DRYING OF CLAY AND NONCLAY MEDIA : HEAT AND MASS TRANSFER AND QUALITY ASPECTS

The researches on drying of clay and nonclay media are briefly reviewed and the role of drying in the manufacturing process is summarized. The drying process must be carefully controlled to maintain the desired product configuration. Inefficient completion of drying and poor operation of the dryer influence directly the product quality. The importance of R&D on the heat and moisture transfer phenomena, shrinkage mechanisms, deformation behavior, strain-stress relations and the internal pressure in the media during drying is stressed. Suggestions are given for further improvement of the drying process and improved design of the molding and casting processes for higher product quality     

Methanol synthesis from CO2 over Cu/ZnO catalysts prepared from various coprecipitated precursors

Various precursors of Cu/ZnO catalysts were prepared by coprecipitation methods. By varying the conditions of coprecipitation, precursors having different structures (aurichalcite, malachite, hydrozincite, or their mixture) were obtained at given Cu/Zn ratios, ranging from 30/70 to 70/30. In a wide range of the Cu/Zn ratios, the catalysts derived from the precursors containing aurichalcite exhibited high performance in the methanol synthesis from CO₂.     

Large-Scale Shake Table Experiment and Numerical Simulation on the Nonlinear Behavior of Pile-Groups Subjected to Large-Scale Earthquakes

This paper describes the results of large-scale shake-table experiments involving a 3×3 pile-group. The pile-group was embedded in dry sand and subjected to sinusoidal waves and an earthquake motion recorded from the 1995 Hyogo-ken Nanbu (Kobe) earthquake. The load transfer between soil and pile was derived and the group effect was captured. Numerical simulations were also performed using a Beam-on-Nonlinear-Winkler-Foundation approach with a new hysteretic p-y curve. A comparison of the experimental and numerical results revealed that the numerical simulation is capable of accounting for the soil-pile interaction observed in the experiment.     

Research on some basic deformations in free forging with robot and servo-press

Due to the disadvantages in casting or hot forging of Ti alloy artificial bones, such as low strength and high energy cost, this paper prompted an alternative method to manufacture individuated artificial bones. Free forging with a 6-axis freedom robot and servo-press could be very economical in the forming of complex shape parts because of its high flexibility and simple die-setting. Based on this system, the authors studied deformations of some basic elements, which could be assembled to artificial bones with complex shape. Firstly, the compression limit and effect of compression parameters on the roundness during reducing diameter process were declared for Al alloy and pure Ti. Secondly, an approximate theoretical equation of bending angle or curvature radius was proposed, and it matches experimental results well. Finally, a dimension prediction equation was presented by considering effect of material anisotropy, and then the ladder part without width spread was manufactured accordingly.     

Characterisation of volatile sulphur-containing compounds generated in crushed leaves of Chinese chive (Allium tuberosum Rottler)

To characterise the composition of sulphur-containing constituents in Chinese chive (Allium tuberosum Rottler), GC–MS and HPLC analyses were carried out, using 12 varieties of Chinese origin, 4 varieties of Japanese origin and 6 commercially available cultivars. Five disulphides (dimethyl, allyl methyl, methyl 1-(E)-propenyl, diallyl, and allyl 1-(E)-propenyl), two trisulphides (dimethyl and allyl methyl), and two vinyldithiins (3-vinyl-[4H]-1,2- and 2-vinyl-[4H]-1,3-) were identified on the basis of their mass spectral and GC-retention data. Among the detected sulphur compounds, sulphides with a methyl group predominated over those with an allyl group. This was supported by the HPLC estimations, suggesting that all cultivars examined had much greater amounts of methiin than alliin. Also, two novel compounds were tentatively identified as [3H,4H]-1,2-dithiin and [2H,4H]-1,3-dithiin on the basis of their mass spectral features, GC-retention data, and some experimental results on their formation in reaction mixtures with different proportions of methiin and alliin. Their formation mechanism was proposed.     

Effect of transition elements on the properties of MC carbides in IN-100 nickel-based superalloy

The effect of nine transition elements on the morphology, distribution and composition of MC carbides (MCs) in a nickel-base superalloy, IN-100, was investigated by differential thermal analysis (DTA), microstructural observation and X-ray microanalysis. The doping with tantalum, tungsten and molybdenum caused a significant change in the morphology and distribution of MCs as well as the profile of DTA curve of IN-100. The compositions of the MC in IN-100 were TiC and (Ti_0.80Mo_0.17V_0.03) C, and the doping with niobium, tantalum and tungsten changed significantly the composition of MC. On the other hand, the doping with chromium, vanadium, hafnium and zirconium scarcely changed the composition. In addition to TiC and (Ti, Mo, V) C, zirconium- and hafnium-rich MCs were found in the zirconium- and hafnium-doped alloys, respectively. The effect of the dopants on the composition of MCs could be explained by a relationship between the metallic radius and the free energy of formation for the MC.     

Organic Analysis of Peridotite Rocks from the Ashadze and Logatchev Hydrothermal Sites

This article presents an experimental analysis of the organic content of two serpentinized peridotite rocks of the terrestrial upper mantle. The samples have been dredged on the floor of the Ashadze and Logatchev hydrothermal sites on the Mid-Atlantic Ridge. In this preliminary analysis, amino acids and long chain n-alkanes are identified. They are most probably of biological/microbial origin. Some peaks remain unidentified.     

Purification and characterization of an extracellular alpha-neoagarooligosaccharide hydrolase from Bacillus sp. MK03

An agarolytic bacterium was isolated from soil in Gifu prefecture, Japan, and identified as Bacillus sp. strain MK03. The strain secreted neoagarooligosaccharide hydroluse into the culture medium. The enzyme was purified 49.7-fold from the culture fluid by ammonium sulfate precipitation and anion-exchange and gel-filtration column chromatographic methods. The purified enzyme appeared as a single band on polyacrylamide gel electrophoresis (PAGE) and sodium dodecyl sulfate (SDS)-PAGE. Estimations of the molecular mass by gel filtration and SDS-PAGE gave values of 320 kDa and 42 kDa, respectively, indicating that the enzyme is octametric. The enzyme cleaved the alpha-1,3 linkage in neoagarobiose to produce 3,6-anhydro-L-galactose and D-galactose. It also selectively cleaved the alpha-1,3 linkage at the nonreducing end in neoagarotetraose or neoagarohexaose to give 3,6-anhydro-L-galactose and agarotriose or agaropentaose. The optimum temperature and pH for the enzyme were 30 degrees C and 6.1, respectively. The N-terminal amino acid sequence showed no homology to sequences of other known neoagarooligosaccharide hydrolases and agarases.     

A novel MOSFET with vertical signal‐transfer capability for 3D‐structured CMOS image sensors

We have developed a novel MOSFET that can transfer signals vertically without through‐silicon vias but by using a fully depleted silicon‐on‐insulator (FDSOI) structure with its source region connected to the back electrodes as well as the front ones. A prototype MOSFET fabricated using the backside anisotropic wet etching technique has confirmed that the electrical characteristics measured from the front and the back electrodes are identical. The subthreshold factor S of the prototype was found to be 64.5 mV/decade, suggesting a good switching performance. Since the double‐sided MOSFET has vertical signal‐transfer capability and excellent operating characteristics, it is expected to contribute to developing a More‐than‐Moore type device of three‐dimensional integration such as pixel‐parallel image sensors. © 2014 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.