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921.
Dong Wu Si‐Zhu Wu Shuai Zhao Jia Yao Jiang‐Nan Wang Qi‐Dai Chen Hong‐Bo Sun 《Small (Weinheim an der Bergstrasse, Germany)》2013,9(5):760-767
A simple strategy to realize new controllable 3D microstructures and a novel method to reversibly trapping and releasing microparticles are reported. This technique controls the height, shape, width, and arrangement of pillar arrays and realizes a series of special microstructures from 2‐pillar‐cell to 12 cell arrays, S‐shape, chain‐shape and triangle 3‐cell arrays by a combined top down/bottom up method: laser interference lithography and capillary force‐induced assembly. Due to the inherent features of this method, the whole time is less than 3 min and the fabricated area determined by the size of the laser beam can reach as much as 1 cm2, which shows this method is very simple, rapid, and high‐throughput. It is further demonstrated that the ‘mechanical hand’‐like 4‐cell arrays could be used to selectively trap/release microparticles with different sizes, e.g., 1.5, 2, or 3.5 μm, which are controlled by the period of the microstructures from 2.5 to 4 μm, and 6 μm. Finally, the ‘mechanical hand’‐like 4‐cell arrays are integrated into 100 μm‐width microfluidic channels prepared by ultraviolet photolithography, which shows that this technique is compatible with conventional microfabrication methods for on‐chip applications. 相似文献
922.
Xiaozhi Xu Ding Yi Zhichang Wang Jiachen Yu Zhihong Zhang Ruixi Qiao Zhanghao Sun Zonghai Hu Peng Gao Hailin Peng Zhongfan Liu Dapeng Yu Enge Wang Ying Jiang Feng Ding Kaihui Liu 《Advanced materials (Deerfield Beach, Fla.)》2018,30(6)
Metal corrosion is a long‐lasting problem in history and ultrahigh anticorrosion is one ultimate pursuit in the metal‐related industry. Graphene, in principle, can be a revolutionary material for anticorrosion due to its excellent impermeability to any molecule or ion (except for protons). However, in real applications, it is found that the metallic graphene forms an electrochemical circuit with the protected metals to accelerate the corrosion once the corrosive fluids leaks into the interface. Therefore, whether graphene can be used as an excellent anticorrosion material is under intense debate now. Here, graphene‐coated Cu is employed to investigate the facet‐dependent anticorrosion of metals. It is demonstrated that as‐grown graphene can protect Cu(111) surface from oxidation in humid air lasting for more than 2.5 years, in sharp contrast with the accelerated oxidation of graphene‐coated Cu(100) surface. Further atomic‐scale characterization and ab initio calculations reveal that the strong interfacial coupling of the commensurate graphene/Cu(111) prevents H2O diffusion into the graphene/Cu(111) interface, but the one‐dimensional wrinkles formed in the incommensurate graphene on Cu(100) can facilitate the H2O diffusion at the interface. This study resolves the contradiction on the anticorrosion capacity of graphene and opens a new opportunity for ultrahigh metal anticorrosion through commensurate graphene coating. 相似文献
923.
Artificial Protection Film on Lithium Metal Anode toward Long‐Cycle‐Life Lithium‐Oxygen Batteries 下载免费PDF全文
924.
Indium tin oxide (ITO) thin films deposited on flexible polyethylene terephthalate (PET) substrates at low temperature by DC magnetron sputtering from an In-Sn (90-10 wt pct) alloy target were studied. The correla-tion between deposition conditions and ITO property was systematically investigated and characterized. These as-deposited ITO films were used as the anode contact for flexible organic light-emitting diodes (FOLEDs). The fabricated FOLEDs with a structure of PET/ITO/NPB (50 nm)/Alq (20 nm)/Mg:Ag (100 nm) showed a maximum luminance of 2125 cd/m2 at 13 V. 相似文献
925.
等离子体溅射沉积是制备直接甲醇燃料电池电极的非常好的方法。采用磁控溅射,Pt被成功溅射在气体扩散层上。在不同的溅射功率和气压下制备了具有相同Pt负载量(0.1mg/cm2)的电极。X射线衍射测试显示Pt以面心立方结构存在。X射线光电子能谱证明了电极中的Pt以Pt(0)态的形式存在。扫描电镜观测显示Pt催化剂以纳米粒子和纳米团簇的形式存在。溅射电极的循环伏安曲线都具有Pt金属的典型性质。将用溅射方法制备的阴极与商用催化剂制备的阳极组装成膜电极一体化,并测试了单电池的性能。结果显示,在5.3Pa,110W条件下制备的阴极相比其他溅射参数下制备的电极具有较好的电性能,这主要是由于Pt粒径的降低以及多孔催化剂层的形成。 相似文献
926.
927.
NR/SBR共混物的动态疲劳与断裂特征 总被引:7,自引:0,他引:7
以断裂力学为基础,采用分子观点描述了天然橡胶/丁苯橡胶的动态疲劳过程。结合断裂力学的参数β和C0,对S ̄N曲线特性和断口形貌进行分析和比较,为最佳共混比的选择提供了理论依据。 相似文献
928.
Thermally Stable Metal‐Organic Framework‐Templated Synthesis of Hierarchically Porous Metal Sulfides: Enhanced Photocatalytic Hydrogen Production 下载免费PDF全文
Porous nanostructured materials are demonstrated to be very promising in catalysis due to their well accessible active sites. Thermally stable metal‐organic frameworks (MOFs) as hard templates are successfully utilized to afford porous metal oxides and subsequently metal sulfides by a nanocasting method. The resultant metal oxides/sulfides show considerable Brunauer–Emmett–Teller (BET) surface areas, by partially inheriting the pore character of MOF templates. Preliminary investigation on the obtained hierarchically porous CdS for water splitting, as a proof of concept, demonstrates its much higher activity than both corresponding bulk and nanosized counterparts, under visible light irradiation. Given the structural diversity and tailorability of MOFs, such synthetic approach may open an avenue to the synthesis of advanced porous materials for functional applications. 相似文献
929.
Integration of Multiple Plasmonic and Co‐Catalyst Nanostructures on TiO2 Nanosheets for Visible‐Near‐Infrared Photocatalytic Hydrogen Evolution 下载免费PDF全文
Wenya Jiang Song Bai Limin Wang Xijun Wang Li Yang Yanrui Li Dong Liu Xiaonong Wang Zhengquan Li Jun Jiang Yujie Xiong 《Small (Weinheim an der Bergstrasse, Germany)》2016,12(12):1640-1648
Utilization of visible and near‐infrared light has always been the pursuit of photocatalysis research. In this article, an approach is developed to integrate dual plasmonic nanostructures with TiO2 semiconductor nanosheets for photocatalytic hydrogen production in visible and near‐infrared spectral regions. Specifically, the Au nanocubes and nanocages used in this work can harvest visible and near‐infrared light, respectively, and generate and inject hot electrons into TiO2. Meanwhile, Pd nanocubes that can trap the energetic electrons from TiO2 and efficiently participate in the hydrogen evolution reaction are employed as co‐catalysts for improved catalytic activity. Enabled by this unique integration design, the hydrogen production rate achieved is dramatically higher than those of its counterpart structures. This work represents a step toward the rational design of semiconductor–metal hybrid structures for broad‐spectrum photocatalysis. 相似文献