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11.
Single-walled carbon nanotube networks grown on SiO2 pillars were studied by means of scanning photoemission microscopy. The individual nanotubes or nanotube bundles growing from the pillar tops were observed in C 1s images. Band bending near catalytic Fe/nanotube contacts in an end-bonded configuration was studied by measuring C 1s spectra along the tube axes. Within our experimental resolution, no band bending was observed. This implies that the depletion width is less than the spatial resolution of the scanning photoemission microscope (90 nm) or that the amount of the band bending is less than 0.1 eV. 相似文献
12.
An efficient, reliable and easily programmed method for solving systems of equilibrium stage separation devices is described. The method is an extension of an algorithm developed by Ishii and Otto(9) for single columns. It solves all equations simultaneously, takes advantage of the basic tridiagonal matrix form form of the linearized steady state equations and can handle configurations which include distillation columns, absorbers and reboiled absorbers. The solution for a thermally coupled distillation system is presented. 相似文献
13.
Natural graphite particles with high crystallinity sieved to obtain a particle size range of under 63 μm were ground with a ball mill, under various well-controlled grinding atmospheres such as N2, O2, He, H2, and vacuum. The ratio, Xdif50/Xst50, i.e. between the 50 wt.% Stokes diameter and the 50 wt.% laser diffraction diameter, of the ground particles, was used as an index of the flakiness of the particles. The specific resistance of films composed of the ground graphite particles was systematically measured. The rate of reduction in the size of the particles by grinding was slow under an O2-rich atmosphere such as 100% O2 and dry air. On the other hand, it was relatively fast in vacuum, or under an N2 or He atmosphere, and a gas mixture of 99% N2 and 1% O2. The rate of size reduction by grinding under a H2 atmosphere was intermediate. In our experimental conditions, the flakiness of the ground particles increased with the decrease in the particles’ sizes. The electrical conductivity of the ground particles, however, tended to decrease with the decrease in their sizes. Under the condition that the Stokes diameter of the ground particles remains constant, the electrical conductivity of films made from the ground particles increases with the increase in the flakiness of the particles. It was finally determined from our systematic grinding experiments that small flaky particles, which had a size, Xst of ∼1 μm, with a high electrical conductivity can be produced by grinding in a gas mixture of 99% N2 and 1% O2. In this case, the flaky shape of the ground particles was visually confirmed by scanning electron microscopy. 相似文献
14.
Yoshikazu Suzuki Naoki Kondo Tatsuki Ohji Peter E. D. Morgan 《International Journal of Applied Ceramic Technology》2004,1(1):76-85
Uniformly porous composites with 3-D network structure (UPC-3D) have been recently developed via a pyrolytic reactive sintering process, which takes advantage of the evolved CO2 gas from a decomposing carbonate source (e.g., dolomite, CaMg(CO3 )2 ) and does not require any additional pore-forming agent nor long-time burning-out process. Through liquid formation via LiF doping, strong necks are formed between constituent particles before completion of the pyrolysis of carbonate, resulting in the formation of a strong 3-D network structure. The pore size distribution is very narrow (with typical pore size: ∼1 μm), and the porosity was controllable (∼30–60%) by changing the sintering temperature. This article presents the development details of UPC-3D, and reports the recent findings in CaZrO3 /MgAl2 O4 system, which will be one of the more promising systems for practical applications. 相似文献
15.
Masahiro Kato Kazuaki Nakagawa Kenji Essaki Yukishige Maezawa Shin Takeda Ryosuke Kogo Yoshikazu Hagiwara 《International Journal of Applied Ceramic Technology》2005,2(6):467-475
We have discovered a series of lithium-containing oxides that immediately react with ambient carbon dioxide (CO2 ) up to 700°C. The products react and return reversibly to the oxides at a temperatures higher than about 700°C. The absorption capacity surpasses that of other CO2 absorbents by a factor of 10. Utilizing these absorbents, the possibility of a CO2 separation system that operates at around 500°C is proposed. It is generally believed that a CO2 separation process operable at temperatures higher than 500°C has the special benefit of a small energy penalty. Moreover, the absorption also proceeds at ambient temperature in the atmospheric environment. This property offers the possibility of many other applications, such as air cleaners or cartridges. Therefore, we think these materials have the potential to make a valuable contribution to the realization of CO2 emission control. 相似文献
16.
Sun-Chan Jeong Ichiro Katayama Hirokane Kawakami Yutaka Watanabe Hironobu Ishiyama Nobuaki Imai Yoshikazu Hirayama Hiroari Miyatake Masao Sataka Satoru Okayasu Hiroyuki Sugai Shin-Ichi Ichikawa Katsuhisa Nishio Shinichi Mitsuoka Takamitsu Nakanoya Masahito Yahagi Takanori Hashimoto Kazunori Takada Mamoru Watanabe Tomoko Ishikawa Akihiro Iwase 《Journal of Phase Equilibria and Diffusion》2005,26(5):472-476
For the effective use of short-lived radioactive beams, soon to be available at the Tokai Radioactive Ion Accelerator Complex, the authors have developed a radiotracer method for diffusion studies in solids. The experimental test was performed by the measurement of the diffusion coefficients of Li in a sample of the compound βLiAl using an α-emitting radiotracer of 8Li (T1/2=0.84 s). It was found that the time-dependent yields of the α particles from the diffusing 8Li that was initially implanted in the sample could be used as a measure of the diffusivity of the tracer in a nondestructive way. The method was applied to measure the self-diffusion coefficients of Li in βLiGa, and for investigating how the Li diffusion in the Li ionic conductors is affected by the concentration of atomic defects (i.e., the existence of the atomic vacancies of Li and the defects in Ga sites that are replaced by Li). 相似文献
17.
It is demonstrated theoretically and experimentally that the inversion symmetry of the diffraction pattern of a binary grating at normal incidence can be efficiently broken by the use of nonsymmetric profiles with wavelength-scale transverse features. Theoretically, binary gratings with two grooves (of unequal widths but with the same depth) within the period can deflect as much as ~80% of normally incident radiation into the minus first diffraction order when the deflection angle is 45°. 相似文献
18.
Yoshikazu Iida Masato Hirai Masato Shiga Tetsushi Ono Tatsuki Inuzuka 《Electrical Engineering in Japan》2023,216(1):e23414
We are planning to develop the new Advanced Distribution Automation System (ADAS) equipped with optical communication network and sectionalizer with sensor for more grid reliability and efficiency on maintenance operation. The new system is featured with the function of fault cause or damaged part estimation. The new sectionalizer captures the waveform of electrical line surge originated by fault and the system analyzes the waveform for this function. This paper mainly introduces the system configuration of ADAS and an early stage examination of fault cause estimation technology. 相似文献
19.
Correlation between Chemical Dopants and Topological Defects in Catalytically Active Nanoporous Graphene
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20.
Koji Matsumoto Ken Oikawa Masashi Okada Yoshikazu Teraoka Tetsuo Kawagoe 《International Journal of Refrigeration》2006,29(6):1010
This study focuses on an emulsion as a new thermal storage material for ice storage. Two types of emulsions were formed using an oil–water mixture with a small amount of additive. A silicone, light and lump oils were used. The water contents of the emulsions were 70, 80 and 90%. The additive was an amino group modified silicone oil. No depression of freezing point was observed for the emulsions because of their hydrophobic properties. In order to determine the structure of the emulsions, their electrical resistances were measured. Moreover, components of the liquids separating from the emulsions were analyzed. The results indicated that one emulsion was a W/O type emulsion, while the other was an O/W type. Finally, adaptability of the two emulsions to ice storage was discussed, it was concluded that a high performance ice slurry could be formed by the W/O type emulsion. 相似文献