Rational design on photoelectrodes and devices to boost photoelectrochemical performance of solar-driven water splitting: a mini review

As an eco-friendly, efficient, and low-cost technique, photoelectrochemical water splitting has attracted growing interest in the production of clean and sustainable hydrogen by the conversion of abundant solar energy. In the photoelectrochemical system, the photoelectrode plays a vital role in absorbing the energy of sunlight to trigger the water splitting process and the overall efficiency depends largely on the integration and design of photoelectrochemical devices. In recent years, the optimization of photoelectrodes and photoelectrochemical devices to achieve highly efficient hydrogen production has been extensively investigated. In this paper, a concise review of recent advances in the modification of nanostructured photoelectrodes and the design of photoelectrochemical devices is presented. Meanwhile, the general principles of structural and morphological factors in altering the photoelectrochemical performance of photoelectrodes are discussed. Furthermore, the performance indicators and first principles to describe the behaviors of charge carriers are analyzed, which will be of profound guiding significance to increasing the overall efficiency of the photoelectrochemical water splitting system. Finally, current challenges and prospects for an in-depth understanding of reaction mechanisms using advanced characterization technologies and potential strategies for developing novel photoelectrodes and advanced photoelectrochemical water splitting devices are demonstrated.     

固体碱催化法合成壬基酚甲醛树脂的工艺研究

本文研究了以壬基酚和甲醛为原料,固体碱为催化剂,合成壬基酚醛树脂的新工艺。对酚醛比、催化剂用量、反应时间、反应温度四个影响因素进行了正交优化实验,确定了优化合成工艺,得到了黏度为20000 mPa·s左右的壬基酚醛树脂,该工艺稳定可靠。     

分布式离散事件系统的模式故障预测研究

针对分布式离散事件系统,提出了一种模式故障预测方法.首先对分布式离散事件系统的模式故障可预测性进行形式化.通过构造一个模式故障识别器,从系统所有行为中识别出所发生的模式故障,并针对分布式系统的不同观测点构造不可观测闭包.在此基础上,联合各站点观测到的事件序列构造出模式故障预测验证器,解决了分布式离散事件系统的模式故障预...     

基于 LeNet5like 的迁移学习风电机组叶片覆冰故障诊断研究

针对海上风电场和高海拔地区风机机组的叶片覆冰故障模型精度低、建模速度慢等问题,提出一种基于 LeNet5like 的 迁移学习风电机组叶片覆冰故障诊断方法。 首先,整合监控和数据采集系统的记录数据与风机覆冰情况进行预处理,建立训练 数据集;其次,基于改进后的 LeNet5like 网络构建覆冰故障诊断模型,提取数据集中多变量间的相关性特征信息;然后,经网络 参数微调迁移学习对模型进行训练,实现对其他风机覆冰故障诊断模型的快速建立;最后,经实验验证,该模型覆冰故障诊断准 确率为 98. 90% ,较无迁移模块网络训练时间缩短 28 s,提升约 15. 91% ,验证了基于 LeNet5like 的迁移学习风电机组叶片覆冰 故障诊断方法的精确性和快速性。     

悬臂爬升模板支撑结构在不同风向作用下的受力分析

近几年对于高层建筑、高墩建筑的施工越来越普遍,爬升模板在高墩中的使用越来越多,爬升模板结构的受力对整体施工有着重大的意义.结合现场施工桥梁高墩的悬臂爬升模板支撑结构在不同风向作用下受力进行计算,验算模板结构在施工过程中的稳定性,确保施工安全,浇筑混凝土结构稳定,可为此类工程施工提供参考.     

Lignin-based Hydrogels for Biological Application

Lignin is the most abundant aromatic compound found in nature.The rich functional groups of lignin are responsible for its antibacterial,antioxidant, anti-ultraviolet, and biocompatible properties. As modified lignin has a higher molecular weight, water solubility, and better surface activity, it is a good candidate for the construction of new biological materials. Ligninbased hydrogels are a type of functional materials with broad application prospects in the biomedical field. This review aimed...     

Discovery and characterization of tyrosinases from sea anemone pedal disc

Abstract

The formation of underwater adhesion is a complicated physiological process and many different types of enzymes are found to be essential apart from structural proteins. Previous studies have shown that various tyrosinases were present in marine adhesives, but little information is available about the over-expression and enzymatic characterization of these enzymes. Specifically, this study first identified four significantly up-regulated tyrosinases in the pedal disc of Haliplanella luciae by means of multi-omics technology, and made preliminary bioinformatics predictions. Sequence alignment showed that the Tyr1_Hl contained six conserved His residues that bind to copper ions, of which a tyrosinase with diphenolase activity named as Tyr1_Hl^Δ, was expressed in Escherichia coli BL21 (DE3) cells and purified by affinity chromatography. Enzymatic characterization showed that the activity of Tyr1_Hl^Δ was Cu²⁺ dependent and maximum catalytic activities were in 20?mM Tris–HCl (pH 8.0) at 37?°C. In summary, we identified novel tyrosinases in the pedal disks of sea anemone for the first time and the Tyr1_Hl^Δ was successfully recombinant expressed. Our study will provide basis for future exploration of bio-adhesion mechanism and design of bio-adhesives derived from sea anemones.     

某含锌锡多金属硫化矿石锌浮选试验研究

某含锌锡多金属硫化矿石Zn、Sn、Fe、S含量分别为6.04%、1.05%、29.33%、19.08%,锌主要以铁闪锌矿、闪锌矿的形式存在,锡主要以锡石的形式存在,铁主要以黄铁矿、磁黄铁矿等形式存在,其中的金属矿物共生关系密切,相互包裹现象普遍。为确保不影响后续选锡,对锌浮选流程进行了试验研究。结果表明：矿石在磨矿细度为-0.074 mm占80%的情况下,采用预先脱硫—锌硫混浮再分离流程处理,在选择硫酸铜为锌矿物活化剂、丁基黄药为捕收剂、松醇油为起泡剂、石灰为黄铁矿抑制剂的情况下,经1段脱硫、2粗1扫锌硫混浮、1粗2精锌硫分离,锌硫分离精选尾矿与锌硫混浮扫选精矿2次精选后锌硫分离,最终获得锌精矿Zn品位47.06%、回收率90.76%,试验指标良好。