Influence of Reaction Parameters on the Hydrogenolysis of Hydroxymatairesinol Over Carbon Nanofibre Supported Palladium Catalysts

The density functional theory (DFT/B3LYP) calculations were applied to investigate the interaction of a Pt₆ particle with the ZSM-5 zeolite framework. The electronic structure of the metal particle is strongly affected by the interaction with basic framework oxygens and acid sites of the zeolite support. Adsorption on basic sites (E_ads = 6 kcal/mol) favors the formation of the electron enriched metal cluster. Interaction of the platinum cluster with the acid site characterized by stabilization energy of 47 kcal/mol results in oxidation of the metal particle and suppression of Brønsted acidity of the support. The hypothesis is put forward that the oxidized platinum particle can function as an active site for the alkane isomerisation on platinum supported high silica zeolites.     

Phase states of a two-dimensional non-Heisenberg ferromagnet

The effects of a biquadratic exchange and an external magnetic field on the phase states of a twodimensional non-Heisenberg ferromagnet have been studied with allowance for magnetoelastic and magnetodipolar interactions.     

The Geometry of D-Decomposition of a Two-Dimensional Plane of Arbitrary Coefficients of the Characteristic Polynomial of a Discrete System

The D-decomposition of a two-dimensional plane of arbitrary coefficients of a discrete characteristic polynomial is studied. The geometry of the boundary curve is analyzed and its common properties with a linear discrete system of any order are described. Example are given.     

Neural-Net Analysis of the Plasticity of ÉP-450 Ferrite–Martensite Steel with Different Alloying Element Concentrations

The results of a computational experiment with a neural-net model simulating the effect of the chemical composition on the plastic properties of ÉP-450 steel are presented. It is shown that computer-aided development of reactor steel with prescribed properties is, in principle, possible.     

SVBR-75/100 Multipurpose Modular Low-Power Fast Reactor with Lead–Bismuth Coolant

The results of development work on the SVBR-75/100 modular fast reactor cooled by lead–bismuth coolant are presented. The design is based on the experience gained operating reactors in nuclear-powered submarines. The SVBR-75/100 reactor is inherently safe because of its low power, the chemical inertness and high boiling point of the lead–bismuth coolant, and the integrated basin-type arrangement of the first-loop equipment. This eliminates the conflict between the safety and economic requirements that is characteristic of conventional-type reactors. The lower power makes it possible to build the reactor in a factory and deliver the reactor using any form of transportation to the nuclear power plant site. All safety systems operate passively. Most of these systems are used as normal-operating systems. This creates conditions for multipurpose applications of such reactor modules in developed and developing countries.     

Reliability of the Coolant Flow Rate Measuring System at the Ignalina Nuclear Power Plant

Age assessment and control of the reliability of the coolant flow-rate measurement system of the RBMK-1500 reactor at the Ignalina nuclear power plant are examined. A statistical analysis is made of the data obtained from measurements of the techanical characteristics of SHADR-32M flow meters. A mathematical model of the aging of flow meters and reliability estimates is constructed. A strategy is developed for replacing SHADR; this strategy makes it possible to support the required relaibility of the entire coolant flow-rate measurement system.     

Analysis and comparison of two-dimensional permanent-magnet arrays for planar motor

This paper investigates three kinds of permanent-magnet arrays used in planar motors with polarity centers distributed in the lattices of a matrix. The magnetic field of every kind of magnet array is analyzed by analytical methods. First, we give a Laplace equation of magnetic scalar potential and a series of boundary conditions. Then, we derive the analytical expressions of magnet field strength and magnet flux density in the air gap of each kind of magnet array by the method of separation of variables. Finally, we compare the three types of magnet arrays on the basis of the analytical solutions.     

Fault-aware Communication Mapping for NoCs with Guaranteed Latency

As feature sizes shrink, transient failures of on-chip network links become a critical problem. At the same time, many applications require guarantees on both message arrival probability and response time. We address the problem of transient link failures by means of temporally and spatially redundant transmission of messages, such that designer-imposed message arrival probabilities are guaranteed. Response time minimisation is achieved by a heuristic that statically assigns multiple copies of each message to network links, intelligently combining temporal and spatial redundancy. Concerns regarding energy consumption are addressed in two ways. First, we reduce the total amount of transmitted messages, and, second, we minimise the application response time such that the resulted time slack can be exploited for energy savings through voltage reduction. The advantages of the proposed approach are guaranteed message arrival probability and guaranteed worst case application response time.     

Hydrogen degradation of steels in gas mains after long periods of operation

We study the degradation of the mechanical and corrosion properties of 17G1S steel in gas mains as a result of operation for 28–40 yr. We reveal the simultaneous decrease in its strength and hardness, on the one hand, and impact toughness and crack resistance, on the other hand. The indicated parameters prove to be most sensitive to the in-service degradation of the metal. The degradation of steel leads to the increase in the strain-hardening coefficient and the appearance of the yield plateau in the tensile stress-strain diagram and causes the appearance of sensitivity to hydrogen embrittlement increasing in the process of operation. We analyze the role of absorbed hydrogen affecting the mechanism of strain aging and responsible for the appearance of defects. It is shown that the polarization resistance can be used not only for monitoring of the corrosion state of gas pipelines but also for the prediction of changes in their mechanical properties in the process of operation. __________ Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 43, No. 5, pp. 97–104, September–October, 2007.