Experimental and numerical analysis of channel-length-dependent electrical properties in bottom-gate,bottom-contact organic thin-film transistors with Schottky contact

Channel length dependence of field-effect mobility and source/drain parasitic resistance in pentacene thin-film transistors with a bottom-gate, bottom-contact configuration was investigated. Schottky barrier effect such as nonlinear behaviors in transistor output characteristics appeared and became more prominent for shorter channel length less than 10 μm, raising some concerns for a simple utilization of conventional parameter extraction methods. Therefore the gate-voltage-dependent hole mobility and the source/drain parasitic resistance in the pentacene transistors were evaluated with the aid of device simulation accounting for Schottky contact with a thermionic field emission model. The hole mobility in the channel region shows smaller values with shorter channel length even after removing the influence of Schottky barrier, suggesting that some disordered semiconductor layers with low carrier mobility exist near the contact electrode. This experimental data analysis with the simulation enables us to discuss and understand in detail the operation mechanism of bottom-gate, bottom-contact transistors by considering properly each process of charge carrier injection, carrier flow near the contact region, and actual channel transport.     

Improvement of Electrical Contact Between TE Material and Ni Electrode Interfaces by Application of a Buffer Layer

A single ??-structure thermoelectric (TE) module based on p-type NaCo₂O₄, n-type Mg₂Si, and Ni electrode was fabricated by the spark plasma sintering (SPS) method. The NaCo₂O₄ powder was synthesized by using a metal?Ccitric acid complex decomposition method. Bulk Mg₂Si prepared by melt quenching was ground into a powder and sieved to particle size of 75???m or less. To obtain a sintered body of NaCo₂O₄ or Mg₂Si, the powder was sintered using SPS. Pressed Ni powder or mixed powder consisting of Ni and SrRuO₃ powder was inserted between these materials and the Ni electrode in order to connect them, and electrical power was passed through the electrodes from the SPS equipment. The open-circuit voltage (V _OC) values of a single module in which TE materials were connected to the Ni electrodes by using pressed Ni powder was 82.7?mV, and the maximum output current (I _max) and maximum output power (P _max) were 212.4?mA and 6.65?mW at ??T?=?470?K, respectively. On the other hand, V _OC of a single module in which TE materials and an Ni electrode were connected with a mixed powder (Ni:SrRuO₃?=?6:4 volume fraction) was 109?mV, and I _max and P _max were 4034?mA and 109?mW at ??T?=?500?K, respectively. These results indicate that the resistance at the interface between the TE materials and the Ni electrode can be decreased and the output power can be increased by application of a buffer layer consisting of Ni and SrRuO₃.     

Source-Field Relationships for Cardiac Generators on the Heart Surface Based on Their Transfer Coefficients

We consider three different types of equivalent sources over a closed surface enclosing all the electrical cardiac generators: the (in situ) potential, the (in situ) normal current density, and the (macroscopic) transmembrane potential on the heart surface. The last equivalent source, which behaves as a double layer, is derived from the bidomain (bisyncytia) model for anisotropic cardiac muscle. This model predicts that if ratios of intracellular to interstitial conductivity along all directions are equal, field potential can be calculated only using surface integrals. The volume integral arising from the tissue anisotropy of cardiac muscle vanishes in that case. For each type of source under study, we give the field potential in a bounded inhomogeneous volume conductor in the form of an integral equation. We also derive the conditions which the lead field (or the transfer coefficients) must satisfy. The in situ potential and normal current are related to the cardiac sources in a complex way, but their lead fields are independent of conductivity of heart muscle, whereas the transmembrane potential is directly involved as a source term, but the lead field depends on the anisotropy of the heart muscle.     

Heat capacities and thermal conductivities of AmO2 and AmO1.5

The thermal diffusivity of AmO₂ was measured from 473 to 773 K and that of AmO_1.5 between 473 and 1373 K using a laser flash method. The enthalpy increment of AmO₂ was measured from 335 to 1081 K and that of AmO_1.5 between 335 and 1086 K using drop calorimetry. The heat capacities of AmO₂ and AmO_1.5 were derived from the enthalpy increment measurements. The thermal conductivity was determined from the measured thermal diffusivity, heat capacity and bulk density. The heat capacities of AmO₂ was found larger than that of AmO_1.5. The thermal conductivities of AmO₂ and AmO_1.5 were found to decrease with increasing temperature in the investigated temperature range. The thermal conductivity of AmO_1.5 with A-type hexagonal structure was smaller than that of AmO₂ with C-type fluorite structure but larger than that of sub-stoichiometric AmO_1.73.     

Apatite crystal in hard tissue of conodont fossils

The present study was aimed at examining the nature of apatite crystal in the tooth apparatus of a conodont fossil using transmission electron microscopy (TEM), scanning electron microscopy (SEM), laser Raman microprobe spectrometry and electron-probe microanalysis (EPMA). The hard tissue of the condont consisted of 2 layers and the organization varied with the size of the crystal. Higher magnification showed that the crystals were observed in the lattice of (100) and the central dark lines were not present. Ca, P, and F were detected in the crystal using EPMA. Our results indicate that the apatite crystal in conodont fossils is not hydroxyapatite but fluorapatite.     

Mesophase structure discovered through in-situ X-ray measurement in drawing process of poly(ethylene 2,6-naphthalene dicarboxylate) fiber

The structure development in the continuous laser-heated drawing process of poly(ethylene 2,6-naphthalene dicarboxylate) (PEN) fiber was analyzed by in-situ X-ray diffraction measurement. Because of the rapid and uniform laser heating, and the resultant steady-state nature of the necking-drawing, the structure development after the on-set of necking could be measured in the time resolution of several hundred microseconds. We found for the first time the temporal appearance of meridional (001′) diffraction at several milliseconds after the on-set of necking indicating that the mesophase structure similar to the one reported for poly(ethylene terephthalate) was also formed in the initial stage of fiber structure development of PEN. The d-spacing of the (001′) diffraction 1.230 ± 0.003 nm was shorter than the c-axis lengths of both α and β crystals.     

Heat capacities of NpN and AmN

The heat capacities of NpN and AmN were determined with the drop calorimetry method. The NpN and AmN samples were prepared by the carbothermic reduction of the respective dioxides. The heat capacity of NpN obtained was in good agreement with the reported values in the temperature range from 334 to 1067 K, which was close to those of UN and PuN. The heat capacity of AmN was obtained experimentally for the first time, which was slightly smaller than those of UN, NpN and PuN in the temperature range from 354 to 1071 K.