Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent

A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO₄-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P₂O₅-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO₄-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO₄-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn₃(PO₄)₂ · 4H₂O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO₄-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C).     

C语言学习方法与实践的探讨

针对C语言程序设计课程本身的特点，分析学习过程中存在的问题，强调实践的必要性。结合一些学校课程改革和实践的经验．提出面向应用的，科学的学习内容、方法和模式。同时提高学习者的专业动手能力。     

状如琼，凝为脂

在我们喝的饮料粒粒橙中，为什么那些细小的橙子颗粒是悬浮在橙汁中的呢？果冻和布丁为什么是透明，且柔软有弹性的呢？去看看成分表，我们不难发现共同之处，看似不同的食品都添加了一种共同的成分——琼脂。[编者按]     

厦门市筼筜湖城市防汛排涝现状及其对策

本文通过分析筼筜湖的自然概况、防汛排涝系统设施及实际运行等资料,提出进一步提高筼筜湖防汛排涝能力的对策。     

A 3-D Enlarged Cell Technique (ECT) for the Conformal FDTD Method

In this paper, we present an enlarged cell technique (ECT) to avoid the time step reduction encountered in the conformal finite-difference time-domain (CFDTD) method due to small irregular cells truncated by metallic boundaries. We focus our efforts on the discussion of the accuracy and stability of the ECT and its comparison with other conformal methods, especially the one called the uniformly stable conformal (USC) method. We also provide a simplified ECT, which is much easier to implement. In the ECT, a stability criterion is first constructed to identify instable irregular cells, i.e., those having so small an area to cause instability. Those instable cells are then enlarged into their adjacent cells to obtain a large, stable area. Careful treatment is performed on the communication between the intruding and intruded cells in terms of electromotive force by keeping the total electromotive force conservative. This technique is verified by several 3-D numerical experiments. Results show that the ECT is second-order accurate and numerically stable at the regular Courant time step limit.     

裂齿矩形翅片板翅式换热器优化设计的分析

对裂齿矩形翅片板翅式换热器中的裂齿矩形翅片的传热效率作了分析,并以单位质量材耗的换热能力最大为目标函数,分析研究了在不同雷诺数(Re)的操作条件下裂齿矩形翅片间角度、翅片厚、长度、宽度及极厚之间的关系。结果表明:在气体换热的场合下,当Re在某一范围时翅片可有效地起到强化传热的作用。当板厚为5mm,翅片厚为3mm,翅片间夹角为45°～70°,Re为2×10~3～8×10~3,最佳翅片纵向间距与翅片长度和翅片厚度乘积的平方根的比为1.5～2.5,最佳翅片尺寸系数为3～5时,传热强化效果较好。     

无纸化建造

本文通过分析先锋建筑师借鉴汽车制造领域的无纸化技术进行的建造实践,揭示了无纸化建造的操作过程,并探讨了无纸化建造的意义,那就是无纸化不仅改变了传统的设计方法,而且改变了传统的建造方式,这将是人类的建造技术发展史上的一场伟大的变革.文章最后探讨了无纸化建造在中国的实践意义.     

Effects of Y and Ce on Microstructures and Properties of Nb-Si System Composites

The effects of yttrium and cerium on microstructures and properties of Nb-Si system composites were investigated by scanning electron microscopy( SEM), energy dispersive spectrum(EDS), X-ray diffraction(XRD) and high temperature oxidation experiments.It is found that the coarse primary silicide phase became finer and more homogeneous with Y and Ce addition.The results of high temperature oxidation experiments show that the oxidation rates of NbSi system composites with an appropriate amount of Y and Ce decrease compared with those of alloys without Y or Ce addition, and oxidation products mainly distribute along the phase boundaries between the Nb solid solution and silicide.     

稀土改善09CuPTiRE耐候钢耐蚀性的作用机理

应用扫描电镜(SEM)、离子探针(IMA)、X射线光电子能谱(XPS)和交流阻抗法研究含不同稀土耐候钢稀土提高耐大气腐蚀作用机理。结果表明,合适的稀土含量可显著提高钢的耐腐蚀性,稀土能促进Si、Cu和P在内锈层中以Si~(4+)、Cu~+和P~(5+)形态富集,并观察到锈层中的稀土。钢中加入稀土形成了致密连续厚而粘附性好的含硅铜稀土的复合铁锈层,从而提高了抗大气腐蚀性能。     

A distributed adverse drug reaction detection system using intelligent agents with a fuzzy recognition‐primed decision model

Discovering unknown adverse drug reactions (ADRs) in postmarketing surveillance as early as possible is highly desirable. Nevertheless, current postmarketing surveillance methods largely rely on spontaneous reports that suffer from serious underreporting, latency, and inconsistent reporting. Thus these methods are not ideal for rapidly identifying rare ADRs. The multiagent systems paradigm is an emerging and effective approach to tackling distributed problems, especially when data sources and knowledge are geographically located in different places and coordination and collaboration are necessary for decision making. In this article, we propose an active, multiagent framework for early detection of ADRs by utilizing electronic patient data distributed across many different sources and locations. In this framework, intelligent agents assist a team of experts based on the well‐known human decision‐making model called Recognition‐Primed Decision (RPD). We generalize the RPD model to a fuzzy RPD model and utilize fuzzy logic technology to not only represent, interpret, and compute imprecise and subjective cues that are commonly encountered in the ADR problem but also to retrieve prior experiences by evaluating the extent of matching between the current situation and a past experience. We describe our preliminary multiagent system design and illustrate its potential benefits for assisting expert teams in early detection of previously unknown ADRs. © 2007 Wiley Periodicals, Inc. Int J Int Syst 22: 827–845, 2007.