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101.
102.
Dianjun Yao 《Polymer》2005,46(12):4390-4396
The crystalline conformations of perylene polyimides (PPIs), with alkyl spacers varying in length from C3 to C12 are discussed. Although modeling of single chains would suggest the possibility that those with odd number of CH2 groups adopt a flat helical shape, X-ray diffraction suggests that the chains with odd and even spacers have the same conformation, due to the necessity to pack the perylene units. Upon annealing, the UV-vis absorption maximum red-shifts by about 10 nm, indicating enhanced π-stacking between the perylenes. Several changes in the spectra are seen with an increase in annealing time, at a given temperature. With an increase in annealing time, X-ray diffraction patterns show changes in the number of reflections, indicative of a crystal to mesogenic transition. The time required for this transition increases with a decrease in the spacer length, and annealing temperature, suggesting that the dynamics of this transition is very slow. 相似文献
103.
文章提出了对索赔事项的分类办法,并对水利水电工程施工合同范本中涉及到的索赔与反索赔事项与条款进行了分解,指出了承、发包方可能面临的索赔风险及其确定方法 相似文献
104.
Qingzhao Yao Yuming Zhou Yanqing Sun Xiaoyun Ye 《Journal of Inorganic and Organometallic Polymers and Materials》2008,18(4):477-484
TiO2 hybrid molecular imprinted polymer (MIP) for ethofumesate using methacrylic acid (MAA) as the functional monomer and silane
coupling agent 3-(trimethoxysilyl) propylmethacrylate (KH570) as organic–inorganic connective bridge was synthesized via photo-excitation
method. Hydrogen bond was proved to act between MAA and ethofumesate for pre- and post-polymerization binding properties as
testified by UV spectrometric method. KH570 modified TiO2 nanoparticles were prepared via sonochemical reaction, which can accelerate hydrolysis, increase collision chance for the
reactive system and improve the dispersion of the nanoparticles. Scanning electron microscope (SEM), transmission electron
microscope (TEM), binding and the adsorption kinetics experiments as well as thermogravimetric analysis (TGA) were employed
for characterization. The results indicated that the hybrid MIP revealed a larger surface area and more ordered imprinting
cavities with improved thermal stability compared to organic-only MIP. Furthermore, faster adsorption kinetics and enhancive
adsorption capacity were achieved, which made it promising in chemical sensor applications. 相似文献
105.
The present study is an investigation on the behaviors of concrete-filled thin-walled steel tubular members subjected to combined loading, such as compression and torsion, bending and torsion, compression, bending and torsion. ABAQUS software is used in this paper for the finite element analysis (FEA). A comparison of results calculated using this modeling shows generally good agreement with test results. The FEA modeling is then used to investigate the influence of important parameters that determine the ultimate strength of the composite members under combined loading, such as compression and torsion, bending and torsion, compression, bending and torsion. The parametric studies provide information for the development of formulae for calculating the ultimate strength of the composite members subjected to combined loading. 相似文献
106.
蒋熙 《中国服装(北京)》2005,(23):b0010-b0025
1995年4月下旬,中国服装设计师协会主办了首届中国“十佳”服装设计师评选活动。在符合条件的上万名设计师当中选拔出15名候选人,进而评选出十位最佳设计师,被赋予“十佳”称号。首届获得十佳称号的设计师为张肇达、刘洋、王新元、吴海燕、马可、于泽正、崔游、陈红、刘丽丽和罗亚平等十人。 相似文献
107.
108.
Wei Li Zhang Wei Pan Bin Luo Xi Hua Zou Meng Yao Wang 《Photonics Technology Letters, IEEE》2008,20(9):712-714
A theoretical construction of one-to-many (OTM) and many-to-one (MTO) chaos synchronization communications using semiconductor lasers is presented. One center laser provides strong injections (strong link) to other side lasers, and the side lasers also provide weak injections (weak link) to the center one. Simulation results show that the side lasers synchronize with the center laser through injection-locking. In addition, messages transmitted via the strong links or the weak links experience strong chaos pass filtering, enabling us to realize OTM and MTO communications. 相似文献
110.
本文通过石墨阴极溶液涂膜法制得甲基丙烯酸-丙烯酸共聚物[P(MMA-co-MAA)]与环氧乙烷(PEO)的共混聚合物,并以其为基质制备了聚合物基铜金属复合膜(CPCFs).在这一过程中,对所得溶胀阴极膜(SCF)进行半干燥处理后,用电化学方法使其还原以得最终产物.实验研究表明:(1)低P(MMA-co-MAA)含量会增强SCF的离子电导率;(2)还原反应中酸性环境会增强电导性;(3)水-乙醇共溶剂有助于增强电导率.偏光显微镜测试显示:poly(MMA-co-MAA)会影响PEO的结晶.X-射线衍射实验也证实了还原铜金属单质的存在. 相似文献