Application of membrane reactor for dehydrogenation of ethylbenzene

Two types of membrane reactors have been constructed in order to evaluate the influence of membrane reactor configuration on the performance of the dehydrogenation of ethylbenzene in a porous alumina membrane reactor. The type I construction combine reaction and separation in the same space. The type II configuration is comprised of three parts, i.e., reaction prior to separation, reaction and separation, and reaction after separation. The results showed that the overall yield of styrene in Type I is only 4% higher than that of the fixed bed reactor at 893 K, while 11 % enhancement in yield to styrene was obtained with Type II through optimizing the reaction conditions.     

Preparation and thermal property of hybrid nanocomposites by free radical copolymerization of styrene with octavinyl polyhedral oligomeric silsesquioxane

The poly(styrene‐co‐octavinyl‐polyhedral oligomeric silsesquioxane) (PS–POSS) organic–inorganic hybrid nanocomposites containing various percent of POSS were prepared via one‐step free radical polymerization and characterized by FTIR, high‐resolution ¹H NMR, ²⁹Si NMR, GPC, DSC, and TGA technologies. The POSS contents in these nanocomposites were determined using FTIR calibration curve. The result shows that the POSS contents in nanocomposites can be tailored by varying the POSS feed ratios. On the basis of the POSS contents in the nanocomposites and the ¹H NMR spectra, the number of reacted vinyl groups of each octavinyl‐POSS macromonomer were calculated to be 6–8. DSC and TGA measurements indicate that the incorporation of POSS into PS homopolymer can apparently improve the thermal properties of the polymeric materials. The dramatic T_g and T_dec increases are mainly due to the formation of star and low cross‐linking structure of the nanocomposites, where POSS cores behave as the joint points and hinder the motion and degradation of the polymeric chains. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Host Plant Volatiles Synergize Response to Sex Pheromone in Codling Moth, Cydia pomonella

Plant volatile compounds synergize attraction of codling moth males Cydia pomonella to sex pheromone (E,E)-8,10-dodecadien-1-ol (codlemone). Several apple volatiles, known to elicit a strong antennal response, were tested in a wind tunnel. Two-component blends of 1 pg/min codlemone and 100 pg/min of either racemic linalool, (E)-beta-farnesene, or (Z)-3-hexen-1-ol attracted significantly more males to the source than codlemone alone (60, 58, 56, and 37%, respectively). In comparison, a blend of codlemone and a known pheromone synergist, dodecanol, attracted 56% of the males tested. Blends of pheromone and plant volatiles in a 1:100 ratio attracted more males than 1:1 or 1:10,000 blends. Adding two or four of the most active plant compounds to codlemone did not enhance attraction over blends of codlemone plus single-plant compounds. Of the test compounds, only farnesol was attractive by itself; at a release rate of 10,000 pg/min, 16% of the males arrived at the source. However, attraction to a 1:10,000 blend of codlemone and farnesol (42%) was not significantly different from attraction to codlemone alone (37%). In contrast, a codlemone mimic, (E)-10-dodecadien-1-ol, which attracted 2% males by itself, had a strong antagonistic effect when blended in a 1:10,000 ratio with codlemone.     

PC／PA1010共混物的热行为

利用热失重、微分热失重和显示扫描量热法研究了聚碳酸酯／尼龙１０１０共混物的热行为和解降解过程。结果表明：共混物在６００℃以下分两步降解，降解温度随尼龙１０１０用量增加有下降趋势；共混物的熔点随尼龙１０１０用量增加而升高。     

CAE技术在模具设计过程中的并行应用

介绍CAE技术在模具设计并行工程中应用的基本思路、设计流程和主要特点，并应用Moldflow软件对空气取水机门盖进行CAE分析，以说明CAE技术的并行应用过程。实践证明，CAE技术的并行应用可以提高模具设计质量、缩短模具设计时间，为设计人员提供有效的技术支持，最大限度地发挥CAE的技术优势。     

NiMnFeO_4的制备与性能研究

采用 (NH4) 2 C2 O4为沉淀剂 ,基于共沉淀法制备了NiMnFeO4NTC热敏陶瓷 ,用TG、XRD、SEM、电导率测量等方法对前驱体、氧化物粉体及NTC陶瓷样品的进行了表征。结果表明 ,用此种方法制备的NTC陶瓷 ,其结构均匀、致密 ;烧结后经随炉冷却的样品 ,在 15 0℃老化 10 0 0h后 ,电阻漂移小于 1% ;而在 115 0℃下淬火的样品在同样的条件下 ,电阻漂移大于 4 %。     

试论我国锦纶生产发展方向

回顾了锦纶发展简史，综述了国内锦纶生产现状，并论述了我国锦纶生产发展方向，必须大力发展原料工业；加快老企业的设备改造；使其达到规模经济，大力发展差别化、高附加值、功能性纤维。同时，提出了锦纶各品种的发展趋向。     

分子生物技术在石油降解微生物研究中的应用

总结了生物法治理石油污染的局限性,介绍了几种在石油降解微生物研究中广泛应用的分子生物技术,并对该研究领域未来的发展趋势进行了预测。     

A paraffin-fueled SOFC system design and integration

This paper addresses an integrated design of paraffin-reformer, gas separations and the electricity production with a solid oxide fuel cell (SOFC). The overall design consists of three modules. First module is a system of paraffin reformer. In this module, the paraffin feed stream is to send to a steam-reformer. In the second module, the gas separations method illustrated is the combination of a methane-permeable membrane with a pressure-swing adsorption (PSA). In the third module, the purified hydrogen is fed to the SOFC unit. To be energy efficient, this paraffin-fueled SOFC system is designed with the consideration of heat integration. The intent of this paper is to provide a possible, alternative way of cogeneration systems for refinery and petrochemical plants.     

加氢催化剂的器外再生

介绍了国内外再生技术的发展状况，对比器内和器外再生技术的优缺点以及催化剂活性恢复率的差异，说明器外再生技术是催化剂再生的发展方向。