聚氨酯/聚丙烯酸酯复合乳液的研制进展

综述了近年来聚氨酯－丙烯酸酯（PUA）复合乳液研究的新进展，总结介绍了各类聚氨酯－聚丙烯酸酯复合乳液（PUA共混复合乳液、PUA复合核／壳乳液、互穿网络PUA复合乳液）的制备方法和性能特点。并对该领域进一步的发展作了展望。     

气相色谱法测定油墨中的六种溶剂

本文报道了用气相色谱法同时测定油墨中的正丁醇、丁酮、甲苯、乙酸丁酯、二甲苯、环己酮，这方法具有良好的精密度、回收率和线性关系，测定了四种油墨所含的溶剂。     

Relationships Between the Crystal Structures and the Multiple Melting Behaviors of Poly(ethylene 2,6‐naphthalate)

Summary: Poly(ethylene 2,6‐naphthalate) (PEN) can crystallize either from the glassy state or from the melt state. When crystallized from the glassy state, the sample was quenched from the melt in liquid nitrogen and then annealed at certain crystallization temperatures. When crystallized from the melt state, the sample was cooled to a preset temperature from the melt and then annealed for a certain time. The crystal modifications, morphologies and melting behaviors of PEN were investigated by means of wide‐angle X‐ray diffraction (WAXD), polarized optical microscopy (POM), small‐angle light scattering (SALS) and differential scanning calorimetry (DSC). The results show that an α crystal modification of PEN was obtained when PEN crystallized from the glassy state, whilst a β crystal modification was obtained when PEN crystallized from the melt state at a higher temperature. An hedritic morphology of PEN crystal was obtained with only one melting peak observed in DSC curves when PEN was crystallized at a higher temperature from either the glassy state or the melt state. The α crystal modification could also be obtained when PEN was crystallized at a lower temperature from the melt. Spherulitic or banded spherulitic morphologies of PEN crystals, exhibiting multiple melting peaks in DSC curves, were observed when PEN was crystallized at a lower temperature. The multiple melting behaviors of PEN crystals may be associated with spherulitic structures composed of lamellae of varying thickness.

WAXD patterns of PEN isothermally crystallized from different states.     

微晶纤维素增粘剂的研制

以棉浆为原料，废盐酸为水解催化剂，所得合成革用微晶纤锥素增粘剂的质量指标达到了德国和日本同类产品的标准。     

Study of different effect on foaming process of biodegradable bionolle in supercritical carbon dioxide

Microcellular foaming of biodegradable Bionolle in supercritical CO₂ has been produced. The effects of a series of variable factors, such as saturation temperature, saturation pressure, and depressurization time and step on the foam structures and density, were studied through measurement of density and SEM observation. The experimental results show that higher saturation temperatures lead to an increase in bulk densities; and different depressurization time and step result in different product cell morphology. In addition, at some saturation temperature, the orientation of the cells can be found in the product morphology. XRD experimental results show that the foaming treatment with SC CO₂ increased the crystallinity of Bionolle. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2901–2906, 2006     

我国烟草品牌延伸策略初探

随着<烟草控制框架公约>在我国的正式实施,烟草品牌的宣传将受到更大的制约,品牌延伸因此将成为烟草品牌发展路径的重要选择.论述了烟草行业实行品牌发展及品牌延伸策略的必要性,阐述了烟草品牌延伸的误区,提出了烟草品牌延伸的对策.     

四氯化硅的应用现状研究

综述了四氯化硅的主要处理方法和应用研究进展。详细介绍了四氯化硅在制备二氧化硅、多晶硅、三氯硅烷及其他硅烷产品方面的应用及其制备原理,并对各制备工艺技术进行了分析。     

反旋向多漩流器阵列燃烧室流场的数值研究

采用雷诺应力模型(RSTM)对于反旋向多漩流器阵列贫油直喷(LDI)燃烧室的非反应冷态流场进行了数值模拟.研究中采用了一种3×3的漩流器阵列结构,相邻漩流器的旋向交替变化.计算结果表明,所研究的燃烧室流场结构十分复杂.由于相邻漩流器之间对于漩流的强化作用,因而各回流区维持了较长的长度.流场中存在的多个回流区及强湍流表明该燃烧室有潜力实现良好的燃烧性能.通过将雷诺应力模型的模拟结果与LDV实验数据进行比较发现,计算结果与实验值符合良好,说明雷诺应力模型较好地求解了回流区和高速度梯度问题.     

敏感性问题的一种调查方法

基于调查数量特征的敏感性问题的随机变量乘法模型提出了一种改进模型,该模型比随机变量乘法模型有着更高的精度．由此,将此改进模型推广到最优分配下的分层抽样情形,在总体适合分层时,能提高总体估计量的估计精度;另外,由于在不同层中可以使用不同的随机化装置,这在实际的调查操作中有着更强的可行性．     

IECM模型在燃煤电站汞污染控制及经济性预测中的应用

对现有电站污染物控制装置基础上进行技术改造,协同实现汞污染控制是行之有效的技术方案,汞污染控制系统的技术经济性评估是燃煤电站管理者面临的首要问题.用Integrated Environmental Control Modeling(IECM)软件模拟了温度、煤种及空气污染控制装置的配置对活性炭吸附电站燃煤烟气汞效果的影响,并对不同条件下,活性炭的喷射量进行了模拟和经济性分析.结果表明活性炭捕获汞的效果是与排烟温度成反比的.对于燃烧烟煤的电厂,加入烟气脱硫装置(FGD)后活性炭的喷射量将大大减少,再结合选择性催化还原装置(SCR)后,可以达到很高的汞脱除效果;对于无烟煤和褐煤,加入烟气脱硫装置(FGD)可减少约27%的活性炭喷射量,但再加入催化还原装置(SCR)后,对活性炭的注入量几乎没有影响.