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83.
Ming-Yue Zhang Yu Song Duo Yang Zengming Qin Di Guo Li-Jun Bian Xiao-Guang Sang Xiaoqi Sun Xiao-Xia Liu 《Advanced functional materials》2021,31(1):2006203
Conducting polymers (CPs) have been widely studied for electrochemical energy storage. However, the dopants in CPs are often electrochemically inactive, introducing “dead-weight” to the materials. Moreover, commercial-level electrode materials with high mass loadings (e.g., >10 mg cm−2) often encounter the problems of inferior electrical and ionic conductivity. Here, a redox-active poly-counterion doping concept is proposed to improve the electrochemical performance of CPs with ultra-high mass loadings. As a study prototype, heptamolybdate anion (Mo7O246−) doped polypyrrole (PPy) is synthesized by electro-polymerization. A 2 mm thick PPy electrode with mass loading of ≈192 mg cm−2 reaches a record-high areal capacitance of ≈47 F cm−2, competitive gravimetric capacitance of 235 F g−1, and volumetric capacitance of 235 F cm−3. With poly-counterion doping, the dopants also undergo redox reactions during charge/discharge processes, providing additional capacitance to the electrode. The interaction between polymer chains and the poly-counterions enhances the electrical conductivity of CPs. Besides, the poly-counterions with large steric hindrance could act as structural pillars and endow CPs with open structures for facile ion transport. The concept proposed in this work enriches the electrochemistry of CPs and promotes their practical applications. 相似文献
84.
Gunhyu Bae Yoo Sang Jeon Min Jun Ko Yuri Kim Seong-Beom Han Ramar Thangam Wonsik Kim Hee Joon Jung Sungkyu Lee Hyojun Choi Sunhong Min Hyunsik Hong Sangwoo Park Seong Yeol Kim Kapil D. Patel Na Li Jeong Eun Shin Bum Chul Park Hyeon Su Park Jun Hwan Moon Yu Jin Kim Uday Kumar Sukumar Jae-Jun Song Soo Young Kim Seung-Ho Yu Yun Chan Kang Steve Park Seung Min Han Dong-Hwee Kim Ki-Bum Lee Qiang Wei Liming Bian Ramasamy Paulmurugan Young Keun Kim Heemin Kang 《Advanced functional materials》2021,31(37):2103409
Developing materials with the capability of changing their innate features can help to unravel direct interactions between cells and ligand-displaying features. This study demonstrates the grafting of magnetic nanohelices displaying cell-adhesive Arg-Gly-Asp (RGD) ligand partly to a material surface. These enable nanoscale control of rapid winding (“W”) and unwinding (“UW”) of their nongrafted portion, such as directional changes in nanohelix unwinding (lower, middle, and upper directions) by changing the position of a permanent magnet while keeping the ligand-conjugated nanohelix surface area constant. The unwinding (“UW”) setting cytocompatibility facilitates direct integrin recruitment onto the ligand-conjugated nanohelix to mediate the development of paxillin adhesion assemblies of macrophages that stimulate M2 polarization using glass and silicon substrates for in vitro and in vivo settings, respectively, at a single cell level. Real time and in vivo imaging are demonstrated that nanohelices exhibit reversible unwinding, winding, and unwinding settings, which modulate time-resolved adhesion and polarization of macrophages. It is envisaged that this remote, reversible, and cytocompatible control can help to elucidate molecular-level cell–material interactions that modulate regenerative/anti-inflammatory immune responses to implants. 相似文献
85.
Lei Zhang Jing Li Songtao Yang Bin Wang Xingchao Bian 《Wireless Personal Communications》2018,101(2):943-961
In location-based service (LBS), the un-trusted LBS server can preserve lots of information about the user. Then the information can be used as background knowledge and initiated the inference attack to get user’s privacy. Among the background knowledge, the profile attribute of users is the especial one. The attribute can be used to correlate the real location in uncertain location set in both of the snapshot and continuous query, and then the location privacy of users will be revealed. In most of the existing scheme, the author usually assumes a trusted third party (TTP) to achieve the profile anonymity. However, as the TTP disposes all anonymous procedure for each user, it will become the center of attacks and the bottleneck of the query service. Furthermore, the TTP may be curious about user’s privacy just because of the commercial consideration. In order to deal with the inference attack and remedy the drawback of TTP scheme, we propose a similar attributes anonymous scheme which based on the CP-ABE, and with the help of center server and collaborative users, our scheme can resist the inference attack as well as the privacy detection of any entity in the service of query. At last, security analysis and experimental results further verify the effectiveness of our scheme in privacy protection as well as efficiency of the algorithm execution. 相似文献
86.
Tao Yan Bo Qu Ying Wang Guoyong Wang Wenying Lei Lang Bian Yansong Meng 《Wireless Personal Communications》2018,103(3):1895-1925
The dual-frequency constant envelope modulated (DCEM) signals, represented by alternative binary offset carrier signal, have obvious advantages in code tracking accuracy and anti-multipath performance compared with traditional binary phase shift keying signal, and are attracting more and more attention in the field of global navigation satellite system signal design. However, DCEM signal has a multiple-peaked auto-correlation function, which would lead to the tracking ambiguity problem. To deal with this problem, this paper proposes an unambiguous tracking method based on weighted discriminator function (WDF). This method uses the discriminator functions of noncoherent early minus late power (NELP) and sub carrier phase cancellation (SCPC) to generate a linear WDF without no false-lock points. In addition, a simplified version of the proposed WDF method is also provided for interoperable application. The theoretical code tracking error in thermal noise is derived out and verified. The performance of the proposed WDF is evaluated and compared with SCPC and pseudo correlation function methods with the help of simulation. Results show that our method has a significant improvement in code tracking accuracy. Not only the ambiguity threat is efficiently removed, but also the outstanding performance of DCEM signal is maintained. 相似文献
87.
报道了基于双端泵Nd:YVO4固体脉冲激光器泵浦的基于周期性畴极化反转氧化镁掺杂铌酸锂晶体(PPMgLN)的光参量振荡器(OPO)。双端泵Nd:YVO4固体脉冲激光器采用激光二极管作为双端泵浦源,在25 kHz重频下获得了平均功率为23.5 W的1064 nm近基模线偏振激光输出。使用该激光器泵浦一个基于PPMgLN的OPO,获得了平均功率为3.54 W的3.83μm中红外激光输出。OPO的斜率效率为65.2%,其中,从1.064μm到3.83μm的斜率效率为18.1%。该系统结构十分紧凑、成本低、实用性强,在4 h内的稳定度小于4%,具有较高的应用价值。 相似文献
88.
激光熔覆同轴送粉喷嘴研制 总被引:5,自引:1,他引:5
针对现有送粉喷嘴粉末汇聚性差、出粉口容易堵塞以及受热变形的缺点,设计了一种四孔式同轴送粉喷嘴。喷嘴中央为激光束及保护气通道,沿中心锥孔轴向均布的4个小孔,为粉末通道。建立了数值计算模型,应用FLUENT软件对粉末通道不同出口形状和不同倾角条件下粉末流场情况进行数值模拟,选择最优方案。计算结果表明,在其他工艺参数一定的前提下,采用收缩出口与粉末通道倾角为70°时有利于改善熔覆成形效果。最后利用研制的送粉喷嘴进行粉末汇聚、激光熔覆成形等实验,验证该送粉喷嘴的实验效果。 相似文献
89.
The microwave properties of barium strontium titanate (Ba0.6Sr0.4TiO3) thin films grown on (100) LaAlO3 (LAO) and (100) MgO single-crystal substrates through the sol–gel technique were investigated. The interdigital capacitor (IDC) technique was used to measure the nonlinear dielectric properties in the frequency range from 1 GHz to 10 GHz. The results show that the Curie temperature, capacitance, and tunability of the films are strongly dependent upon the substrate. The film fabricated on the LaAlO3 substrate has a higher tunability of 16.77% than that grown on the MgO substrate (~8.38%), measured at 10 GHz with an applied voltage of 35 V. The loss tangent is a linear function of the frequency in the microwave range, and the film grown on the MgO substrate has a lower loss tangent than that grown on the LAO substrate. This work reveals the great potential of Ba0.6Sr0.4TiO3 (BST) films for application in tunable microwave devices. 相似文献
90.
LD抽运355-nm准连续紫外激光器 总被引:1,自引:1,他引:1
报道了激光二极管(LD)侧面抽运Nd:YAG激光晶体腔内三倍频355 nm紫外激光器.实验中采用声光调Q技术,选用结构简单、紧凑的三镜折叠、平一凹腔设计,在腔内对1064 nm基波采用Ⅰ类相位匹配LiB3O5(LBO)晶体二倍频、Ⅱ类相位匹配LBO晶体实现三倍频,获得了较好光束质量的准连续紫外激光输出.在激光二极管抽运功率为155 W,声光调Q的调制频率为5.40 kHz的工作条件下,获得脉宽为45 ns,最高平均输出功率为2.14 W,光场均匀分布的355 nm准连续紫外激光,808 nm抽运光到355 nm紫外激光的光-光转换效率达到1.38%,1 h内输出稳定性为3.30%.此外,对影响腔内三倍频转换效率的因素进行了相应的分析研究. 相似文献