Mesophase structure discovered through in-situ X-ray measurement in drawing process of poly(ethylene 2,6-naphthalene dicarboxylate) fiber

The structure development in the continuous laser-heated drawing process of poly(ethylene 2,6-naphthalene dicarboxylate) (PEN) fiber was analyzed by in-situ X-ray diffraction measurement. Because of the rapid and uniform laser heating, and the resultant steady-state nature of the necking-drawing, the structure development after the on-set of necking could be measured in the time resolution of several hundred microseconds. We found for the first time the temporal appearance of meridional (001′) diffraction at several milliseconds after the on-set of necking indicating that the mesophase structure similar to the one reported for poly(ethylene terephthalate) was also formed in the initial stage of fiber structure development of PEN. The d-spacing of the (001′) diffraction 1.230 ± 0.003 nm was shorter than the c-axis lengths of both α and β crystals.     

High-Performance Induction Motor Drive System Using a PWM Inverter

A high-performance speed control system for cage induction motors is described which utilizes a PWM inverter. The effects of primary current coincidence and machine constant variation on system characteristics such as response time, torque precision, and operating noise were investigated. Based on the results obtained, new control methods have been devised; one varies the gain of the current controller in proportion to the primary frequency, and a second compensates for the slip frequency by using the deviation between the flux reference value and the actual value. Effectiveness of the compensation methods was confirmed in tests.     

Molecular dynamics simulation of 〈<Emphasis Type="Bold">c</Emphasis>+<Emphasis Type="Bold">a</Emphasis>〉 dislocation core structure in hexagonal-close-packed metals

The core structures of 〈c+a〉 dislocations in hexagonal-close-packed (hcp) metals have been investigated by molecular dynamics (MD) simulation using a Lennard-Jones-type pair potential. The 〈c + a〉 edge dislocation has two types of core at 0 K; one is a perfect dislocation (type A), and the other has two 1/2 〈c+a〉 partials (type B). Type A transforms to type B by abruptly increasing temperature from 0 K to 293 K, while type B is stable in temperature range from 0 K to 293 K. In contrast, type A extends parallel to (0001) at 30 K, and this extended core is still stable at 293 K. These results suggest that the 〈c+a〉 edge dislocation glides on the {11 2} as two 1/2 〈c+a〉 partial dislocations and becomes sessile due to changes of the core structure. The 〈c+a〉 screw dislocation spreads over two {10 1} planes at 0 K. The core transforms into a unsymmetrical structure at 293 K, which is spread over {11 2} and {10 1}, and core spreading occurs parallel to {11 2} at 1000 K. A critical strain to move screw dislocations depends on the sense of shear strain. The dependence of the yield stress on the shear direction can be explained in terms of these core structures. This article is based on a presentation made in the symposium entitled “Defect Properties and Mechanical Behavior of HCP Metals and Alloys” at the TMS Annual Meeting, February 11–15, 2001, in New Orleans, Louisiana, under the auspices of the following ASM committees: Materials Science Critical Technology Sector, Structural Materials Division, Electronic, Magnetic & Photonic Materials Division, Chemistry & Physics of Materials Committee, Joint Nuclear Materials Committee, and Titanium Committee.     

X-ray absorption fine structure combined with fluorescence spectrometry for monitoring trace amounts of lead adsorption in the environmental conditions

The local structure of trace amounts of lead in an adsorbent matrix that contains a high concentration of iron and magnesium (Mg6Fe2(OH)16(CO3) x 3H2O) was successfully monitored by means of X-ray absorption fine structure spectroscopy combined with fluorescence spectrometry. A eutectic mixture of PbCO3 and Pb(OH)2 coagulated when Pb2+ was adsorbed from a 1.0 ppm aqueous solution, and in contrast, the major species was ion-exchanged Pb2+ in the case of adsorption from a 100 ppb aqueous solution. The difference was ascribed to the balance between the precipitation equilibrium for coagulation and the rate of the ion exchange reaction with surface hydroxyl groups.     

Coupling-loss reduction of a vertically coupled microring resonator filter by spot-size-matched busline waveguides

To improve the input-output coupling loss of a vertically coupled microring resonator filter, we fabricated microring resonators on an antiresonant reflecting optical waveguide (ARROW) with a large spot size and on the rectangular busline waveguide with a spot-size transformer. The spot size and the tapered structure were optimally designed from the viewpoint of spot-size matching to single-mode fibers and the reduction of radiation loss. Clear dropping responses were demonstrated for the ARROW-based microring resonator filters, and the coupling loss was successfully reduced by 22 dB.     

Positron annihilation lifetime study of vapor sorption in polypropylene and polytetrafluoroethylene

Positron annihilation lifetime (PAL) spectra were measured for two different kinds of polymers: polypropylene (PP) and polytetrafluoroethylene (PTFE), during sorption of vapors of the following molecules: n-hexane, cyclohexane, benzene, methyl methacrylate, acrylic acid, and water. The behavior of ortho-positronium (o-Ps) annihilation parameters: lifetime, τ₃, and intensity, I₃, can be explained by considering different sorption mechanisms in rubbery and glassy polymers. The mean size of the intermolecular-space holes and the relative free-volume fraction of PP and PTFE were estimated before and during the sorption process from the o-Ps parameters obtained. Sorption of n-hexane, cyclohexane, and benzene in both polymers affect the o-Ps component in a systematic way, for PP τ₃ and I₃ tend to decrease, while in PTFE, τ₃ stay almost constant and I₃ diminishes. These effects are interpreted in relation to the different states of the polymers studied: rubbery for PP and glassy for PTFE. In case of methyl methacrylate molecules, the behavior of o-Ps parameters was more complicated. For acrylic acid and water, their associated polarity provokes a diminution in I₃, which is explained from the viewpoint of the spur model of positronium formation. Large changes in the mean size and the fraction of free volume, as well as their constant behavior in some cases, were interpreted to be due to positive or negative interactions, respectively, between vapor molecules and PP and PTFE, which could be correlated with the solvent-interaction parameters calculated. © 1995 John Wiley & Sons, Inc.