分子结构、相容性和流变性对抗冲共聚聚丙烯中分散颗粒形态的影响

分散颗粒形态对抗冲共聚聚丙烯的冲击强度有较大影响。综述了影响分散颗粒形态的因素,包括等规聚丙烯的分子结构和丙烯均聚工艺、等规聚丙烯和乙丙橡胶之间的相容性、长丙烯链段乙烯-丙烯嵌段共聚物的分子结构及其对等规聚丙烯和乙丙橡胶之间相容性的增强作用、长乙烯链段乙烯-丙烯嵌段共聚物的分子结构及其对乙丙橡胶流变性的干扰等。调整共聚反应的乙烯与烯烃摩尔比可以有效改善抗冲共聚聚丙烯分散颗粒的形态。     

四川盆地中江气田成藏条件及勘探开发关键技术

川西坳陷东部斜坡的侏罗系油气藏总体表现出上三叠统须家河组五段和下侏罗统优质烃源岩"双源"供烃、多期多套叠置河道规模砂岩储集体发育、烃源断层持续活动供烃以及古今断裂-砂体配置条件有利的特征,具备形成致密砂岩大气田的成藏地质条件与源-储时空组合.通过总结分析中江气田的成藏地质条件,提出了中江气田中侏罗统沙溪庙组油气藏为"河...     

准噶尔盆地环玛湖凹陷二叠系砂砾岩储层沸石类胶结物的形成及石油地质意义

准噶尔盆地环玛湖凹陷二叠系砂砾岩储层中广泛发育沸石类胶结物。X射线衍射、铸体薄片、扫描电镜、包裹体测温和能谱分析等分析结果表明,研究区沸石类胶结物中浊沸石最为发育,其次为片沸石,方沸石含量较低,其形成条件为富含Na⁺、Ca²⁺、Mg²⁺的弱碱性还原环境。研究区沸石矿物的晶型较为完整,罕见方沸石与片沸石、浊沸石共生,也没有发生方沸石向片沸石和浊沸石转化的现象,表明沸石矿物是在成岩阶段从孔隙水中自形结晶形成;方沸石形成于早成岩阶段A期,其形成温度较低,为60~70℃,片沸石和浊沸石形成于早成岩阶段B期,片沸石形成温度为90~100℃,浊沸石形成温度为100~110℃。岩石学及矿物学特征表明,研究区沸石类胶结物更易发育于杂基含量较低、分选和磨圆度较好、原生孔隙发育、孔隙水易于流动的扇三角洲前缘水下分流河道砂砾岩中。早期形成的方沸石易发生溶蚀但其含量较低,片沸石和浊沸石形成时间较晚,更接近油气充注时期,且稳定性较高,一般很难发生强烈溶蚀,因此研究区沸石的溶蚀作用对储层的储集性能改善不大。研究区压实作用强烈,适度含量的沸石类胶结物可有效抵御砂砾岩储层的压实作用,保留良好的剩余粒间孔及连通的孔隙喉道,为后期酸性流体的进入提供必要的空间基础,有利于溶蚀作用;大量沸石胶结会破坏砂砾岩原有的储集空间,堵塞孔隙喉道,阻碍后期酸性流体的进入,使储层孔隙度和渗透率大幅度降低,因而不利于储层的改善。     

东海盆地西湖凹陷平北斜坡带平湖组煤系原油地球化学特征与油-源精细对比

东海盆地西湖凹陷平北斜坡带平湖组煤系原油性质及分布规律复杂,烃源岩纵、横向沉积环境及生物来源非均质性强,具有斜坡带和西次凹多源供烃特征.将地质与地球化学相结合,进行了原油类型划分与油-源精细对比,梳理了原油分布与生烃次洼的关系.结果表明:平北地区原油以凝析油为主,含少量轻质油和正常原油,根据生物标志化合物特征,可划分为...     

深水盐下湖相碳酸盐岩缝洞地震预测

桑托斯盆地F油田位于巴西深水区域的盐岩之下,具有埋藏深、岩性多样、非均质性强的特点。与常规的以孔隙型为主的储层和中国西部“串珠状”的大型溶洞储层不同,研究区碳酸盐岩为深水盐下湖相碳酸盐岩,其溶蚀孔洞孔径小、裂缝类型多,导致地震响应特征极其不明显,常规缝洞预测方法不适用。另外,受上覆巨厚盐岩层的影响,缝洞发育储层段的地震资料分辨率低,增加了利用叠后地震方法预测其分布规律的难度。因此,针对研究区缝洞发育特点,采取井震相结合的思路,以消除泥岩及火成岩岩性干扰为前提,首先进行地震资料优化处理,然后充分利用岩心、FMI测井等资料以及生产漏失等信息,综合分析地震异常可能表达的地质信息,探索了一套适用于深水盐下多种岩性发育背景的小尺度湖相碳酸盐岩缝洞储层地震预测方法。该方法明确了裂缝与孔洞的敏感地震属性,通过联合构造应力场进行裂缝预测,结合波阻抗、孔隙度及CGR等地震反演结果,开展溶蚀孔洞预测,取得了良好的预测效果,对湖相碳酸盐岩缝洞储层预测研究有借鉴意义。     

某型雷达板级模块测试适配器的设计与实现

某型雷达电路板测试适配器需要对二十多种电路板进行功能测试,被测电路板信号时序复杂,接口定义不统一,给适配器设计带来困难。本文采用通用适配器设计方案成功的解决了问题,实践证明,该适配器设计灵活,大大简化多电路板检测适配器的设计难度,具有一定的工程借鉴价值。     

Development of SnAg-based lead free solders in electronics packaging

Lead free solder alloys for electronic assembly is being driven by environmental and health concerns regarding toxicity of lead and, more importantly, by the perceived economic advantage of marketing “green” products. Of the currently available lead free solders, SnAg has the greatest potential. In this solder, the Ag₃Sn compound is distributed in a eutectic network throughout the β-Sn matrix and these results represent mechanical strength. In order to further improve the microstructures and properties of SnAg-based alloys, alloying elements such as rare earth, Zn, In, P, Cu, Ni and particles such as ZrO₂, POSS are selected to meet the requirement of high reliability of high-density electronics devices. For SnAg solder bearing rare earth (Ce and La), the creep-rupture life of solder joints can be remarkably increased up to four times more than that of the original SnAg solder joints at room temperature, meanwhile, rare earths can dramatically reduce the thickness of IMCs layer at solder/pad interfaces and also refine the microstructure of the alloy which results in the enhancement of mechanical properties of the SnAg solder. Moreover, the addition of ZrO₂ nanoparticles significantly refined the size of Ag₃Sn due to the adsorption effect of the ZrO₂ nanoparticles. This paper summarizes the effects of alloying elements and particles on the wettability, mechanical properties, creep behavior, microstructures, etc. of SnAg-based lead free solder alloys.     

基于双态混沌PSO的机载激光通信视轴稳定控制

机载空间激光通信视轴稳定是激光通信链路建立的前提。在视轴稳定平台中应用自抗扰控制方法取得了良好的控制效果,但自抗扰控制需调整参数众多且缺乏规范的调整手段。针对自抗扰控制调参难的问题,本文提出了一种利用双态混沌粒子群算法优化自抗扰控制参数的方法。仿真结果表明,与PSO-PID控制方法相比,该方法具有更快的响应速度,更强的抗干扰能力和更好的鲁棒性。     

Single-Component Photochromic Smart Semiconductor with Photoswitchable Fast Bidirectional Electron Transfer

Introduction of photochromic properties into semiconductors confers semiconductors with smart behaviors, color-related applications, and new modulation approaches. Photochromophores with electron-transfer (redox) behavior, such as viologen and naphthalene diimide, are ideal functional motifs to design photochromic semiconductors owing to good adaptability to the solid matrix, but their reverse reactions are exclusively realized by the thermal mode, which is slow (in dozens of seconds or longer) and thus significantly hinders real applications in the fields that require high-speed switching. This study reveals that photoexcitation in the electronic absorption band of the π-aggregate of viologen cation radicals can successfully trigger reverse electron transfer quickly (in 1 s with a continuous-wave 808 nm laser at a power density of 5 W cm⁻²; the photothermal effect is excluded), and the first single-component all-optically photochromic semiconductor is accordingly discovered. This discovery breaks through a traditional concept that reverse reactions of viologen compounds can not be triggered by the light, and provides a potential approach to realize all-optical switch of single-component photochromic smart semiconductors based on electron-transfer photochromic functional motifs.     

球注法装药与注装法装药的工艺特性

针对使用注装法进行弹药装药的现状,对注装法装药和球注法装药的工艺特性进行研究。从装药方法特点、工艺参数、装药质量和安全自动化程度等方面对球注法装药和注装法装药进行分析比较,并根据这2种装药方法各自的特点及国内兵工行业发展现状,分析其未来的发展趋势。研究结果表明:球注法装药质量较高,生产周期短,操作简单,具备自动快速装药生产能力;注装法装药在一次装药过程中需要更换多次注装,距离全自动化还有一定距离。因此可以得出结论,球注法装药的工艺特性优于注装法装药。