Synthesis and Morphology of TiO2 Nanotube Arrays by Anodic Oxidation Using Modified Glycerol-Based Electrolytes

Titanium dioxide (TiO₂) nanotube arrays were prepared by electrochemical anodization of titanium sheets in the glycerol 176 mL/H₂O 44 mL/NH₄F 0.5 wt% electrolytes modified with H₂SO₄ and NaAc addition. The surface morphologies, average inner diameter, and the length of the nanotube arrays changed with the solution pH in the range from 5.6 to 4.0 by adding H₂SO₄. A uniform surface morphology of the nanotubes with average inner diameter of ∼80 nm and a length of ∼1000 nm was obtained when the solution pH was 5.0. The growth rates of the nanotubes were remarkably enhanced by NaAc addition in the range of 0.04–0.14 M . With NaAc addition of 0.10 M , the length of the nanotube arrays reached 4.16 μm after an 8-h anodization, increasing 3.23 μm compared with no NaAc addition. The relationship between solution pH and growth of TiO₂ nanotubes was analyzed by current–time curves, solution electrical conductivities, and scanning electron microscopy (SEM), and the role of NaAc was also discussed based on SEM and solution electrical conductivities.     

High catalytic activity of PdOx/MnO2 for CO oxidation and importance of oxidation state of Mn

PdO_x/MnO₂ has been examined as a catalyst for CO oxidation using a conventional flow reactor at reaction temperatures between 50 and 150°C. In the reaction conditions of GHSV (gashourlyspacevelocity) of 1.22 × 10⁵/h and CO concentration of 2000 ppm, PdO_x/MnO₂ showed higher catalytic activity compared with PdO_x/Mn₂O₃, which had been previously reported as an effective catalyst due to the cooperative action of Pd and Mn₂O₃ for this reaction. The reason for higher activity of PdO_x/MnO₂ than PdO_x/Mn₂O₃ has been investigated using TPR (temperatureprogrammed reduction) and XPS studies. TPR showed that PdO_x/MnO₂ could be reduced by CO at much lower temperature than PdO_x/Mn₂O₃. During the experiment of reduction and oxidation, XPS showed that the valence of Mn in the PdO_x/MnO₂ was between 4+ and 3+, which is higher than that of Mn in the PdO_x/Mn₂O₃ catalyst of which the valence has been reported to be between 3+ and 2+. It is known that in this catalyst system the support supplies oxygen onto Pd, where the oxidation occurs with adsorbed CO, and the ability of the support to provide oxygen improves the performance of the catalyst. Therefore, it was concluded that the readiness of MnO₂ to be reduced with maintaining a higher oxidation state showed higher CO oxidation activity than Mn₂O₃ as support for PdO_x.     

Performance evaluation of anti-radiation based on the gamma degradation process

In the environment of space radiation, the high-energy charged particles or high-energy photons acting on a spacecraft can cause either temporary device degradation or permanent failure. The traditional probability model is difficult to obtain reliable estimation of unit radiation resistance performance with small samples. Considering that different products will change differently after high-energy particle radiation, we construct a model based on the gamma degradation process. This model can efficiently describe the law of unit radiation resistance variation with the total radiation dose levels under the effect of the total dose and displacement damage. Finally, the proposed model is used to assess the anti-radiation performance of the N-channel power MOSFET device STRH60N20FSY3 produced by STM to obtain average unit radiation resistance, survival probability, survival function, etc.     

新日铁高炉冷却壁技术的进展及其在宝钢的应用

从结构、材料、冷却方式和壁厚等方面介绍了新日铁高炉用冷却壁的1～4代演变过程，同时简述了宝钢引进的第3代冷却壁制造技术及其应用概况。认为今后大型高炉冷却系统的设计会向冷却壁倾斜。     

含Cl^-溶液中SO4^2-对316不锈钢临界点蚀温度的影响

采用外加恒电位下腐蚀电流-温度扫描方法研究了在0．5％Cl^-溶液中，SO4^2-浓度对316不锈钢点腐蚀行为的影响．结果表明，随着SO4^2-浓度的增加，钝化电流增加，开路电位降低．当SO4^2-浓度低于0．42％时，316不锈钢的临界点蚀温度比不存在SO4^2-时的临界点蚀温度低；当SO4^2-浓度大于0．42％时，临界点蚀温度比不存在SO4^2-时的临界点蚀温度高．从离子竞争吸附的角度进行分析，对SO4^2-加速与抑制点蚀两种作用规律的形成原因进行了解释．     

汽车用磁性材料和磁性器件

汽车前灯装置用的磁性材料为了减少汽车夜间行驶的交通事故,一个重要的办法就是提高驾驶员的眼睛的夜间辨认能力,这就要在汽车上安装高亮度前灯（High Intensity Dischrge Lamp,简写为HID灯）,这种灯较传统用的卤灯省电且更亮,这样驾驶员就能借助它容易发现路面障碍物.HID灯是水银灯、金属卤化物灯、高压钠灯的统称.其中金属卤化物灯用作汽车前灯有2个缺点：①从点灯至达到规定亮度需数分至数十分钟;②一旦灯灭,再点着也必需数分至数十分钟.为克服这两点缺点在其点灯电路中必须设置变换器和触发器.     

Redundancy filtering and fusion verification for video copy detection

Multimedia Systems - Recently, the frame fusion based video copy detection scheme provides a possibility to detect copies in a continuous query video stream. However, its computational complexity...     

可组合的描述符泄露类型检查

应用程序通过操作系统的系统调用对文件描述符进行操作并管理文件资源。如果应用程序对资源描述符的管理出现错误并发生描述符泄漏,会严重影响系统的可用性。据此,提出了一种检查程序是否会导致描述符泄漏的类型系统,给出了描述符操作方法的语义和类型约束,证明了类型系统的可靠性定理。此外,还初步讨论了该类型系统在并发程序下的扩展。     

探析西方现代主义景观设计的起源

现代主义景观的兴起源于工业化生产,工业革命的快速发展对自然、社会,以及人类身心造成了严重的影响。现代主义景观作为一种协调人与自然之间关系的媒介,其产生与发展经历了漫长的过程,并受到了方方面面的影响,是一种根植于早期景观设计基础上的现代社会文化产物。了解西方现代主义景观设计的形成初始,有利于为当代景观设计提供思想溯源,具有一定学术意义。