Influence of thermal annealing on microstructural,morphological, optical properties and surface electronic structure of copper oxide thin films

In this study, effect of the post-deposition thermal annealing on copper oxide thin films has been systemically investigated. The copper oxide thin films were chemically deposited on glass substrates by spin-coating. Samples were annealed in air at atmospheric pressure and at different temperatures ranging from 200 to 600°C. The microstructural, morphological, optical properties and surface electronic structure of the thin films have been studied by diagnostic techniques such as X-ray diffraction (XRD), Raman spectroscopy, ultraviolet–visible (UV–VIS) absorption spectroscopy, field emission scanning electron microscopy (FESEM), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). The thickness of the films was about 520 nm. Crystallinity and grain size was found to improve with annealing temperature. The optical bandgap of the samples was found to be in between 1.93 and 2.08 eV. Cupric oxide (CuO), cuprous oxide (Cu₂O) and copper hydroxide (Cu(OH)₂) phases were observed on the surface of as-deposited and 600 °C annealed thin films and relative concentrations of these three phases were found to depend on annealing temperature. A complete characterization reported herein allowed us to better understand the surface properties of copper oxide thin films which could then be used as active layers in optoelectronic devices such as solar cells and photodetectors.     

Prediction of flow fields and temperature distributions due to natural convection in a triangular enclosure using Adaptive-Network-Based Fuzzy Inference System (ANFIS) and Artificial Neural Network (ANN)

Artificial Neural Network (ANN) and Adaptive-Network-Based Fuzzy Inference System (ANFIS) were used to predict the natural convection thermal and flow variables in a triangular enclosure which is heated from below and cooled from sloping wall while vertical wall is maintained adiabatic. Governing equations of natural convection were solved using finite difference technique by writing a FORTRAN code to generate database for ANN and ANFIS in the range of Rayleigh number from Ra = 10⁴ to Ra = 10⁶ and aspect ratio of triangle AR = 0.5 and AR = 1. Thus, the results obtained from numerical solutions were used for training and testing the ANN and ANFIS. A comparison was performed among the soft programming and Computational Fluid Dynamic (CFD) codes. It is observed that although both ANN and ANFIS soft programming codes can be used to predict natural convection flow field in a triangular enclosure, ANFIS method gives more significant value to actual value than ANN.     

Classification of Diabetic Macular Edema and Its Stages Using Color Fundus Image

Diabetic macular edema(DME)is a retinal thickening involving the center of the macula.It is one of the serious eye diseases which affects the central vision and can lead to partial or even complete visual loss.The only cure is timely diagnosis,prevention,and treatment of the disease.This paper presents an automated system for the diagnosis and classification of DME using color fundus image.In the proposed technique,first the optic disc is removed by applying some preprocessing steps.The preprocessed image is then passed through a classifier for segmentation of the image to detect exudates.The classifier uses dynamic thresholding technique by using some input parameters of the image.The stage classification is done on the basis of an early treatment diabetic retinopathy study(ETDRS)given criteria to assess the severity of disease.The proposed technique gives a sensitivity,specificity,and accuracy of 98.27%,96.58%,and 96.54%,respectively on publically available database.     

A thermodynamic interpretation of a model for the equilibrium states of water phases in porous materials

A thermodynamic explanation is given for the empirical coefficients in a model for the equilibrium state of water in a porous material.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 47, No. 2, pp. 221–228, August, 1984.     

A new spatial path persistency model for TOA-based indoor geolocation

Analysis of the persistency and birth/death of multipath components of the channel impulse response is essential for performance evaluation of indoor geolocation algorithms using indirect paths for ranging. The use of indirect paths via multipath diversity is particularly important for situations where the direct path gets blocked. In this letter, we propose a statistical model for the spatial behavior of the persistency of multipath components as a mobile moves inside a building. Based on empirical data from a measurement calibrated ray tracing algorithm we show that the persistency in a typical building is modeled by log-logistic distribution rather than commonly assumed exponential distribution and path birth can be modeled as a Poisson distribution.     

Current scenario and potential of biodiesel production from waste cooking oil in Pakistan: An overview

Biodiesel utilization has been rapidly growing worldwide as the prime alternative to petrodiesel due to a global rise in diesel fuel demand along with hazardous emissions during its thermochemical conversion. Although, several debatable issues including feedstock availability and price, fuel and food competition, changes in land use and greenhouse gas emission have been raised by using edible as well as inedible feedstocks for the production of biodiesel. However, non-crop feedstocks could be a promising alternative. In this article, waste cooking oils have been recommended as a suitable option for biodiesel production bearing in mind the current national situation. The important factors such as the quantity of waste cooking oil produced, crude oil and vegetable oil import expenses, high-speed diesel imports, waste management issues and environmental hazards are considered. Moreover, process simulation and operating cost evaluation of an acid catalyzed biodiesel production unit are also conducted. The simulation results show that the production cost of waste cooking oil-based biodiesel is about 0.66USD·L^-1. We believe that the present overview would open new pathways and ideas for the development of biofuels from waste to energy approach in Pakistan.     

The Influence of Al2O3 and TiO2 Additives on the Electrical Resistivity of Epoxy Resin‐Based Composites at Low Temperature

Electrical insulation is a major security problem in aerospace applications where temperature can reach relatively low values. Epoxy resins are well known as easily formable dielectric materials and can be used to prepare complex insulator parts. In this study, the electrical performance of bisphenol A/epichlorohydrin epoxy resin matrix‐based nanocomposites containing 1, 3, or 6 wt% titanium oxide (TiO₂) or aluminium oxide (Al₂O₃) nanofillers are investigated. Composites are characterized with thermogravimetric analysis, scanning electron microscopy‐coupled electron dispersive spectroscopy, and confocal Raman spectroscopy. Furthermore, the role of additives and their ratio on the resistivity performance of the composites are evaluated from 77 to 500 K by applying a direct current voltage from 1 to 20 V. It is observed that the electrical properties of the matrix are directly influencing the insulation performance of the nanocomposite. For example, the abrupt decrease at 370 K of the positive temperature coefficient of the resin for all nanocomposites. It is found that the most resistive composite contains 3 wt% TiO₂ nanoparticles with a value above 3.7.10¹⁰ Ω from 77 to 370 K at 20 V. As a result, this work gives information on to the choice of appropriate insulator materials in extreme working conditions.     

Polyimide-coated fabrics with multifunctional properties: Flame retardant,UV protective,and water proof

Multifunctional technical textiles are of great interest both by industry and academia and these products are considered as high value-added products that contribute to the economies of countries. In this study, polyamic acid (PAA) was synthesized through polycondensation of pyromellitic dianhydride (PMDA) and 4,4′-oxydianiline (ODA) in dimethyl acetamide (DMAc) at low temperature. Then, PAA was coated onto woven cotton and polyester fabric by padding technique. Finally, polyimide (PI)-coated multifunctional cotton and polyester fabrics were obtained by an easy coating technique and low-temperature imidization. Thus, low cost, easily accessible and widely used cotton and polyester fabrics were converted to high-performance textile products, which are flame retardant, UV protective, acid resistant, and waterproof. The chemical, thermal, morphological, optical, mechanical, wettability, chemical resistance, and flame retardancy properties of developed fabrics were investigated. Optical results showed that both PI-coated cotton and polyester fabrics are UV-A protective compared to noncoated fabrics. Moreover, PI-coated samples have high contact angles which are 111.43° and 113.40° for PI-coated cotton (PI-c-C) and PI-coated polyester (PI-c-PET), respectively. Young's modulus of PI-c-PET fabrics increased four times more than noncoated polyester fabric. PI coating changed the burning behavior of both cotton and polyester fabrics in a positive way. All the test results showed that these developed multifunctional textile products might find an application in different industrial areas such as automotive, aerospace, protective clothing, and so on due to easy and inexpensive production techniques and also superior properties. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47616.     

Fixed frequency sliding mode control of renewable energy resources in DC micro grid

The rising cost of fossil fuels, their high depleting rate and issues regarding environmental pollution have brought the attention of the researchers towards renewable energy technologies. Different renewable energy resources like wind turbines, fuel cells and solar cells are connected to DC micro grid through controllable power electronic converters. In presence of these diverse generation units, robust controllers are required to ensure good power quality and to regulate grid voltage. This paper presents a sliding mode control based methodology to address the above mentioned challenges. The proposed technique keeps the switching frequency constant so that electromagnetic compatibility (EMC) issues can be solved with conventional filter design. Parallel operation of converter in DC micro gird is considered. Chattering reduction and power quality improvement by harmonic cancellation is proposed. A scaled down hardware for unregulated 11.5 V to 17.5 V input and 24V output is designed and tested. The experimental results show good performance of the controller under different loads and uncertain input voltage conditions. Moreover, the results show the robustness of the closed loop system to sudden variations in load conditions. Furthermore, a significant improvement in power quality is achieved by harmonic cancellation of chattering in the output of the converters.     

Exploration of Advanced Electrode Materials for Approaching High‐Performance Nickel‐Based Superbatteries

The surging interest in high performance, low‐cost, and safe energy storage devices has spurred tremendous research efforts in the development of advanced electrode active materials. Herein, the in situ growth of zinc–iron layered double hydroxide (Zn–Fe LDH) on graphene aerogel (GA) substrates through a facile, one‐pot hydrothermal method is reported. The strong interaction and efficient electronic coupling between LDH and graphene substantially improve interfacial charge transport properties of the resulting nanocomposite and provide more available redox active sites for faradaic reactions. An LDH–GA||Ni(OH)₂ device is also fabricated that results in greatly enhanced specific capacity (187 mAh g^?1 at 0.1 A g^?1), outstanding specific energy (147 Wh kg^?1), excellent specific power (16.7 kW kg^?1), along with 88% capacity retention after >10 000 cycles. This approach is further extended to Ni–MH and Ni–Cd batteries to demonstrate the feasibility of compositing with graphene for boosting the energy storage performance of other well‐known Ni‐based batteries. In contrast to conventional Ni‐based batteries, the nearly flat voltage plateau followed by a sloping potential profile of the integrated supercapacitor–battery enables it to be discharged down to 0 V without being damaged. These findings provide new prospects for the design of high‐performance and affordable superbatteries based on earth‐abundant elements.