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排序方式: 共有513条查询结果,搜索用时 304 毫秒
61.
In our previous article on the photodegradation of polypropyle (PP), the effect of ferric chloride (FeCl3) accelerating the formation of peroxy radical and depressing the formation of alkyl radical were reported. In the present article, the influence of FeCl3 on model compounds of PP was examined using electron spin resonance (ESR) spectrometry. The following compounds were employed as models of PP, including its irregular structures: 2-methylpentane (2-MP), 2,4-dimethylpentane (2,4-DMP), 2-methyl-4-pentanone (2-M4P), 2,6-dimethyl-4-heptanone (2,6-DM4H), 2-methyl-1-pentene (2-M1P), and tert-butylhydroperoxide (t-BuO2H). FeCl3 accelerated the formation of alkyl radicals for 2-MP and 2,4-DMP, alkyl and acyl radicals for 2-M4P and 2,6-DM4H, and alkyl radicals for 2-M1P. As no definite effect of FeCl3 was observed for n-pentane and 2-octanone, FeCl3 was assumed to attack saturated hydrocarbons, ketones at a tertiary carbon-hydrogen bond, and hydrocabons at an allylic hydroge, leading to easier photodegradations. FeCl3 was also effective for the photodegradation of t-BuO2H using λ >300 nm, so that FeCl3 is believed to contribute also to the photodegradation of PP under the same irradation conditions. The catalytic effect of FeCl3 in photodegradation seems to origirate in a redox reaction. 相似文献
62.
Shirasaki Y Tanaka J Makazu H Tashiro K Shoji S Tsukita S Funatsu T 《Analytical chemistry》2006,78(3):695-701
We have developed a microfabricated fluorescence-activated cell sorter system using a thermoreversible gelation polymer (TGP) as a switching valve. The glass sorter chip has Y-shaped microchannels with one inlet and two outlets. A biological specimen containing fluorescently labeled cells is mixed with a solution containing a thermoreversible sol-gel polymer. The mixed solution is then introduced into the sorter chip through the inlet. The sol-gel transformation was locally induced by site-directed infrared laser irradiation to plug one of the outlets. The fluorescently labeled target cells were detected with sensitive fluorescence microscopy. In the absence of a fluorescence signal, the collection channel is plugged through laser irradiation of the TGP and the specimens are directed to the waste channel. Upon detection of a fluorescence signal from the target cells, the laser beam is then used to plug the waste channel, allowing the fluorescent cells to be channeled into the collection reservoir. The response time of the sol-gel transformation was 3 ms, and a flow switching time of 120 ms was achieved. Using this system, we have demonstrated the sorting of fluorescent microspheres and Escherichia coli cells expressing fluorescent proteins. These cells were found to be viable after extraction from the sorting system, indicating no damage to the cells. 相似文献
63.
Use of Ponkan mandarin peels as biosorbent for toxic metals uptake from aqueous solutions 总被引:1,自引:0,他引:1
Waste Ponkan mandarin (Citrus reticulata) peel was used as biosorbent to extract Ni(II), Co(II) and Cu(II) from aqueous solutions at room temperature. To achieve the best adsorption conditions the influence of pH and contact time were investigated. The isotherms of adsorption were fitted to the Langmuir equation. Based on the capacity of adsorption of the natural biosorbent to interact with the metallic ions, the following results were obtained 1.92, 1.37 and 1.31 mmol g(-1) for Ni(II), Co(II) and Cu(II), respectively, reflecting a maximum adsorption order of Ni(II)>Co(II)>Cu(II). The quick adsorption process reached the equilibrium before 5, 10 and 15 min for Ni(II), Co(II) and Cu(II), respectively, with maximum adsorptions at pH 4.8. In order to evaluate the Ponkan mandarin peel a biosorbent in dynamic system, a glass column was fulfilled with 1.00 g of this natural adsorbent, and it was fed with 5.00 x 10(-4)mol l(-1) of Ni(II) or Co(II) or Cu(II) at pH 4.8 and 3.5 ml min(-1). The lower breakpoints (BP(1)) were attained at concentrations of effluent of the column attained the maximum limit allowed of these elements in waters (>0.1 mg l(-1)) which were: 110, 100 and 130 bed volumes (V(effluent)/V(adsorbent)), for Ni(II), Co(II) and Cu(II), respectively. The higher breakpoints (BP(2)) were attained when the complete saturation of the natural adsorbent occurred, and the values obtained were: 740, 540 and 520 bed volumes for Ni(II), Co(II) and Cu(II), respectively. 相似文献
64.
Ali Gooya Hongen Liao Kiyoshi Matsumiya Ken Masamune Yoshitaka Masutani Takeyoshi Dohi 《IEEE transactions on image processing》2008,17(8):1295-1312
In this paper, a level-set-based geometric regularization method is proposed which has the ability to estimate the local orientation of the evolving front and utilize it as shape induced information for anisotropic propagation. We show that preserving anisotropic fronts can improve elongations of the extracted structures, while minimizing the risk of leakage. To that end, for an evolving front using its shape-offset level-set representation, a novel energy functional is defined. It is shown that constrained optimization of this functional results in an anisotropic expansion flow which is usefull for vessel segmentation. We have validated our method using synthetic data sets, 2-D retinal angiogram images and magnetic resonance angiography volumetric data sets. A comparison has been made with two state-of-the-art vessel segmentation methods. Quantitative results, as well as qualitative comparisons of segmentations, indicate that our regularization method is a promising tool to improve the efficiency of both techniques. 相似文献
65.
This paper proposes a method for generating a basis translation matrix between isomorphic extension fields. To generate a basis translation matrix, we need the equality correspondence of a basis between the isomorphic extension fields. Consider an extension field Fpm where p is characteristic. As a brute force method, when pm is small, we can check the equality correspondence by using the minimal polynomial of a basis element; however, when pm is large, it becomes too difficult. The proposed methods are based on the fact that Type I and Type II optimal normal bases (ONBs) can be easily identified in each isomorphic extension field. The proposed methods efficiently use Type I and Type II ONBs and can generate a pair of basis translation matrices within 15 ms on Pentium 4 (3.6 GHz) when mlog2 p = 160. 相似文献
66.
Hiroyuki Koide Satoshi Hirano Takafumi Ide Kazuhiro Saito Hikaru Suzuki Go Yasuno Yoshitaka Hamashima Sei Yonezawa Naoto Oku Tomohiro Asai 《Advanced functional materials》2021,31(3):2005641
Protein affinity reagents (e.g., antibodies) are often used for basic research, diagnostics, separations, and disease therapy. Although a lot of “synthetic” protein affinity reagents have been developed as a cost-effective alternative to antibodies, their low biocompatibility is a considerable problem for clinical application. Lipid nanoparticles (LNP) represent a highly biocompatible drug delivery agent. However, little has been reported that LNP itself works as a protein affinity reagent in living animals. Here, LNP is engineered for binding to and neutralizing a target toxic peptide in living animals by multifunctionalization with amino acid derivatives. Multifunctionalized LNP (MF-LNP) is prepared using amino acid derivative-conjugated lipids. Optimized MF-LNP exhibits nanomolar affinity to the target toxic peptide and inhibits toxic peptide-dependent hemolysis and cytotoxicity. In addition, MF-LNP captures and neutralizes the toxic peptide after intravenous injection in the bloodstream; in addition, MF-LNP does not release the toxic peptide in the accumulated organ. These results reveal the potential of using LNP as a highly biocompatible protein affinity reagent such as an antidote. 相似文献
67.
Molecular dynamics simulations of multiwalled carbon nanotubes under hydrostatic pressure are performed to elucidate the novel class of radial buckling in the systems. It is revealed by all-atom simulations that the initial circular cross section transforms into a flower-like wavy configuration at critical pressure on the order of hundreds mega pascals or less. This kind of radial buckling, called radial corrugation, originates from the competition of the three relevant energies in the system: in-plane strain energy, van der Waals interaction energy between adjacent tubes, and out-of-plane bending energy. Their possible consequences for physical properties of carbon nanotubes are also discussed. 相似文献
68.
Makoto Koike Tetsunori Suzuoki Tadashi Takeuchi Takayuki Homma Satoshi Hariu Yoshitaka Takeuchi 《International Journal of Hydrogen Energy》2021,46(50):25689-25698
This work demonstrated the first-ever cold-start operation of an ammonia (NH3)-fueled four-cylinder spark ignition engine with an on-board fuel reformer, applying autothermal reforming. In this system, an electrically heated NH3-air mixture was provided to a reforming catalyst and approximately 3 s was found to elapse between the start of engine rotation and the onset of combustion. Stable fast idle operation in conjunction with a cold start was realized with a H2-to-NH3 molar ratio of 2:1. Nearly zero NH3 emissions were achieved during cold start and fast idle until the engine warmed up, by adsorbing unburned NH3 passing through a three-way catalyst before the catalyst was sufficiently warmed up. The NH3 adsorption capacity of this system could be regenerated during the engine warm-up when the engine was running under lean conditions. 相似文献
69.
Jeong‐Kee Yoon Dae‐Hyun Kim Mi‐Lan Kang Hyeon‐Ki Jang Hyun‐Ji Park Jung Bok Lee Se Won Yi Hye‐Seon Kim Sewoom Baek Dan Bi Park Jin You Seong‐Deok Lee Yoshitaka Sei Song Ih Ahn Young Min Shin Chang Soo Kim Sangsu Bae YongTae Kim Hak‐Joon Sung 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(16)
Atherosclerosis development leads to irreversible cascades, highlighting the unmet need for improved methods of early diagnosis and prevention. Disturbed flow formation is one of the earliest atherogenic events, resulting in increased endothelial permeability and subsequent monocyte recruitment. Here, a mesenchymal stem cell (MSC)‐derived nanovesicle (NV) that can target disturbed flow sites with the peptide GSPREYTSYMPH (PREY) (PMSC‐NVs) is presented which is selected through phage display screening of a hundred million peptides. The PMSC‐NVs are effectively produced from human MSCs (hMSCs) using plasmid DNA designed to functionalize the cell membrane with PREY. The potent anti‐inflammatory and pro‐endothelial recovery effects are confirmed, similar to those of hMSCs, employing mouse and porcine partial carotid artery ligation models as well as a microfluidic disturbed flow model with human carotid artery‐derived endothelial cells. This nanoscale platform is expected to contribute to the development of new theragnostic strategies for preventing the progression of atherosclerosis. 相似文献
70.
Florian Weyland Matias Acosta Malte Vögler Yoshitaka Ehara Jürgen Rödel Nikola Novak 《Journal of Materials Science》2018,53(13):9393-9400
The electric field–temperature phase diagrams of three bismuth sodium titanate-based relaxor ferroelectrics are reported, namely 0.94(Na1/2Bi1/2TiO3)–0.06(BaTiO3), 0.80(Na1/2Bi1/2TiO3)–0.20(K1/2Bi1/2TiO3) and 0.75(Na1/2Bi1/2TiO3)–0.25(SrTiO3). Relaxor behavior is demonstrated by temperature-dependent dielectric permittivity measurements in the unpoled and poled states, as well as by the field-induced phase transition into a ferroelectric phase from the relaxor phase. From temperature-dependent thermometry measurements, we identified the threshold electric field to induce the ferroelectric phase and obtained the released latent heat of the phase transition. We determined the nonergodic and ergodic relaxor phase temperature range based on the absence or presence of reversibility of the relaxor to ferroelectric transition. For all three compositions, the electric field–temperature phase diagram was constructed and a critical point was identified. The constructed electric field–temperature phase diagrams are useful to find optimum operational ranges of ferroelectrics and relaxors for electromechanical and electrocaloric applications. 相似文献