等离子体湮没离子注入

本文扼要地介绍了等离子体湮没离子注入的基本原理，特点，应用效果及发展趋向。     

Intermediate temperature solid oxide fuel cell based on fully integrated plasma-sprayed components

This work addresses the fabrication of membrane-type solid oxide fuel cells (SOFCs) operating at medium temperatures, where all components are fabricated by plasma spray technology, and the evaluation of the performance of the SOFC single unit in a temperature range of 500 to 800 °C. Single cells composed of LaSrMgO₃ cathodes, LaSrGaMgO₃ (LSGM) electrolytes, and Ni/yttria-stabilized zirconia anodes were fabricated in successive atmospheric plasma-spraying processes. Plasma-spraying processes have been optimized and tailored to each layer to achieve highly porous cathode and anode layers as well as high-density electrolyte layers. A major effort has been devoted to the production of the LSGM electrolyte that has a high density and is free of cracks. Electrochemical impedance spectroscopy was used to investigate the conductivity of the electrode layers, and particularly the resistance of the electrolyte layer. It revealed that the heat treatment had a great influence on the specific conductivity of the sprayed electrolyte layers and that the specific conductivity of the heat-treated layers was dramatically increased to the same magnitude as is typical for sintered LSGM pellets. The experimental results have demonstrated that the plasma-spraying process has a great potential for the integrated fabrication of medium-temperature SOFC units. The original version of this article was published as part of the ASM Proceedings, Thermal Spray 2003: Advancing the Science and Applying the Technology, International Thermal Spray Conference (Orlando, FL), May 5–8, 2003, Basil R. Marple and Christian Moreau, Ed., ASM International, 2003.     

铟锡氧化物靶材的应用及管状靶材的爆炸成形

铟在自然界是稀散金属，其氧化物具有许多优异的性能，合理利用铟资源的重要途径之一是生产铟锡氧化物（ＩＴＯ）靶材，介绍了ＩＴＯ靶材的应用领域，分析了平面ＩＴＯ靶材与管状ＩＴＯ靶材的特点，提出了ＩＴＯ管状靶材的爆炸成形技术，与现有成形技术相比，爆炸成形工艺特别适用于管状靶材成形，对制粉的要求将降低，不丧失粉末的优良性质，通过爆炸成形工艺的分析可知，适当控制状飞片厚度，飞行距离，爆速，炸药厚度并与粉末材料     

添加WC对镍基合金激光熔敷层硬度及腐蚀磨损行为的影响

探讨了添加ＷＣ的镍基合金Ｇ１１２激光熔敷层的性能，结果表明，添加２０％ＷＣ的激光熔敷层的硬度ＨＶ０．２比末添加的提高近一倍，在酸性介质中的耐蚀性有所降低，但腐蚀磨损性能却得到大改善，其腐蚀磨损机制在低冲击速度下，由犁削磨损，坑穴腐蚀及应力腐蚀变为犁削磨损为主，在高冲击速度下，两者的腐蚀磨损机制趋于一致，均为犁削磨损为主，伴以抗穴腐蚀及应力腐蚀。     

电流密度对声电沉积生物活性透钙磷石涂层结构和形貌的影响

通过声电沉积工艺在碳／碳复合材料表面制备了生物活性透钙磷石涂层，采用SEM、FFIR、XRD研究了超声场中电流密度对涂层组成结构和形貌的影响。发现在一定工艺条件下，随电流密度增加，涂层的平均晶粒尺寸减小，致密度增加；当电流密度小于l0mA／cm^2时涂层形貌为片状，l0mA／cm^2-26mA／cm^2时为粒状，32mA／cm^2时为花菜心状。且涂层中透钙磷石晶体的择优取向也发生变化，择优晶面依次为(021)、(111)、(220)。同时还讨论了涂层微观结构变化机理。     

矿岩粉碎全过程能耗-粒度关系的连续损伤理论研究SCIEI

本文从连续损伤理论的观点出发,将矿岩粉碎过程描述为在外部荷载作用下矿岩颗粒内部微缺陷(损伤)演化和繁衍的过程。导出了粉碎能耗与产品粒度分布的理论表达式。该式包含了所有传统的理论,同时较传统的能量分配观点前进了一步。     

锻造质量对冷挤压模具寿命的影响

通过改变锻造方法，观察金相组织及模具现场试用，探讨锻造质量对高速钢及基体钢模具寿命的影响，结果表明：控制碳化物不均匀性在三级以内及合理的纤维流线分布，可显著提高引进冷挤压设备上的模具寿命。     

Kinetic and spectral aspects in chemiluminescence system Eu(III)/HCO3/H2O2

Chemiluminescence (CL) of the systems containing Eu₂⁺ or HCO₃⁻ ions and hydrogen peroxide was studied. The kinetic curves and CL emission spectra of the systems were discussed. The emission spectrum of the system containing carbonates revealed two emission maxima: the first directly after initiation of the reaction by hydrogen peroxide and the second in several seconds after the first. On the basis of the characteristic bands in the CL spectrum the emitters in the system Eu₂⁺/HCO₃⁻/H₂O₂ were identified as: excited Eu³⁺ ions and excited products of carbonate decomposition. The emission bands for λ=600 and 420 nm appeared in a time distance of a few ten seconds.     

银纪念币的腐蚀变色研究

银纪念币在大气环境中表面发生变色，失去原有的金属光泽。采用OM，SEM，EMPA，XPS，XRD等现代物理测试技术对变色的银纪念币进行分析。结果表明，银纪念币的变色部位呈均匀的浅褐色，并随机分布着深褐色的斑点。变色银纪念币表面沿着划痕密集分布着蚀孔。表面分析显示，除Ag外，还有S和O元素。XPS，XRD分析发现，变色银纪念币表面存在Ag2S，Ag2SO3和Ag2O。实验室加速变色试验毒明，在含S气体环境中，Ag被氧化生成A82S，导致银纪念币表面变色,从而验证银纪念币的变色是由电化学腐蚀引起的，S和O元素参与了腐蚀历程。