Effect of spatial structure on colorfulness adaptation for natural images

We examined whether the perception of the colorfulness of an image is influenced by the adaptation of the visual system to natural and shuffled images with different degrees of saturation. In the experiment, observers first became adapted to several images with different levels of saturation and then their colorfulness perception of a test image was measured. The results show that their perception of colorfulness was influenced by their adaptation to the saturation of images. The effect was stronger following adaptation to natural images than to images consisting of a shuffled collage of randomized color blocks, which suggests that the naturalness of the spatial structure of an image affects the strength of the effect.     

High-Field Magnetization of the Distorted Spin Frustration System Ni5(TeO3)4Br2

We performed high-field magnetization measurements, M(H), on the Ni₅(TeO₃)₄Br₂ by using a pulse magnet. The Ni²⁺ ions (S = 1) of this compound form a two dimensional distorted spin frustrated system (distorted kagome lattice), and undergo a Neel transition at T _N ～29 K, due to the anisotropy. Below T _N , a complex spin arrangement which contains ten spin sub-lattices was suggested by neutron scattering and electron spin resonance studies. We observed a step-like transition at H _c ～11 T when T<T _N . By contrast, at T>T _N , the field-dependent magnetization curves behaved like a straight line. The H _c is close to those obtained by previous spin resonance studies of Ni₅(TeO₃)₄Br₂ and Ni₅(TeO₃)₄Cl₂ in which a spin-flop-like transition was proposed to explain the field-dependent resonance spectra. Interestingly, the observed change in magnetization (ΔM) at H _c corresponds to nearly one-half of the magnetic moment of Ni²⁺ ion, suggesting that the observed step-like behavior possibly corresponds to a spin-flip-like transition (i.e. from antiferromagnetic state to ferrimagnetic state). In addition, in the high-field region (H>H _c ), the M(H) curves did not show plateau behavior, but exhibited the straight lines having finite slopes without any sign of saturation up to 55 T.     

Fe content effects on electrochemical properties of Fe-substituted Li2MnO3 positive electrode material

Fe-substituted Li₂MnO₃ including a monoclinic layered rock-salt structure (C2/m), (Li_1+x(Fe_yMn_1−y)_1−xO₂, 0 < x < 1/3, 0.1 ≤ y ≤ 0.5) was prepared by coprecipitation-hydrothermal-calcination method. The sample was assigned as two-phase composite structure consisting of the cubic rock-salt () and monoclinic ones at high Fe content above 30% (y ≥ 0.3), while the sample was assigned as a monoclinic phase (C2/m) at low Fe content less than 20%. In the monoclinic Li₂MnO₃-type structure, the Fe ion tends to substitute a Li (2b) site, which corresponds to a center position of Mn⁴⁺ hexagonal network in Mn-Li layer. The electrochemical properties including discharge characteristics under high current density (<3600 mA g⁻¹ at 30 °C) and low temperature (<−20 °C at 40 mA g⁻¹) were severely affected by chemical composition (Fe content and Li/(Fe + Mn) ratio), crystal structure (monoclinic phase content) and powder property (specific surface area). Under the optimized Fe content (0.2 < y < 0.4), the Li/sample cells showed high initial discharge capacity (240-300 mAh g⁻¹) and energy density (700-950 mWh g⁻¹) between 1.5 and 4.8 V under moderate current density, 40 mA g⁻¹ at 30 °C. Results suggest that Fe-substituted Li₂MnO₃ would be a non-excludable 3 V positive electrode material.     

Why attend school? Chinese immigrant and European American preschoolers' views and outcomes.

The developing views of the purposes of school learning (PSLs) and related achievement among immigrant Chinese preschoolers and their European American (EA) age-mates were examined. Both culture and socioeconomic status (SES) were considered simultaneously, an often neglected research approach to studying Asian children. One hundred and fifty 4-year-olds—50 each of middle-class Chinese (CHM), low-income Chinese (CHL), and EA children—completed 2 story beginnings about school and were also tested for their language and math achievement. Results showed that 4-year-olds held sophisticated PSLs, ranging from intellectual to social and affect benefits. Large cultural and SES differences also emerged. CHM children mentioned more adult expectation and seriousness of learning than EA children who expressed more positive affect for self and compliance with adults. CHL children mentioned fewest PSLs. Achievement scores for oral expression of both immigrant groups were significantly lower than those of EA children despite similar reading and math achievement. Controlling for culture and SES, the authors found that children's articulated intellectual, but not other purposes, uniquely predicted their achievement in all tested domains. Cultural and SES influences on immigrant children are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Novel synthesis of poly(methyl methacrylate) brush encapsulated silica particles

Silica (SiO₂)‐crosslinked polystyrene (PS) particles possessing photofunctional N,N‐diethyldithiocarbamate (DC) groups on their surface were prepared by the free‐radical emulsion copolymerization of a mixture of SiO₂ (diameter = 20 nm), styrene, divinyl benzene, 4‐vinylbenzyl N,N‐diethyldithiocarbamate (VBDC), and 2‐hydroxyethyl methacrylate with a radical initiator under UV irradiation. In this copolymerization, the inimer VBDC had the formation of a hyperbranched structure by a living radical mechanism. The particle sizes of such core–shell structures [number‐average particle diameter (D_n) = 35–40 nm] were controlled by the variation of the feed amounts of the monomers and surfactant, or emulsion system. The size distributions were relatively narrow (weight‐average particle diameter/D_n ≈ 1.05). These particles had DC groups on their surface. Subsequently, poly(methyl methacrylate) brush encapsulated SiO₂ particles were synthesized by the grafting from a photoinduced atom transfer radical polymerization approach of methyl methacrylate initiated by SiO₂‐crosslinked PS particles as a macroinitiator. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008