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排序方式: 共有1716条查询结果,搜索用时 46 毫秒
31.
Yoshiro Funakoshi Masaki Yamamoto Yoshihiko Matsumura Hiromu Komeda 《Powder Technology》1980,27(1):13-21
Necessary conditions were studied for the optimum operation of agglomeration granulation. The mechanisms that would realize these conditions were investigated by several experiments.On the basis of the results obtained, a novel granulating system involving a surface wetness control mechanism has been developed.The present paper describes the mixing and dispersing characteristics of the coating vessel, the detection method for wetness control, the particular spraying units, and the operating conditions thereof, together with the characteristics of this newly developed powder coating granulation system.This system has been shown to provide an easy and reproducible granulating technique even when products below 1 mm in size are required. 相似文献
32.
The rest potential, Er, of the hydrogen electrode in deuterium-containing hydrogen and a solution of light water as referred to the reversible hydrogen electrode in the light hydrogen and the same solution is formulated as a function of deuterium content of the gaseous hydrogen and the deuterium separation factor, Sb, in the hydrogen ionization reaction. It is shown that the relation is not significantly affected by the operative mechanism of the hydrogen-electrode reaction. Consequently, the relation provides a convenient method of evaluating Sb from the observation of Er.
Experiments were carried out on Pt, Ni, Au and Ag in the system composed of deuterium-containing hydrogen and light water. The value of Sb as evaluated from Er was practically independent of the deuterium content in the gaseous hydrogen. The values obtained were 1·1 for Pt in acidic and alkaline solutions, 1·6 for Ni in alkaline solution, 1·2 for Au and 1·5 for Ag, both in acidic solution. These values multiplied by the partition coefficient of deuterium between hydrogen and water (4·0 at room temperature) give approximate values of the deuterium separation factor in the hydrogen evolution reaction. 相似文献
33.
Maki Itoh Toshimitsu Suzuki Yoshihiko Tsujimoto Ken-ichi Yoshii Yoshinobu Takegami Yoshihisa Watanabe 《Fuel》1983,62(1):98-102
Thermal cracking of tar-sand bitumens has been carried out using a two-stage pyrolysis reactor with temperature zones of 440°C and 750–800°C, respectively. Feedstocks were pyrolysed in the first stage into cracked oils, which were carried to the second stage for subsequent pyrolysis. Only 12–14 wt% of ethylene was obtained from tar-sand bitumens at the residence time of 1.2 s in the second stage, although 27 and 16 wt% were obtained from Taching and Iranian heavy vacuum residues, respectively. The tar-sand bitumens contain shorter paraffinic straight-chains and have more branched molecules than the vacuum residues of petroleum. A straight-chain paraffin index is proposed, with which a good correlation was obtained between ethylene yield and the fraction of straight-chain paraffin carbons in the heavy oil. 相似文献
34.
Hideki Ishida Kaori Sasaki Yoshihiko Okada Takeshi Mitsuda 《Journal of the American Ceramic Society》1992,75(9):2541-2546
The effect of curing temperature (40°, 60°, 80°C) on the hydration behavior of β-dicalcium silicate (β-C2 S) was investigated. The β-C2 S was obtained by decomposition of hillebrandite, Ca2 (SiO3 )(OH)2 , at 600°C, has a specific surface area of about 7 m2 /g, and is in the form of fibrous crystals. The dependence of the hydration reaction on temperature continues until the reaction is completed. The hydration is completed in 1 day at 80°C and in 14 days at 14°C. The hydration mechanism is different above and below 60°C, but at a given temperature, the reaction mechanism and the silicate anion structures of C-S-H do not change significantly from the initial to the late stages of the reaction. High curing temperature and long curing times after completion of reaction promote silicate polymerization. The Ca/Si ratio of C-S-H shows high values, being almost 2.0 above 60°C and 1.95 below 40°C. 相似文献
35.
Catalytic performances of various metal molybdates were tested in the oxidative dehydrogenation of propane to propene with molecular oxygen under an atmospheric pressure. Most of the molybdates tested promoted the selective oxidative conversion of propane to propene and among them cobalt and magnesium molybdates were found highest in the activity and selectivity. It was also found that their catalytic activities were highly sensitive to the catalyst composition, and it turned out that Co0.95MoO
x
and Mg0.95MoO
x
catalysts which have slightly excess molybdenum showed the highest activity in the oxidative dehydrogenation of propane. Under the optimized reaction conditions, higher reaction temperatures and lower partial pressures of oxygen, these catalysts gave 60% selectivity to propene at 20% conversion of propane. Since the molybdates having the surface enriched with molybdenum oxide tended to show high activity for the propane oxidation, surface molybdenum oxide clusters supported on metal molybdate matrix seem to be the active sites for the selective oxidative dehydrogenation of propane. 相似文献
36.
A film of poly(l-lactic acid) (PLLA) consisting of highly oriented α crystals was uniaxially drawn by tensile force. The effects of the draw ratio (DR), draw temperature (Td), and draw stress on the crystal/crystal transformation from the α- to the β-form crystals were studied. At the initial stage of drawing, the highly oriented α crystals of the starting film transformed into a broader orientation distribution, and significant crystal disorder was introduced. Upon further drawing, the α crystals steadily transformed into β crystals with increasing the DR. For the drawing at a constant Td, the crystal transformation proceeded more efficiently at a higher draw rate and, hence, at a higher draw stress. Furthermore, for the drawing at a constant draw rate, the transformation proceeded with DR most efficiently for the tensile draw at a Td around 140 °C, although the draw stress increased with decreasing the Td. The present result combined with the previous finding in the drawing of PLLA by solid-state extrusion [Macromolecules 36 (2003) 3601] suggests that there is a Td of around 140 °C at which the crystal transformation proceeds most efficiently with DR, suggesting that there are two factors that have opposite effects on the efficiency of the crystal transformation with increasing the Td. However, as a result of the combined effects of the Td and DR on the crystal transformation and the ductility increase with the Td, an oriented film consisting predominantly of β crystals was obtained by tensile drawing at a Td in the range of 140-170 °C to the highest DR achieved at each Td. 相似文献
37.
Kenichi Yokoyama Toshio Ogawa Kenzo Asaoka Junichi Sakai 《Journal of Alloys and Compounds》2005,400(1-2):227-233
The hydrogen absorption properties of Ti–0.2 mass% Pd (Ti–0.2Pd) alloy in 2.0% and 0.2% acidulated phosphate fluoride (APF) and neutral 2.0% NaF solutions (25 °C) has been evaluated by hydrogen thermal desorption analysis. During the early stage of immersion (120 h) in the 2.0% APF solution, the amount of absorbed hydrogen was lower than 500 mass ppm. A thermal desorption of hydrogen primary appearing with a peak at 500–600 °C and a broad desorption ranging from 100 to 400 °C were observed. In the 0.2% APF solution, the amount of absorbed hydrogen saturated at 100–200 mass ppm; the thermal desorption of hydrogen appeared with a single peak at 550 °C. In the 2.0% NaF solution, hydrogen absorption was negligible even after 1000 h of immersion, although corrosion pits were observed. The results of the present study suggest that the hydrogen absorption of Ti–0.2Pd alloy, as compared with commercial pure titanium, is suppressed in fluoride solutions. 相似文献
38.
Yoshihiko Sadaoka Enrico Traversa Masatomi Sakamoto 《Journal of Alloys and Compounds》1996,240(1-2):51-59
Perovskite-type LaxLn1−x″CoO3 oxides are prepared by the thermal decomposition of LaxLn1−x″ [Co(CN)6] · nH2O hetero-nuclear complexes. Except for LaCoO3 (hexagonal), the structures observed for LaxSm1−xCoO3 are othorhombic. While the perovskite-type oxide HoCoO3 is not formed by decomposition at 1000°C of the corresponding hexacyano complex, the partial replacing of Ho with La is effective in forming the pervoskite-type oxide having an orthorhombic structure containing Ho even at 800°C. A monotonous correlation (quasi-linear relationship) was found between the b- and c-lattice constants of the orthorhombic structures of the perovskite-type oxides and the effective radii of Ln ions, defined as reff = xr1.a + (1 − x)r1.0″. The distortion parameter for the orthorhombie cell (3″a/b−1) increaseswith decrease in reff and is expected to be 0.270 for perovskite-type HoCoO3. The crystal structure of the LaxLn1−x″, CoO3 oxides is mainly controlled by the effective radii of Ln ions. 相似文献
39.
Yasuhiro Jimbo Yuki Tamatsukuri Minato Ito Kohei Yokoyama Yoshiharu Hirakata Shunpei Yamazaki 《Journal of the Society for Information Display》2015,23(7):313-318
To improve the reliability and mechanical durability of a flexible organic light‐emitting diode display, the entire flexible display is coated with an aluminum oxide film by atomic layer deposition (ALD). Because the step coverage of ALD is excellent, the AlOx film was deposited not only on the front and back surfaces but also on the side surfaces of the display. A high‐temperature and high‐humidity preservation test, repetitive bending tests, and a pencil hardness test were conducted on the flexible display with ALD‐AlOx coating. The display survived 500 h of a 65°C, 95% preservation test, endured a 100,000‐time repetitive bending test with a curvature radius of 4 mm, and was found to have a pencil hardness of 4H. 相似文献
40.
The effect of small dose of topiroxostat on serum uric acid in patients receiving hemodialysis
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Yume Nagaoka Yoshiko Tanaka Hiroshi Yoshimoto Rie Suzuki Kakei Ryu Mio Ueda Minako Akiyama Miho Nagai Yoshitaka Miyaoka Eiichiro Kanda Shinnichi Iwai Michio Nagaoka Yoshihiko Kanno 《Hemodialysis international. International Symposium on Home Hemodialysis》2018,22(3):388-393
Introduction : Topiroxostat, a recently developed xanthine oxidase inhibitor, is expected to have fewer adverse effects than allopurinol because it has different mechanism of action from alloprinol. However, its dosage, usage and safety have not been established in patients with impaired renal function or those undergoing dialysis at the development since no studies was conducted in these patients. Methods : Cross over clinical trial using 3 months of allopurinol and topiroxostat on 27 maintain Japanese HD patients were carried out. The effects on oxidative stress status of both drugs were also evaluated by measuring oxidation reduction potential. Findings : Twenty‐five of twenty‐seven patients completed study. The mean serum uric acid levels in the topiroxostat‐treated arm was significantly lower than it in the allopurinol‐treated arm time‐dependently (P < 0.0001). Corrected oxidative stress ratio defined as biological antioxidant potential/diacron reactive oxygen metabolites was significantly increased in topiroxostat‐arm (*P = 0.0035), but not in allopurinol‐arm (P = 0.1429). No significant difference was seen in diacron reactive oxygen metabolites, biological antioxidant potential, static oxidation‐reduction potential, and capacity oxidation‐reduction potential between pre and post treatment of both drugs. Discussion : It is suggested that a low dose of topiroxostat decreased serum uric acid sufficiently to maintain it below 7.0 mg/dL in patients receiving hemodialysis. 相似文献