A PAM control method for a matrix converter based on a virtual AC/DC/AC conversion method

In this paper, a novel control method for a matrix converter is proposed. The proposed method is a PAM (Pulse Amplitude Modulation) control method based on a virtual AC/DC/AC conversion method. Output voltage amplitude is controlled by controlling a virtual DC link voltage with a virtual rectifier. Output frequency is controlled by a virtual inverter. First, the proposed method is explained. Next, the validity of the proposed method is confirmed through simulation and experiment using a 750‐W prototype matrix converter. Moreover, various characteristics of the proposed method and conventional virtual AC/DC/AC method are compared through experiment. As a result of the experiment, it has been understood that total harmonic distortion of output current and common‐mode voltage can be reduced compared with the case of using a conventional virtual AC/DC/AC conversion method. © 2008 Wiley Periodicals, Inc. Electr Eng Jpn, 166(4): 88–96, 2009; Published online in Wiley InterScience ( www.interscience. wiley.com ). DOI 10.1002/eej.20601     

TEM/STEM Observation of ZrC Coating Layer for Advanced High-Temperature Gas-Cooled Reactor Fuel, Part II

The Japan Atomic Energy Agency (JAEA) has started to study and develop zirconium carbide (ZrC)-coated fuel particles for advanced high-temperature gas-cooled reactors. The ZrC coating layer has been fabricated at JAEA by chemical vapor deposition using a pyrolytic reaction of zirconium bromide. The microstructures of the ZrC layers, whose nominal deposition temperatures could be measured and controlled during the deposition process, were characterized by means of TEM and STEM. In the present study, three batches were prepared and compared with each other as well as the previous batches. The crystallographic orientation of ZrC with regard to the growth direction in the ZrC layers deposited at a constant temperature of 1630 K was different from that deposited at varying temperatures in the 1493–1823 K range. A thin layer of turbostratic carbon was observed at the boundary between pyrolytic carbon and ZrC in particles deposited at the highest temperature among those used in this study (the nominal temperature was 1769 K); no such structure was found in a batch deposited at a lower temperature (the nominal temperature was 1632 K). Therefore, precise control of temperature is shown to be critical to the formation of good ZrC coatings.     

Impact of different moderator ratios with light and heavy water cooled reactors in equilibrium states

As an issue of sustainable development in the world, energy sustainability using nuclear energy may be possible using several different ways such as increasing breeding capability of the reactors and optimizing the fuel utilization using spent fuel after reprocessing as well as exploring additional nuclear resources from sea water. In this present study the characteristics of light and heavy water cooled reactors for different moderator ratios in equilibrium states have been investigated. The moderator to fuel ratio (MFR) is varied from 0.1 to 4.0. Four fuel cycle schemes are evaluated in order to investigate the effect of heavy metal (HM) recycling. A calculation method for determining the required uranium enrichment for criticality of the systems has been developed by coupling the equilibrium fuel cycle burn-up calculation and cell calculation of SRAC 2000 code using nuclear data library from the JENDL 3.2. The results show a thermal spectrum peak appears for light water coolant and no thermal peak for heavy water coolant along the MFR (0.1 ? MFR ? 4.0). The plutonium quality can be reduced effectively by increasing the MFR and number of recycled HM. Considering the effect of increasing number of recycled HM; it is also effective to reduce the uranium utilization and to increase the conversion ratio. trans-Plutonium production such as americium (Am) and curium (Cm) productions are smaller for heavy water coolant than light water coolant. The light water coolant shows the feasibility of breeding when HM is recycled with reducing the MFR. Wider feasible area of breeding has been obtained when light water coolant is replaced by heavy water coolant.     

Selective and in-situ determination of carbonate and oxide particles in aqueous solution using laser-induced breakdown spectroscopy (LIBS) for wearable information equipment

Laser-induced breakdown spectroscopy (LIBS) has been applied for quantitative analysis of Al₂O₃, CaCO₃ and MgO particles suspended in water. In the single elemental system, the plasma emission intensities of Al, Ca and Mg were linearly increased with concentration of elements in the range of 1.0×10^?5–1.0×10^?3  M, 1.0×10^?4–2.0×10^?3 M and 8.0×10^?5 –4.0×10^?3 M, respectively. We also investigated the concentration dependence of breakdown spectra for suspended mixtures of Al₂O₃, CaCO₃ and MgO particles. The emission lines, such as Al I, Ca I, Ca II and Mg I, were appeared in the LIBS spectrum simultaneously, and each emission peak could be deconvoluted. The plasma emission intensities of Al, Ca and Mg in the multielemental system were also linearly increased with their concentrations in the range of 1.0×10^?5–1.0×10^?3 M, 1.0×10^?4–2.0×10^?3 M and 4.0×10^?4–2.0×10^?3 M, respectively. LIBS was found to be available for quantitative and qualitative measurement of the concentrations of Al₂O₃, CaCO₃ and MgO particles suspended in water. The present results suggest that LIBS is a potentially useful tool for in-situ analysis on particles composition and concentrations for environmental monitoring by the wearable information equipments.     

Selective isopentane formation from CH3OH on a new one-atomic layer ZrO2/ZSM-5 hybrid catalyst

A new one-atomic layer ZrO₂/ZSM-5 hybrid catalyst was prepared by using the repeated reactions between Zr(OC₂H₅)₄ and of the OH groups of the external surfaces of ZSM-5, followed by calcination. The one-atomic layer ZrO₂ attached on the ZSM-5 surface was characterized by means of X-ray diffraction, X-ray fluorescence and EXAFS. The ZrO₂ overlayer is suggested to epitaxially grow on the ZSM-5(001) plane in a [111] direction of tetragonal ZrO₂. The one-atomic layer ZrO₂/ZSM-5 is a unique catalyst which produces selectively isopentane from CH₃OH.     

Fate of herbicide CNP in rivers and agricultural drainages

The occurrence and fate of a herbicide CNP (2,4,6-trichlorophenyl-4′-nitrophenylether) in rivers and agricultural drainages was investigated. CNP residues in water samples were extracted by adsorption on a macroreticular XAD-2 resin column and subjected to gas chromatographic analysis using an electron capture detection after desorption from the column and concentration. The minimum detectable amount was 0.04 ng and a positive identification of CNP residue in water samples was obtained with a combined gas chromatography-mass spectrometry-computer system when 500 ng of CNP was injected. CNP residues were detected in water samples taken in June to September, and these levels were between 0.01 and 16.67 μg l⁻¹. The maximum level was found in a sample taken on 13th July, 1977, about a month after beginning rice seedling transplantation, and the minimum level was detected on August 29th, 1977. However CNP residue levels were increased again in September because flooded water on the paddy fields was excluded. CNP was more persistent in the aquatic environment than a herbicide benthiocarb.     

Occurrence,horizontal transfer and degeneration of VDE intein family in Saccharomycete yeasts

VDE is a homing endonuclease gene originally discovered as an intervening element in VMA1s of Saccharomyces cerevisiae. There have been two independent subfamilies of VDE, one from S. cerevisiae strain X2180-1A and the other from Saccharomyces sp. DH1-1A in the host VMA1 gene, and they share the identity of 96.3%. In order to search the occurrence, intra/interspecies transfer and molecular degeneration of VDE, complete sequences of VMA1 in 10 strains of S. cerevisiae, eight species of saccharomycete yeasts, Candida glabrata and Kluyveromyces lactis were determined. We found that six of 10 S. cerevisiae strains contain VDEs 99.7-100% identical to that of the strain X2180-1A, one has no VDE, whereas the other three harbour VDEs 100% identical to that of the strain DH1-1A. S. carlsbergensis has two VMA1s, one being 99.8% identical to that of the strain X2180-1A with VDE 100% identical to that of the strain DH1-1A and the other containing the same VMA1 in S. pastorianus with no VDE. This and other evidence indicates that intra/interspecies transmissions of VDEs have occurred among saccharomycete yeasts. Phylogenetic analyses of VMA1 and VDE suggest that the S. cerevisiae VDEs had branched earlier than other VDEs from an ancestral VDE and had invaded into the host loci as relatively late events. The two VDEs seemed to degenerate in individual host loci, retaining their splicing capacity intact. The degeneration of the endonuclease domains was distinct and, if compared, its apparent rate was much faster than that of the protein-splicing domains.     

Determination of captafol,cyhexatin, 1-naphthylacetic acid and quintozene in apple,Japanese pear and melon by simultaneous extraction

A simple and rapid method is described for the determination of the non-registered pesticides, captafol, quintozene (PCNB), cyhexatin and 1-naphthylacetic acid (NAA), in fruits. These pesticides were extracted with acidified acetone, then captafol and PCNB were purified with a Florisil mini column and analyzed by GC-ECD. Cyhexatin was ethylated with ethylmagnesium bromide, and the ethyl derivative was analyzed by GC-FPD (Sn filter). NAA was purified with liquid-liquid extraction and determined by HPLC equipped with a fluorescence detector. These analytes were identified with GC/MS or LC/MS. The minimum identified concentration of the pesticides was below 0.2 ng per injection, which corresponds to a detection limit of below 0.02 microgram/g in the original samples. Recoveries of the pesticides spiked at 0.1 microgram/g into apple, Japanese pear and melon were greater than 61%.     

Intracellular recovery of gold by microbial reduction of AuCl4 ions using the anaerobic bacterium Shewanella algae

Microbial reduction and intracellular precipitation of gold was achieved at 25 °C and pH 7 by using the mesophilic anaerobic bacterium Shewanella algae with H₂ as the electron donor. The reductive precipitation of gold by S. algae was a fast process: 0.1–1 mol/m³ AuCl₄⁻ ions were completely reduced to insoluble gold within 30 min. The biogenic precipitates were crystalline gold nanoparticles of 10–20 nm present in the periplasmic space. The reducing power of S. algae at 3.2 × 10¹⁵ cells/m³ and 25 °C was comparable to that of aqueous citric acid solution (chemical reductant) at 20 mol/m³ and 50 °C. The intracellular recovery of gold is potentially attractive as an environmentally friendly alternative to conventional methods.     

A feasible core design of lead bismuth eutectic cooled CANDLE fast reactor

Among the innovative reactor concepts, CANDLE has several advantages over conventional reactor designs. However, when CANDLE is extended to long life, the clad integrity at high neutron fluence, the build-up of fission product gases, and the pressure drop for long cores pose technological challenges which have to be overcome. In this paper, we propose practically viable design procedures, such as recladding the entire fuel pins and replacement of different amounts of fuel at different radial positions, to ensure clad integrity and flat power distribution, respectively. We demonstrate the efficacy of such design procedures by calculations that are performed on a LBE CANDLE reactor. Our calculations show that for a reactor operation period of 3700 days the various reactor parameters are within the limits proposed by Japan Atomic Energy Agency (JAEA).