Experimental Study of Macro- and Microbehavior of Natural Diatomite

Diatomite is widely deposited in Oita prefecture of Japan. It has high natural water content but its consolidation yield stress is much higher than the overburden pressure. Oedometer and triaxial consolidated undrained shear tests were performed in this study to investigate its macrobehavior in terms of compressibility and strength. The test results indicate that the compressibility and undrained shear strength of diatomite in the preyield state (i.e., the consolidation stress lower than the yield stress) are independent of the consolidation stress level. When the consolidation stress is higher than the yield stress, however, like virtually all soils, the compressibility of the diatomite increases dramatically. Similarly, the undrained shear strength of the diatomite depends on the confining stress when the confining stress is higher than the transitional stress. Both mercury intrusion porosimetry analysis and scanning electron microscopy were performed to investigate the change of the microstructure of the natural diatomite with the consolidation stress. The test results indicate that the microstructure of the diatomite remains unchanged in the preyield state, but it changes significantly in the vicinity of the yield stress. This unchanged microstructure is attributed to the unchanged macrobehavior within the preyield state. The breakage of diatoms particles and the compression of interparticle pores between the diatom particles in the postyield state contribute to the high compressibility of the diatomite.     

Photo-induced graft copolymerization of methyl methacrylate on oxidized poly(vinyl alcohol) fiber

Photo-induced graft copolymerization of methyl methacrylate on oxidized poly(vinyl alcohol) fiber was investigated. Oxidation of the fiber sample with sodium hypochlorite or periodic acid led the radical formation by photo-irradiation to intensify markedly. ESR spectra of the irradiated oxidized sample proved that a considerable amount of triplet component radical was contained in it, whereas the unoxidized sample mostly indicated a singlet. The spectra found in the irradiated unoxidized sample was assigned to two radicals, I and II, and for the oxidized sample, to III and IV. The spectrum for I must be a singlet, and a triplet for II, III, and IV. Among the last three, II was less stable toward heat. As the oxidized sample has a high activity for photoinitiation, the radicals of III and IV are presumed to be the sites of graft copolymerization:      

Evaluation of method for simultaneous determination of pesticide residues in fruits and vegetables by collaborative study

A collaborative study involving 8 laboratories was conducted to evaluate a method for the simultaneous determination of pesticide residues in 6 types of fruits and vegetables (spinach, tomato, apple, radish, cabbage and carrot). The method of analysis was the same as reported by Kakimoto et al. in 2003. One hundred and thirty-nine pesticides were spiked by each of 8 laboratories at levels of 0.1 microg/g (pesticides analyzed by GC/MS) or 0.5 microg/g (pesticides analyzed by HPLC) into the 6 kinds of samples. Statistical analysis showed that 111 pesticides could be analyzed with practical precision by this method. For screening purposes, the method could analyze 118 pesticides. The median values of the limits of detection were 0.001-0.041 microg/g. The calibration curves were linear in the range of 0.5-5 microg/mL for most pesticides with median correlation coefficients of 0.983-1.000.     

Electric field–temperature phase diagram of sodium bismuth titanate-based relaxor ferroelectrics

The electric field–temperature phase diagrams of three bismuth sodium titanate-based relaxor ferroelectrics are reported, namely 0.94(Na_1/2Bi_1/2TiO₃)–0.06(BaTiO₃), 0.80(Na_1/2Bi_1/2TiO₃)–0.20(K_1/2Bi_1/2TiO₃) and 0.75(Na_1/2Bi_1/2TiO₃)–0.25(SrTiO₃). Relaxor behavior is demonstrated by temperature-dependent dielectric permittivity measurements in the unpoled and poled states, as well as by the field-induced phase transition into a ferroelectric phase from the relaxor phase. From temperature-dependent thermometry measurements, we identified the threshold electric field to induce the ferroelectric phase and obtained the released latent heat of the phase transition. We determined the nonergodic and ergodic relaxor phase temperature range based on the absence or presence of reversibility of the relaxor to ferroelectric transition. For all three compositions, the electric field–temperature phase diagram was constructed and a critical point was identified. The constructed electric field–temperature phase diagrams are useful to find optimum operational ranges of ferroelectrics and relaxors for electromechanical and electrocaloric applications.     

Preface

Multimedia Tools and Applications -     

日本彩色聚乙烯涂覆钢管的开发

试验了彩色聚乙烯涂覆钢管的耐腐蚀性和耐气候性，由于聚乙烯涂层隔绝水的作用，聚乙烯涂覆钢管具有优良的耐腐蚀性能，电阻绝缘值和优良的机械性能。建立了一个新的方式去研究分析聚乙烯抗老化剂消耗和在聚乙烯中的扩散。用有效测定的方法定量地预测彩色聚乙烯涂覆层的寿命，应用这些分析结果，不仅可使新的有色聚乙烯涂覆钢管在恶劣腐蚀环境介质情况下具有高的耐腐蚀性，而且有长的耐气候性。     

Use of Ponkan mandarin peels as biosorbent for toxic metals uptake from aqueous solutions

Waste Ponkan mandarin (Citrus reticulata) peel was used as biosorbent to extract Ni(II), Co(II) and Cu(II) from aqueous solutions at room temperature. To achieve the best adsorption conditions the influence of pH and contact time were investigated. The isotherms of adsorption were fitted to the Langmuir equation. Based on the capacity of adsorption of the natural biosorbent to interact with the metallic ions, the following results were obtained 1.92, 1.37 and 1.31 mmol g(-1) for Ni(II), Co(II) and Cu(II), respectively, reflecting a maximum adsorption order of Ni(II)>Co(II)>Cu(II). The quick adsorption process reached the equilibrium before 5, 10 and 15 min for Ni(II), Co(II) and Cu(II), respectively, with maximum adsorptions at pH 4.8. In order to evaluate the Ponkan mandarin peel a biosorbent in dynamic system, a glass column was fulfilled with 1.00 g of this natural adsorbent, and it was fed with 5.00 x 10(-4)mol l(-1) of Ni(II) or Co(II) or Cu(II) at pH 4.8 and 3.5 ml min(-1). The lower breakpoints (BP(1)) were attained at concentrations of effluent of the column attained the maximum limit allowed of these elements in waters (>0.1 mg l(-1)) which were: 110, 100 and 130 bed volumes (V(effluent)/V(adsorbent)), for Ni(II), Co(II) and Cu(II), respectively. The higher breakpoints (BP(2)) were attained when the complete saturation of the natural adsorbent occurred, and the values obtained were: 740, 540 and 520 bed volumes for Ni(II), Co(II) and Cu(II), respectively.     

The effect of small dose of topiroxostat on serum uric acid in patients receiving hemodialysis

Introduction : Topiroxostat, a recently developed xanthine oxidase inhibitor, is expected to have fewer adverse effects than allopurinol because it has different mechanism of action from alloprinol. However, its dosage, usage and safety have not been established in patients with impaired renal function or those undergoing dialysis at the development since no studies was conducted in these patients. Methods : Cross over clinical trial using 3 months of allopurinol and topiroxostat on 27 maintain Japanese HD patients were carried out. The effects on oxidative stress status of both drugs were also evaluated by measuring oxidation reduction potential. Findings : Twenty‐five of twenty‐seven patients completed study. The mean serum uric acid levels in the topiroxostat‐treated arm was significantly lower than it in the allopurinol‐treated arm time‐dependently (P < 0.0001). Corrected oxidative stress ratio defined as biological antioxidant potential/diacron reactive oxygen metabolites was significantly increased in topiroxostat‐arm (*P = 0.0035), but not in allopurinol‐arm (P = 0.1429). No significant difference was seen in diacron reactive oxygen metabolites, biological antioxidant potential, static oxidation‐reduction potential, and capacity oxidation‐reduction potential between pre and post treatment of both drugs. Discussion : It is suggested that a low dose of topiroxostat decreased serum uric acid sufficiently to maintain it below 7.0 mg/dL in patients receiving hemodialysis.     

Analysis of proton exchange membrane fuel cell catalyst layers for reduction of platinum loading at Nissan

The biggest issue that must be addressed in promoting widespread use of fuel cell vehicles (FCVs) is to reduce the cost of the fuel cell system. Especially, it is of vital importance to reduce platinum (Pt) loading of catalyst layers (CLs) in the membrane electrode assembly (MEA) of a proton exchange membrane fuel cell (PEMFC). In order to lower the Pt loading of the MEA, mass transport of reactants related to the performance in high current density should be enhanced significantly as well as kinetics of the catalyst, which can result in the better Pt utilization and effectiveness. In this study, we summarized our analytical approach and methods for reduction of Pt loading in CLs. Microstructure, mass transport properties of the reactants, and their relation in CLs were elucidated by applying experimental analyses and computational methods. A simple CL model for I–V performance prediction was then established, where experimentally elucidated parameters of the microstructure and the properties in CLs were taken into account. Finally, we revealed the impact of lowering the Pt loading on the transport properties, polarization, and the I–V performance.