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11.
H. Kakiuchi H. Ohmi M. Harada H. Watanabe K. Yasutake 《Science and Technology of Advanced Materials》2007,8(3):137-141
The formation of silicon dioxide (SiO2) layers at low temperatures (150-400 °C) by atmospheric pressure plasma oxidation of Si(0 0 1) wafers have been studied using a gas mixture containing He and O2. A 150 MHz very high frequency (VHF) power supply was used to generate high-density atomic oxygen in the atmospheric pressure plasma. Oxidation rate, structure, and thickness and refractive index profiles of the oxidized layers were investigated by ellipsometry and infrared absorption spectroscopy. Atomic force microscopy was also employed to observe atomic-scale morphologies of the layer surface and wafer Si surface, after chemical removal of the oxidized layers. It was found that stoichiometric SiO2 layers were obtained at higher oxidation rates than conventional dry O2 thermal oxidation and radical oxidation processes, even at a very low substrate temperature of 150 °C. Although thickness variations were observed in the plasma region, the refractive index was independent of both substrate temperature and VHF power. In addition, the SiO2 surface and SiO2/Si interface roughnesses were comparable to those obtained in conventional dry oxidation at high temperatures. 相似文献
12.
The single molecular orientation switching of the Tb@C82 endohedral metallofullerene has been studied by using low-temperature ultrahigh vacuum (UHV) scanning tunneling microscopy (STM). An octanethiol self-assembled monolayer (SAM) was introduced between Tb@C82 and the Au111 substrate to control the thermal rotational states of Tb@C82. Scanning tunneling spectroscopy (STS) of Tb@C82 on an octanethiol SAM at 13 K demonstrated hysteresis including negative differential conductance (NDC). This observed hysteresis and NDC is interpreted in terms of a switching of the Tb@C82 molecular orientation caused by the interaction between its electric dipole moment and an external electric field. 相似文献
13.
Dr. Yoshiaki Yasutake Dr. Taiki Nishioka Dr. Noriko Imoto Prof. Tomohiro Tamura 《Chembiochem : a European journal of chemical biology》2013,14(17):2284-2291
Vitamin D3 hydroxylase (Vdh) from Pseudonocardia autotrophica is a cytochrome P450 monooxygenase that catalyzes the two‐step hydroxylation of vitamin D3 (VD3) to produce 25‐hydroxyvitamin D3 (25(OH)VD3) and 1α,25‐dihydroxyvitamin D3 (1α,25(OH)2VD3). These hydroxylated forms of VD3 are useful as pharmaceuticals for the treatment of conditions associated with VD3 deficiency and VD3 metabolic disorder. Herein, we describe the creation of a highly active T107A mutant of Vdh by engineering the putative ferredoxin‐binding site. Crystallographic and kinetic analyses indicate that the T107A mutation results in conformational change from an open to a closed state, thereby increasing the binding affinity with ferredoxin. We also report the efficient biocatalytic synthesis of 25(OH)VD3, a promising intermediate for the synthesis of various hydroxylated VD3 derivatives, by using nisin‐treated Rhodococcus erythropolis cells containing VdhT107A. The gene‐expression cassette encoding Bacillus megaterium glucose dehydrogenase‐IV was inserted into the R. erythropolis chromosome and expressed to avoid exhaustion of NADH in a cytoplasm during bioconversion. As a result, approximately 573 μg mL?1 25(OH)VD3 was successfully produced by a 2 h bioconversion. 相似文献
14.
T Honda K Yasutake N Nihonmatsu M Mercken H Takahashi O Murayama M Murayama K Sato A Omori S Tsubuki TC Saido A Takashima 《Canadian Metallurgical Quarterly》1999,72(1):255-261
Presenilin 1 (PS1) has been identified as a causative gene for most early-onset familial Alzheimer's disease. Biochemical studies revealed that PS1 exists predominantly as two processed fragments in cells and brain tissues. We prepared stably transfected cells expressing the wild-type and familial Alzheimer's disease-associated mutants of PS1 and investigated the enzyme that participates in the metabolism of PS1. After treatment of the cells with proteasome inhibitors, the full-length PS1 was significantly accumulated. The levels of N- and C-terminal fragments were also increased. The accumulation of PS1 with a deletion of exon 10, which is unable to be processed, on treatment of the transfected cells with lactacystin indicated that proteasome can degrade full-length PS1. A synthetic peptide that includes the processing region of PS1 was cleaved by 20S proteasome at the putative processing sites after Met288 and Glu299. Metabolic labeling experiments showed that the appearance of the N-terminal fragment was attenuated by the inhibitor. Finally, 28-kDa N- and 20-kDa C-terminal fragments were generated by purified PS1 in vitro. These data indicated that the proteasome pathway is involved in PS1 processing. These results demonstrate that the proteasome pathway plays dual roles in processing and degradation of PS1. 相似文献
15.
16.
We have prepared a trial oxide thermal rectifier made of two cobalt oxides with different thermal conductivities based on
a theoretical design. We created an experimental system to measure the thermal rectification and found that the rectifying
coefficient defined by the ratio of heat current in a forward direction to that in the opposite direction was 1.43. We verified
the thermal rectification by analyzing it quantitatively. 相似文献
17.
Koji Matsumoto Kazuki Sakae Hirofumi Yamauchi Yoshikazu Teraoka 《International Journal of Refrigeration》2008,31(5):832-840
This study focused ice slurry formation in an ice storage system using W/O emulsions with 70 and 80% water contents. Emulsions consisted of a silicone oil–water mixture with a small amount of amino-group-modified silicone oil additive. Ice slurry was formed by cooling the emulsion without ice adhesion to the cooling wall, as water in the emulsion did not directly contact the cooling wall. As the structure of W/O emulsion slowed the propagation rate of supercooling dissolution, voltage and ultrasonic wave were applied to the W/O emulsion to propagate dissolution more quickly and decrease maximum supercooling degree, respectively. Thus, the effects of voltage and ultrasonic wave applications on propagation rate were clarified. 相似文献
18.
Masahiro Nagae Yasunori Koyama Seita Yasutake Tetsuo Yoshio Kohei Oda 《Journal of the American Ceramic Society》2006,89(11):3550-3553
The corrosion behavior of sialon ceramics was investigated in supercritical water at 450°C under 45 MPa for 2–50 h. α-sialon exhibited better corrosion resistance than β-sialon and α/β-sialon. Pitting corrosion with the formation of corrosion products was observed in the case of β-sialon and α/β-sialon. By contrast, the corrosion behavior of α-sialon was characterized by uniform corrosion with the formation of corrosion products. The degree of strength deterioration was strongly dependent on the corrosion morphology. The bending strength of α-sialon after corrosion for 30 h was about 90% of its initial strength, while the strength of β-sialon decreased to 65% of its original strength. 相似文献
19.
Dean LeeIwao Teraoka 《Polymer》2002,43(9):2691-2697
Samples of poly(ethylene glycol) especially those with functionalized ends have dimeric, trimeric, and tetrameric components at twice, three times, and four times as high a molecular weight (MW) as that of the main component. We used two-dimensional column chromatography to evaluate the MW and identify the terminal groups in each component. The first step is high osmotic pressure chromatography to prepare a sufficient amount of fractions that contain different percentages of the multimeric components. In the second step, each of the fractions was characterized by using regular size exclusion chromatography and high-resolution NMR. Decomposition of the chromatogram combined with isolation of the terminal methoxy peak in the NMR spectrum led to unique identification of the terminal groups. We thus found that the monomeric component is monomethoxy-terminated whereas the dimeric and other multimeric components are mostly dihydroxy-terminated. 相似文献
20.
Yasutake Teraoka Hiroshi Ogawa Hiroshi Furukawa Shuichi Kagawa 《Catalysis Letters》1992,12(4):361-366
The coexistence of alkaline earth (Ca and Sr) and transition metal (Fe, Co and Ni) cations with Cu ions in ZSM-5 zeolite is effective in the promotion of the maximum activity and the expansion of the active temperature range for the reduction of nitric oxide with ethene in the presence of excess oxygen. 相似文献