Structure and composition of guanidine acrylate, guanidine methacrylate, their homopolymers, and copolymers with diallyldimethylammonium chloride

Structures and compositions of the monomers guanidine acrylate and guanidine methacrylate, their homopolymers, and copolymers with diallyldimethylammonium chloride enriched in acrylate comonomer units were determined. It was shown that ampholytic copolymers, owing to their ionic nature, contained comonomeric guanidine acrylate or methacrylate units and diallyldimethylammonium chloride units, as well as the acrylate comonomer with the diallyl counterion and polymeric acrylate and diallyl ion pairs. It follows from IR and ¹H NMR data that guanidine methacrylate has the same structure (with two hydrogen bonds) in the solid state and in solutions. Guanidine acrylate structures in the solid state and in dimethylsulfoxide are identical and analogous to guanidine methacrylate structure in this solvent. In water, the guanidine acrylate structure has another type of hydrogen bonding (with one hydrogen bond, where the proton is shifted toward the guanidine group). These features of hydrogen bonding of guanidine acrylate and guanidine methacrylate are also retained in their homopolymers and copolymers with diallyldimethylammonium chloride. It was shown that the thermal stability of the copolymers was higher than that of their homopolymers, confirming the formation of intramolecular ion pairs of oppositely charged units of ampholytic copolymers. Moreover, the thermal stability of guanidine methacrylate-diallyldimethylammonium chloride copolymers is higher than that of guanidine acrylate-diallyldimethylammonium chloride copolymers.     

Transmission study of germanium using free-electron laser

We have measured optical transmittance through germanium in the mid-infrared region at room temperature using the Osaka free-electron laser (FEL). In spite of the fact that germanium is transparent in the mid-infrared region, we observed strong suppression of optical transmission under high-intensity FEL excitation. We found that the observed suppression is due to optical absorption in germanium. To analyze the experimental results, we have calculated optical transmittance of germanium within Keldysh theory     

On the nonuniformity of a capillary flow

It is established that the capillary rise of a liquid has an oscillatory character, in contrast to the commonly accepted opinion that a vertical capillary is filled at a monotonically varying velocity. The value of the tangential shear stress arising in an ascending liquid is evaluated for ethyl alcohol and distilled water.     

Experimental Electronuclear Setup at the Institute of Theoretical and Experimental Physics

The purpose and current construction status, at the Institute of Theoretical and Experimental Physics, of an experimental electronuclear setup, combining a pulsed proton linear accelerator (36 MeV, 0.5 mA) and a subcritical blanket thermal-power assembly 100 kW, are discussed. The main equipment is already available or is being built in industry. The setup can be used to investigate the dynamics of the interaction of a linac–driver and a subcritical reactor and problems concerning the accelerator–driver and the target–blanket assembly. The proton beams and neutron fluxes will be used for applied purposes. In the future it will be possible to increase substantially the current and energy of the proton beam.     

Vapor pressure and thermodynamic functions of TeI<Subscript>4</Subscript> and its decomposition products

Using a flow method, we have measured the vapor pressure of tellurium tetraiodide, an attractive reagent for chemical vapor deposition technology. The results, combined with earlier tensimetric data, have been used to evaluate the basic thermodynamic functions of TeI₄ and its thermolysis products.     

The structure and properties of a Cr<Subscript>3</Subscript>C<Subscript>2</Subscript>-Ni coating deposited by a high-velocity plasma jet onto a copper substrate

Chromium carbide-nickel coatings were deposited onto a technical grade copper substrate by means of a high-velocity plasma jet of a plasmatron operating in specially selected regimes. An analysis of the coatings showed evidence of the formation of a Ni-based solid solution, a complex chromium carbide (Cr₇C₃), and an fcc crystal phase with a lattice parameter of 3.614 Å. The surface of the coatings exhibits a characteristic relief resulting from a dynamic interaction between melted and fused particles of the initial powder. The local hardness on some areas of the surface and in depth of the coating reaches 66±4.5 HRC, while the coating adhesion strength varies from 25 to 300 MPa.     

Nucleation of Gas Bubbles in Extrusion Foaming of High-Pressure Polyethylene

The nucleation of gas bubbles in extrusion foaming of high-pressure polyethylene is considered. Experiments show that undissolved gas microbubbles in the solution being foamed can have a significant effect on the number density of pores in the foam. A simple model for estimating the number density of supercritical nuclei is proposed. The effect of the time of mixing of gas and polymer in the extruder, the talc concentration, and the geometric characteristics of the nozzle on the number density of pores in the foam is analyzed.     

Trellis and convolutional precoding for transmitter-based interference presubtraction

This paper studies the combination of practical trellis and convolution codes with Tomlinson-Harashima precoding (THP) for the presubtraction of multiuser interference that is known at the transmitter but not known at the receiver. It is well known that a straightforward application of THP suffers power, modulo, and shaping losses. This paper proposes generalizations of THP that recover some of these losses. At a high signal-to-noise ratio (SNR), the precoding loss is dominated by the shaping loss, which is about 1.53 dB. To recover shaping loss, a trellis-shaping technique is developed that takes into account the knowledge of a noncausal interfering sequence, rather than just the instantaneous interference. At rates of 2 and 3 bits per transmission, trellis shaping is shown to be able to recover almost all of the 1.53-dB shaping loss. At a low SNR, the precoding loss is dominated by power and modulo losses, which can be as large as 3-4 dB. To recover these losses, a technique that incorporates partial interference presubtraction (PIP) within convolutional decoding is developed. At rates of 0.5 and 0.25 bits per transmission, PIP is able to recover 1-1.5 dB of the power loss. For intermediate SNR channels, a combination of the two schemes is shown to recover both power and shaping losses.