全文获取类型
收费全文 | 1280篇 |
免费 | 37篇 |
国内免费 | 3篇 |
专业分类
电工技术 | 107篇 |
综合类 | 1篇 |
化学工业 | 384篇 |
金属工艺 | 21篇 |
机械仪表 | 29篇 |
建筑科学 | 28篇 |
能源动力 | 67篇 |
轻工业 | 111篇 |
石油天然气 | 2篇 |
无线电 | 89篇 |
一般工业技术 | 194篇 |
冶金工业 | 151篇 |
原子能技术 | 45篇 |
自动化技术 | 91篇 |
出版年
2023年 | 8篇 |
2022年 | 10篇 |
2021年 | 19篇 |
2020年 | 7篇 |
2019年 | 10篇 |
2018年 | 14篇 |
2017年 | 20篇 |
2016年 | 18篇 |
2015年 | 16篇 |
2014年 | 23篇 |
2013年 | 53篇 |
2012年 | 42篇 |
2011年 | 66篇 |
2010年 | 60篇 |
2009年 | 44篇 |
2008年 | 54篇 |
2007年 | 52篇 |
2006年 | 47篇 |
2005年 | 44篇 |
2004年 | 43篇 |
2003年 | 34篇 |
2002年 | 40篇 |
2001年 | 24篇 |
2000年 | 24篇 |
1999年 | 28篇 |
1998年 | 87篇 |
1997年 | 50篇 |
1996年 | 48篇 |
1995年 | 24篇 |
1994年 | 25篇 |
1993年 | 24篇 |
1992年 | 23篇 |
1991年 | 21篇 |
1990年 | 5篇 |
1989年 | 10篇 |
1988年 | 21篇 |
1987年 | 19篇 |
1986年 | 17篇 |
1985年 | 21篇 |
1984年 | 14篇 |
1983年 | 18篇 |
1982年 | 9篇 |
1981年 | 9篇 |
1980年 | 14篇 |
1979年 | 8篇 |
1978年 | 11篇 |
1977年 | 7篇 |
1976年 | 13篇 |
1975年 | 5篇 |
1974年 | 6篇 |
排序方式: 共有1320条查询结果,搜索用时 15 毫秒
61.
Pd(dibenzylideneacetone)2, when activated in situ with 1 equiv of [CPh3][B(C6F5)4] in the presence of 1 equiv of P(C6H11)3, efficiently catalyzed the addition polymerization and copolymerization of norbornene and its derivatives. Homopolymerization of 5-vinyl-2-norbornene took place regio-selectively with the endo-cyclic double bond to give high-molecular weight polymers, while the exocyclic double bond remained intact so that the resulting polymer had pendent vinyl groups along the polymer chain. In the polymerization of a mixture of the endo-/exo- isomers of 2-methoxycarbonyl-5-norbornene, the endo-isomer was consumed prior to consumption of the exo-isomer, contrary to the well-known tendency in Pd(II)-based catalyst systems. Another notable feature of the present catalytic system was the strong dependency of the molecular weight on the reaction temperature, which was studied in detail for the copolymerization of 2-methoxycarbonyl-5-norbornene with norbornene: we could control the molecular weight without the use of a chain transfer agent. The extracted oligomeric fraction of poly(norbornene) showed the presence of a terminal CC double bond as well as a C6F5 unit that was bound to the first norbornane unit in the polymer chain. 相似文献
62.
Yasuo Takagi Mitsuru Onoda Tamotsu Toriyama Katsunori Kawasaki Toshiyuki Hattori 《亚洲传热研究》2013,42(5):444-458
This study investigated the characteristics of cell performance degradation, decline of component performance, and changes in the properties of membrane electrode assembly materials caused by repeated cold starts under a subzero condition of ?30 °C. It was made clear that functional decay appeared mainly at the cathode due to increased proton conductive impedance and reduction of reactivity of the electrode catalyst. Among the cathode components, an increase in proton conductive impedance in the cathode electrolyte was dominant. Furthermore, the application of ion chromatography and a newly developed proton‐induced gamma‐ray emission method to measure fluorine in the off‐gas drain revealed that decomposition of the electrolyte was dominant in the cathode catalyst layer. A decrease in fluorine in the cathode electrolyte measured by fluorine‐19 nuclear magnetic resonance confirmed this decomposition. A hypothesis is also presented concerning the cause of the performance degradation. © 2012 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.20394 相似文献
63.
64.
KyoungHou Kim Ryo Aida YoungAh Kang Yutaka Ohkoshi Yasuo Gotoh Masanobu Nagura Hiroshi Urakawa 《Polymer》2009,50(19):4429-4431
The structure development in the continuous laser-heated drawing process of poly(ethylene 2,6-naphthalene dicarboxylate) (PEN) fiber was analyzed by in-situ X-ray diffraction measurement. Because of the rapid and uniform laser heating, and the resultant steady-state nature of the necking-drawing, the structure development after the on-set of necking could be measured in the time resolution of several hundred microseconds. We found for the first time the temporal appearance of meridional (001′) diffraction at several milliseconds after the on-set of necking indicating that the mesophase structure similar to the one reported for poly(ethylene terephthalate) was also formed in the initial stage of fiber structure development of PEN. The d-spacing of the (001′) diffraction 1.230 ± 0.003 nm was shorter than the c-axis lengths of both α and β crystals. 相似文献
65.
Nagase Hiroshi Matsuda Yasuo Ohnishi Kazuo Ninomiya Hisakazu Koike Toshio 《Industry Applications, IEEE Transactions on》1984,(6):1482-1489
A high-performance speed control system for cage induction motors is described which utilizes a PWM inverter. The effects of primary current coincidence and machine constant variation on system characteristics such as response time, torque precision, and operating noise were investigated. Based on the results obtained, new control methods have been devised; one varies the gain of the current controller in proportion to the primary frequency, and a second compensates for the slip frequency by using the deviation between the flux reference value and the actual value. Effectiveness of the compensation methods was confirmed in tests. 相似文献
66.
Deletion of Saccharomyces cerevisiae BIG1 causes an approximately 95% reduction in cell wall beta-1,6-glucan, an essential polymer involved in the cell wall attachment of many surface mannoproteins. The big1 deletion mutant grows very slowly, but growth can be enhanced if cells are given osmotic support. We have begun a cell biological and genetic analysis of its product. We demonstrate, using a Big1p-GFP fusion construct, that Big1p is an N-glycosylated integral membrane protein with a Type I topology that is located in the endoplasmic reticulum (ER). Some phenotypes of a big1Delta mutant resemble those of strains disrupted for KRE5, which encodes another ER protein affecting beta-l,6-glucan levels to a similar extent. In a big1Deltakre5Delta double mutant, both the growth and alkali-soluble beta-l,6-glucan levels were reduced as compared to either single mutant. Thus, while Big1p and Kre5p may have similar effects on beta-l,6-glucan synthesis, these effects are at least partially distinct. Residual beta-l,6-glucan levels in the big1Deltakre5Delta double mutant indicate that these gene products are unlikely to be beta-l,6-glucan synthase subunits, but rather may play some ancillary roles in beta-l,6-glucan synthase assembly or function, or in modifying proteins for attachment of beta-l,6-glucan. 相似文献
67.
68.
The local structure of trace amounts of lead in an adsorbent matrix that contains a high concentration of iron and magnesium (Mg6Fe2(OH)16(CO3) x 3H2O) was successfully monitored by means of X-ray absorption fine structure spectroscopy combined with fluorescence spectrometry. A eutectic mixture of PbCO3 and Pb(OH)2 coagulated when Pb2+ was adsorbed from a 1.0 ppm aqueous solution, and in contrast, the major species was ion-exchanged Pb2+ in the case of adsorption from a 100 ppb aqueous solution. The difference was ascribed to the balance between the precipitation equilibrium for coagulation and the rate of the ion exchange reaction with surface hydroxyl groups. 相似文献
69.
To improve the input-output coupling loss of a vertically coupled microring resonator filter, we fabricated microring resonators on an antiresonant reflecting optical waveguide (ARROW) with a large spot size and on the rectangular busline waveguide with a spot-size transformer. The spot size and the tapered structure were optimally designed from the viewpoint of spot-size matching to single-mode fibers and the reduction of radiation loss. Clear dropping responses were demonstrated for the ARROW-based microring resonator filters, and the coupling loss was successfully reduced by 22 dB. 相似文献
70.
Kameda Atsushi Yamamoto Masahito Uejima Hiroki Hagiya Masami Sakamoto Kensaku Ohuchi Azuma 《Natural computing》2005,4(2):103-126
In this paper, we propose a new architecture for a multi-state DNA machine whose conformation of repeated hairpin structures changes sequentially in response to input oligomers. As an application of the machine, we also propose molecular memory in which the machine is used as a memory unit. Addressing in the memory is realized through state transitions of the machine. We then describe a method for designing DNA sequences of the machine, which exhaustively checks conformational changes of the machine by dividing its secondary structure into hairpin units. The method is based on the minimum free energy of the structure, the structure transition paths, and the total frequency of optimal and suboptimal structures. DNA sequences designed by the method were tested in a chemical experiment in which a machine consisting of two hairpins was actually constructed. As a result, we verified that the multi-state DNA machine realized the expected changes in its secondary structure. 相似文献