超支化聚合物在功能材料中的应用

超支化聚合物由于具有高度支化的三维结构以及众多的端基,显示出与相应线型分子截然不同的性质。对超支化聚合物及其在纳米材料、发光材料、特种涂料等功能材料方面的应用做了介绍,显示出其所具有的广阔应用前景。     

反应性乳化剂应用于丙烯酸酯类乳液压敏胶的研制

使用正交试验法设计压敏胶配方,得到用反应性乳化剂参与的AA、HEA、BA和EA、M AA等多元共聚物乳液,研究该聚合物应用于压敏胶的初粘、持粘、剥离强度等力学性能。结果表明,在该体系下引发剂用量、反应温度、AA、反应性乳化剂用量对压敏胶乳液综合性能关系密切,其它各因素影响不明显。得到的优化配方为BA(83%)、AA(1%)、HEA(1%)、MM A和EA的混合单体(15%)。     

Crystallization behavior of carbon nanotubes‐filled polyamide 1010

The nanocomposites of polyamide1010 (PA1010) filled with carbon nanotubes (CNTs) were prepared by melt mixing techniques. The isothermal melt‐crystallization kinetics and nonisothermal crystallization behavior of CNTs/PA1010 nanocomposites were investigated by differential scanning calorimetry. The peak temperature, melting point, half‐time of crystallization, enthalpy of crystallization, etc. were measured. Two stages of crystallization are observed, including primary crystallization and secondary crystallization. The isothermal crystallization was also described according to Avrami's approach. It has been shown that the addition of CNTs causes a remarkable increase in the overall crystallization rate of PA1010 and affects the mechanism of nucleation and growth of PA1010 crystals. The analysis of kinetic data according to nucleation theories shows that the increment in crystallization rate of CNTs/PA1010 composites results from the decrease in lateral surface free energy. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3794–3800, 2006     

利用金属钠制备甲醇钠的生产工艺

介绍了甲醇钠的合成方法、理化性质以及安全保护应该注意的问题。研究了用金属钠制备液体甲醇钠的生产工艺，建立了生产工艺流程。用该工艺制备的甲醇钠溶液的产率达到98％以上，游离碱含量小于0．5％，产品可满足制药行业的特殊需要，它比传统氢氧化钠制取甲醇钠有明显的技术性能优势。同时也对甲醇钠的测定方法进行了深入研究，建立了一种准确、可靠的分析甲醇钠的方法。     

融合交互意图的图神经网络协同过滤算法

传统的协同过滤方法很大程度上以一种统一的方式进行建模,未从交互意图的细粒度上考虑建模关系。为此提出一种融合交互意图的图神经网络协同过滤算法（INTNGCF）。首先,通过将边分解成多个潜在空间来识别潜在意图;其次,利用交互意图融合层确定这些潜在意图的重要性;最后,生成用户对项目的预测评分。在三个真实数据集上与七种基线模型进行对比实验,结果表明,提出的算法与其他先进的推荐模型相比具有一定的性能优势。     

基于坐标—灰度交织映射的视频麦克风声音复原系统

区别于声学麦克风,视频麦克采用高帧率摄像机,利用声音震动引起周围物体的帧间图像细微差异,对声音进行复原。模拟人脑v2皮层位置亮度交织神经网络,提出一种基于二维对数的坐标—灰度交织映射算法。算法将视频帧图像矩阵与函数构造矩阵交织映射,产生混沌吸引子保留并放大帧间图像微差异,并构造基于该算法的视频麦克风声音复原系统。仿真实验表明,该视频麦克风系统可以从薯片袋子的高帧率视频中复原声音信号,相比于传统算法降低了40%的计算量,同时保持语音复原质量。     

Fluorescence of poly(di-n-alkylsilane)s in room-temperature solution

A comprehensive study of the electronic absorption and emission spectra and the fluorescence quantum yield and lifetime of seven poly(di-n-alkylsilane)s and of three isotopically labelled poly(di-n-hexylsilane)s in hydrocarbon solution at room temperature is reported. Also reported are fluorescence polarization and carbon tetrachloride quenching of fluorescence of poly(di-n-hexylsilane). The observed fluorescence spectra, quantum yield, and polarization depend on the selected excitation energy in a very characteristic fashion, whereas the fluorescence lifetime does not; however, it depends on the selected emission energy. These characteristic dependencies are qualitatively accounted for by the previously proposed segment distribution model if one assumes that the photophysical behavior at higher excitation energies is strongly affected by the presence of a low-lying weakly allowed state in short-segment chromophores and the behavior at lower excitation energies is dictated by the selective excitation of emitting long-segment chromophores.     

可编程脉冲吞除频率合成器及其应用分析

可编程脉冲吞除频率合成器是应用微程序控制技术和脉冲吞除技术构成的一种新颖的数字式频率合成器,它的电路结构简单,可以在不改变输入基准频率和电路结构的前提下,通过“编程”来改变输出频率。所产生的输出频率准确稳定,且能灵活改变。文章阐述了这种新型频率合成器设计的数学依据,并以SN368遥测地震仪控制系统主时钟电路为实例,对其电路结构和工作原理进行了深入剖析。图3表2参4     

Infrared reflectance and transmission spectra of semiconducting non-stoichiometric CdGe x As2

The infrared reflectance and transmission spectra of amorphous CdGe _x As₂ were investigated to study the amorphous structure with varying Ge content. The mid-infrared optical absorption edges of amorphous CdGe _x As₂ with 0<x<1.2, were observed in the range 1.6–1.7 m, indicating a structural similarity in short-range order throughout. Comparing the reflectance and transmission spectra of amorphous and devitrified crystalline phases established that the structures of amorphous CdGe _x As₂ transformed from the CdAs₂ basic structure to the chalcopyrite (CdGeAs₂) structure, as one progressed fromx=0 tox=1.2. The infrared spectra were interpreted interactively with radial distribution function, magnetic susceptibility, density measurements, and crystallization studies. The crystallization behaviour of amorphous CdGe _x As₂ that was heat treated at different temperatures was investigated using far-infrared transmission spectra.     

多尺度超像素分割和奇异谱分析的高光谱影像分类

目的 高光谱影像（hyperspectral image,HSI）中“同物异谱,异物同谱”的现象普遍存在,使分类结果存在严重的椒盐噪声问题。HSI中的空间地物结构复杂多样,单一尺度的空间特征提取方法无法有效地表达地物类间差异和区分地物边界。有效解决光谱混淆和空间尺度问题是提高分类精度的关键。方法 结合多尺度超像素和奇异谱分析,提出一种新的高光谱影像分类方法,从而充分挖掘地物的局部空间特征和光谱特征,解决空间尺度和光谱混淆的问题,提高分类精度。利用多尺度超像素对影像进行分割,获取不同尺度的分割影像,同时在分割区域内进行均值滤波,减少类内的光谱差异,增强类间的光谱差异;对每个区域计算平均光谱向量,并利用奇异谱分析方法获取光谱的主要鉴别特征,同时消除噪声的影响;利用支持向量机对不同尺度超像素分割影像进行分类,并进行决策融合,得到最终的分类结果。结果 实验选取了两个标准高光谱数据集和一个真实数据集,结果表明,利用本文算法提取的光谱—空间特征进行分类,比直接在原始数据上进行分类分别提高约26.8%、9.2%和13%的精度;与先进的深度学习SSRN （spectral-spatial residual network）算法相比,本文算法在精度上分别提升约5.2%、0.7%和4%,并且运行时间仅为前者的18.3%、45.4%和62.1%,处理效率更高。此外,在训练样本有限的情况下,两个标准数据集的样本分别为1%和0.2%时,本文算法均能取得87%以上的分类精度。结论 针对高光谱影像分类中的难题,提出一种新的融合光谱和多尺度空间特征的HSI分类方法。实验结果表明,本文方法优于对比方法,可以产生更精细的分类结果。