L－B膜修饰电极循环伏安行为模拟──（Ⅰ）电荷转移速度常数对循环伏安性能的影响

本文用计算机数字模拟方法研究了电活性分子多层Ｚ型Ｌ－Ｂ膜修饰电极的循环伏安行为。计算了电极与修饰Ｌ－Ｂ膜分子第一层之间的电荷转移速度常数Ｋ_ｏ，Ｌ－Ｂ膜分子层间的电荷转移速度常数ｋ_ｉ；对峰电位差△Ｅ_ｐ及阳极峰面积Ｑ的影响，以及在不同条件下各层分子的氧化态分数随扫描时间的变化。为研究和设计电活性分子修饰电极的实际体系提供了大量数据和信息。     

Presupposition failure — A comedy of errors

Presuppositions of utterances are the pieces of information you convey with an utterance no matter whether your utterance is true or not. We first study presupposition in a very simple framework of updating propositional information, with examples of how presuppositions of complex propositional updates can be calculated. Next we move on to presuppositions and quantification, in the context of a dynamic version of predicate logic, suitably modified to allow for presupposition failure. In both the propositional and the quantificational case, presupposition failure can be viewed as error abortion of procedures. Thus, a dynamic assertion logic which describes the preconditions for error abortion is the suitable tool for analysing presupposition.     

地面反射波谱与卫星磁带记录数据间关系模拟的初步探讨──以冬小麦和土壤为例

根据冬小麦和土壤地面反射波谱测试数据，计算了在卫星高度上与卫星磁带数据相对应波段的辐亮度值，对ＮＯＡＡＡＶＨＲＲ和ＴＭ某些通道的差值绿度植被指数ＤＶＩ、归一化绿度植被指数ＮＤＶＩ和比值绿度植被指数ＲＶＩ的分析，从理论上证明了目前采用ＴＭＤＶＩ＿（４，３）提取冬小麦种植面积和ＮＯＡＡＮＤＶＩ＿（２，１）区分植被和土壤背景的有效性。同时在冬小麦种植面积和长势监测方面提出了一些新建议。     

A novel cyclic process using CaSO<Subscript>4</Subscript>/CaS pellets for converting sulfur dioxide to elemental sulfur without generating secondary pollutants: Part I. Feasibility and kinetics of the reduction of sulfur dioxide with calcium-sulfide pellets

Certain new sulfide-smelting processes and coal-gasification processes generate high-strength sulfur dioxide streams, for which a new process for converting sulfur dioxide to elemental sulfur needs to be developed because no process exists that is generally and economically applicable to the treatment of such streams. A thermodynamic and experimental investigation to develop a new process for converting sulfur dioxide to elemental sulfur by a cyclic process involving calcium sulfide and calcium sulfate without generating secondary pollutants was carried out. In this process, the starting raw material, calcium sulfate, is reduced by a suitable reducing agent, such as hydrogen, to produce calcium sulfide, which is used to reduce sulfur dioxide to elemental sulfur vapor and calcium sulfate. The latter is, in turn, reduced to regenerate calcium sulfide. In this Part I, detailed experimental results are presented on the kinetics of the reaction between sulfur dioxide and calcium-sulfide pellets, which produces elemental sulfur and calcium sulfate. The experiments were carried out at temperatures between 1023 and 1088 K and sulfur-dioxide partial pressures between 9 and 60 kPa by the use of a thermogravimetric analysis (TGA) technique. The rate of this reaction was demonstrated by the conversion of 40 pct calcium-sulfide pellets obtained from the hydrogen reduction of fresh calcium sulfate in 10 minutes at 1073 K under a sulfur-dioxide partial pressure of 43 kPa. The reactivity decreased somewhat during the first three cycles but remained largely unchanged thereafter up to the tenth cycle. This characteristic of the pellets is important because the solids must be reusable for repeated cycles to avoid generating secondary pollutants. A pore-blocking model was found to fit the reaction rate. The reaction is first order with respect to sulfur-dioxide partial pressure and has an activation energy of 101 to 134 kJ/mol (24 to 32 kcal/mol) for calcium-sulfide pellets reacted and regenerated several different times. Sulfur dioxide-containing streams from certain sources, such as the regenerator off-gas from an integrated-gasification, combined-cycle, desulfurization unit and new sulfide-smelting plants, contain much higher partial pressures of SO₂. In these cases, the rate of the first reaction is expected to be proportionally higher than in the test conditions reported in this article. The reduction kinetics of calcium-sulfate pellets with hydrogen gas is reported in the accompanying Part II.     

印刷质量控制的基本方法(一)综述

无论哪一种印刷品的生产都要经过若干个工艺过程，才能将原稿上的图文信息转移到承印物上。由于印刷技术的飞跃发展，标准化和质量控制成为一个很重要的问题。标准化和质量控制在很大程度上是依靠仪器和控制装置来实现的。科学技术的极大发展，大大地推动了印刷技术的发展，印刷所使用的原材料和工艺得到了很大的改进，逐步实现了标准化，提高并稳定了生产高质量产品的能力。目前我们评价印刷品质量的优劣大致有三种方法：主观评价法、客观评价法和综合评价法。主观评价法，是以原稿为基础对照样张来评价。这里有人为的因素，根据评价人的知…     

Microbiological denitrification of red beet juice

The purpose of study was the determination of optimal conditions for red beet juice denitrification by Paracoccus denitrificans bacteria as well as the evaluation of the usefulness of microbiologically treated juice for the production of a natural colouring preparation for foods. Total reduction of nitrates was found during bacterial culturing at 25 and 30 °C, at an initial pH of 7.0-8.0 and juice osmotic pressure of 900-1100 mOsm/kg. Microbiological denitrification procedure affected colour, taste and aroma of the juice. However, the use of juice as food colouring and component was made feasible by acidification and partial evaporation of water together with volatile substances.     

分光光度法测定微量茴香醛的研究

研究了测定微量茴香醛的光度分析新方法。在盐酸介质中,硫代巴比妥酸与茴香醛发生缩合反应,生成棕色产物,可用于微量茴香醛的测定。最大吸收波长为415nm,茴香醛浓度在2×10-6-1×10-4mol/L范围内符合比尔定律。该法具有灵敏、准确、操作简便、快速等特点。用于测定食品中茴香醛的含量,结果满意。     

俄罗斯陶瓷及其金属化技术的研究

采用X射线荧光、X射线衍射、金相显微镜和扫描电镜等分析方法 ,通过对微波管陶瓷材料的理化分析 ,对俄罗斯陶瓷及其金属化技术进行了研究 ,并对化学成分和显微结构对性能的影响作了初步的讨论。