Isothermal interphase diffusion with consecutive reactions

For multi-step heterogeneous consecutive reactions affected entirely by interphase diffusion under isothermal condition, the equations for the effectiveness factors, the surface concentrations and the point yields were derived in terms of the Damkoehler numbers or the measurables from the mass balances set up on the assumption that the mass-transfer rate balances the surface-reaction rate at steady state. From the analyses of the equations derived, the effectiveness factors for the intermediate steps and the surface concentrations of intermediates were understood to be enhanced by the measurables inclusive of the concentrations and the mass-transfer coefficients. Then the effect of the concentrations was concluded to be most significant. The effects of these measurables to the effectiveness factors and the surface concentrations were qualitatively discussed for simple consecutive reactions and also for additive consecutive reactions. Especially, as for two-step additive consecutive reactions, the effects of measurables η Da and the concentrations to the effectiveness factors were examined with graphical presentations. Finally, the brief discussion of the dependency of the Damkoehler number upon reaction time and the effect of the Renolds number and diffusivity to the extent of the mass-transfer resistance were presented.     

面向共同配送的建模仿真研究

分析了共同配送的工作程序、建模方法及相关算法。采用基于面向对象的结构化的建模分析方法和eM-plant仿真平台,建立了共同配送的仿真模型。将电子地图导入仿真模型,并运用启发式算法自动规划出车辆配送路线,同时考虑各种确定性与不确定性因素对模型的影响。选用实例验证了该仿真方法。     

单晶钛酸铋纳米片的XPS和Raman特性

以Bi（NO3）3·5H2O和Ti（OC4H9）4为原料，NaOH为矿化剂，采用水热法制备了形貌规则的单晶Bi4Ti3O12纳米片。X射线衍射（XRD）结果表明，所合成的产物为正交相层状钙钛矿结构的Bi4Ti3O12。场发射扫描电子显微镜（FESEM）研究显示：样品是由大量边缘尺寸接近200nm，厚度约为15nm的片状结构组成。利用X射线光电子能谱（XPS）研究产物的化学组分和价态分布。室温拉曼光谱研究表明，Bi4Ti3O12纳米片的声子寿命和热稳定性低于相应的块体材料。     

掺杂InGaAs／InAlAs单量子阱中电子对称态和反对称态磁输运研究

利用变温Hall测量研究了重掺杂InGaAs／InAlAs单量子阱中二维电子气，发现在量子阱中由于存在电子对称态和反对称态导致纵向电阻出现拍频现象。通过分析拍频节点位置，得到电子对称态和反对称态之间的能级间距为4meV。此外，通过迁移率谱方法和多载流子拟合过程研究了不同迁移率电子的浓度和迁移率随温度的变化关系。     

晶体硅薄膜电池制备技术及研究现状

晶体硅薄膜太阳电池近些年来得到广泛的研究和初步的商业化探索。根据所采用的晶体硅薄膜沉积工艺中温度范围的不同，晶体硅薄膜电池研究可分为高温路线和低温路线两个不同发展方向。本文分别从这两个方向综述了目前国外晶体硅薄膜电池制备技术的最新进展，最新实验室研究结果。报导了晶体硅薄膜电池商业化进展状况，指出了晶体硅薄膜电池实现产业化必须解决的问题。     

自动化服务器对客户端访问的实现

用一个实例说明如何用Delphi来实现服务器对客户的访问。     

同沉积断裂带砂砾岩隐蔽油藏研究——以东营凹陷胜北断裂带为例

以构造层序、层序地层分析和基准面分析原理为手段,利用高分辨率地震剖面、测井、岩相等资料,重点研究了东营凹陷胜北断裂带深断陷型湖盆层序中的低位体系域砂体沉积特征、发育规律及其石油地质意义.研究表明,沙三期胜北断裂带的活动形成了断裂坡折带,该坡折带控制沙三段层序低位体系域冲积扇、扇三角洲、浊积扇和小型三角洲等砂体的发育及时空展布.断裂坡折带控制的低位体系域砂体位于层序底部、最大湖泛面之下,成藏条件优良,是隐蔽油气藏勘探的主要方向.      

腐蚀环境中海工混凝土抗氯离子侵蚀性

模拟我国南方沿海浪溅区和水位变动区的海工钢筋混凝土结构物的腐蚀环境，对掺入粉煤灰和矿渣的混凝土抗氯离子侵蚀性进行了试验。结果表明，在水灰比相同的条件下，加掺和料的混凝土抗氯离子侵蚀性高于普通混凝土。     

In situ polymerization and characterization of polyester‐based polyurethane/nano‐silica composites

Polyester‐based polyurethane/nano‐silica composites were obtained via in situ polymerization and investigated by Fourier‐transform infrared spectroscopy (FTIR), or FTIR coupled with attenuated total reflectance (FTIR‐ATR), Transmission electron microscopy (TEM), atomic force microscopy (AFM), an Instron testing machine, dynamic mechanical analysis (DMA) and ultraviolet‐visible spectrophotometry (UV‐vis). FTIR analysis showed that in situ polymerization provoked some chemical reactions between polyester molecules and nano‐silica particles. FTIR‐ATR, TEM and AFM analyses showed that both surface and interface contained nano‐silica particles. Instron testing and DMA data showed that introducing nano‐silica particles into polyurethane enhanced the hardness, glass temperature and adhesion strength of polyurethane to the substrate, but also increased the resin viscosity. UV‐vis spectrophotometry showed that nano‐silica obtained by the fumed method did not shield UV radiation in polyurethane films. Copyright © 2003 Society of Chemical Industry     

龙滩大坝碾压混凝土高温季节施工的温控措施

龙滩水电站地处桂西北,多年平均气温20.1℃,每年高温季节长达7个月以上,而龙滩碾压混凝土重力坝施工要求全年进行,因此解决高温季节的施工难题是保证龙滩工程顺利建设的首要前提。为此,着重研究了原材料选择、配合比设计、降温防护、快速施工、通水冷却等多项措施,为龙滩工程在高温季节下,碾压混凝土重力坝的施工提供了保证。