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31.
    
Gigacycle fatigue data sheets have been published since 1997 by the National Institute for Materials Science. They cover several areas such as high-cycle-number fatigue for high-strength steels and titanium alloys, the fatigue of welded joints, and high-temperature fatigue for advanced ferritic heat-resistant steels. Some unique testing machines are used to run the tests up to an extremely high number of cycles such as 1010 cycles. A characteristic of gigacycle fatigue failure is that it is initiated inside smooth specimens; the fatigue strength decreases with increasing cycle number and the fatigue limit disappears, although ordinary fatigue failure initiates from the surface of a smooth specimen and a fatigue limit appears. For welded joints, fatigue failure initiates from the notch root of the weld, because a large amount of stress is concentrated at the weld toe. The fatigue strength of welded joints has been obtained for up to 108 cycles, which is an extremely high number of cycles for large welded joints. The project of producing gigacycle fatigue data sheets is still continuing and will take a few more years to complete. r 2007 Published by Elsevier Ltd.  相似文献   
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In order to utilize visible light in photocatalytic reactions, nitrogen atoms were doped in commercially available photocatalytic TiO2 powders by using an organic compound such as urea and guanidine. Analysis by X-ray photoelectron spectroscopy (XPS) indicated that N atoms were incorporated into two different sites of the bulk phase of TiO2. A significant shift of the absorption edge to a lower energy and a higher absorption in the visible light region were observed. These N-doped TiO2 powders exhibited photocatalytic activity for the decomposition of 2-propanol in aqueous solution under visible light irradiation. The photocatalytic activity increased with the decrease of doped N atoms in O site, while decreased with decrease of the other sites. Degradation of photocatalytic activity based on the release of nitrogen atoms was observed for the reaction in the aqueous suspension system.  相似文献   
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A new type of hierarchically porous materials is fabricated by assembling mesoporous nanoparticles via spray drying. Well-dispersed mesostructured silica nanoparticles (MSN), whose particle size distribution was narrow in the range of 20 nm and 50 nm, were prepared by a thermal deposition method. By spray drying a MSN suspension, MSN were assembled into spherical secondary particles. After calcination, the spherical particles have two types of mesopores, mesopores of 3 nm in size inside of calcined MSN and larger inter-nanoparticle mesopores of about 15-20 nm. This hierarchical pore system should provide nanospaces for efficient mass transport of guest species with different sizes.  相似文献   
39.
  总被引:1,自引:0,他引:1  
An experimental study was carried out to find material parameters for making fiber reinforced cementitious composites (FRCC) more ductile. One of the dominant factors to control the ductility might be hidden in fracture property of matrix as well as the interface property between fiber and matrix. Therefore this study varied air content and water-binder ratio as the parameters to change the fracture property of matrix and experimentally examined their influence on the ductility of FRCC by three-point bend test with notched beams. As a result, it is concluded that fracture toughness of the matrix could be one of key parameters to control the ductility of FRCC. In case of a polyethylene fiber used in this study, the optimum value of the fracture toughness (critical strain energy release rate): GIC of the matrix was obtained to be 7.5-8.0 N/m.  相似文献   
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Multilayer films of poly(amide-imide)s were prepared as follows: (1) monolayers of long alkyl amine salts of poly(amide-amic acid) were prepared at the air- water interface; (2) these monolayers were deposited on an appropriate plate by the Langmuir-Blodgett method; (3) the multilayers of poly(amide-amic acid) salts on the solid support were treated with acetic anhydride to afford poly(amide-imide) multilayer films. The monolayer thickness of the poly(amide-imide) multilayer films were 0.43–0.55 nm.  相似文献   
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