.05) and octadecenoylglycerol (P<0.01), while it had no effect on the absorption of ricinoleic acid. In vitro, lecithin reduced monomer activities of all three lipids; the changes were greater for oleic acid and octadecenoylglycerol than for ricinoleic acid (P<0.02). From these data it is concluded that lecithin reduces monomer activity of fatty acids in mixed micellar solutions and that it can thereby reduce the absorption rates of micellar lipids. Intact lecithin is not absorbed under these conditions. Maldigestion of lecithin in pancreatic insufficiency may, therefore, aggravate the steatorrhea observed in this condition.     

Graft copolymerization of hydrophilic monomers onto irradiated polypropylene fibers

A method of graft copolymerization of hydrophilic monomers, such as 1-vinyl-2-pyrrolidone, acrylonitrile, acrylic acid, and acrylamide, onto irradiated polypropylene fibers has been studied. γ ray as well as electron beam were employed for the irradiation processes. Graft-copolymerization kinetics and the properties of grafted fibers have been investigated. Moisture regain, dyes absorption, and melting point of the grafted fibers were found to increase with the increasing of the degree of grafting. Polypropylene for 1-vinyl-2-pyrrolidone grafted fibers showed excellent dye absorption for almost all kinds of dyes such as direct, basic, acid, reactive, disper, and naphthol dyes. However, for polypropylene acrylic acid grafted fibers, the colorfastness to washing was found to be unsatisfactory. The colorfastness to washing for polypropylene 1-vinyl-2-pyrrolidone grafted fibers was found to be fairly good for certain types of dyes such as vat and naphthol dyes.     

Friction factors in pulsed turbulent flow

An apparatus for investigating pulsed turbulent liquid flow in a 2 in. diameter, 80 ft. pipeline is described. The pulsation unit was powered by compressed air with a consumption of up to 2.7 std. cu.ft./min. at 35 lb/in² gauge. The pressure drop for water flowing at mean velocities of 7.66 to 12.28 ft./sec. has been measured, both for steady flow and for pulsed flow, at frequencies between 0.48 and 0.82 Hz. The experimentally measured pressure versus time curves for pulsed flow can be matched fairly closely by a solution of Euler's equation employing the friction factors measured under steady flow conditions.     

Investigation of the mechanical properties of low-alloy steels

Technical University, Koice, Czechoslovakia. Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 2, pp. 21–24, February, 1991.     

Structural condition of martensite in the surface layer of cold rolling rolls

Conclusions The martensitic base of the surface hardened layer is inhomogeneous in phase composition. Despite complicating concepts post-hardening tempering does not cause homogenization of the martensitic phase. Decomposition of the martensite has a heterogeneous character. In the hardened layer and the transition zone together with the low-carbide constituent there is formed a high-carbon one. The presence of high-carbon -martensite may not inpoint of concepts on homogeneous martensite, the degree of tetragonality of which is close to unity, it is difficult to explain the phenomenon of high hardness of rolling mill rolls. Undoubtedly the high-carbon constituent is one of the factors causing an increase in hardness in tempering of type 9KhMF steel. The two martensites manifest themselves differently in rolling. Concepts of the heterogeneous nature of maratensite may be used for improving the service conditions of rolling rolls.Kramatorsk Industrial Institute. Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 2, pp. 10–12, February, 1991.     

Infrared reflectance and transmission spectra of semiconducting non-stoichiometric CdGe x As2

The infrared reflectance and transmission spectra of amorphous CdGe _x As₂ were investigated to study the amorphous structure with varying Ge content. The mid-infrared optical absorption edges of amorphous CdGe _x As₂ with 0<x<1.2, were observed in the range 1.6–1.7 m, indicating a structural similarity in short-range order throughout. Comparing the reflectance and transmission spectra of amorphous and devitrified crystalline phases established that the structures of amorphous CdGe _x As₂ transformed from the CdAs₂ basic structure to the chalcopyrite (CdGeAs₂) structure, as one progressed fromx=0 tox=1.2. The infrared spectra were interpreted interactively with radial distribution function, magnetic susceptibility, density measurements, and crystallization studies. The crystallization behaviour of amorphous CdGe _x As₂ that was heat treated at different temperatures was investigated using far-infrared transmission spectra.