双能X射线骨密度仪测定技术研究

以Ｌｕｎａｒ公司ＤＰＸ－Ｌ型双能Ｘ射线骨密度仪为例，研究引起测量误差的主要因素并提出质控措施。用自检模块、腰椎体膜评定仪器的体外测量精度好于１％。对１０位志愿者重复２次测量，体内精度对腰椎，ＭＰＤ（平均百分差）为０．４６，ＣＶ（变异系数）为０．７５；对股骨颈，ＭＰＤ为１．２６、ＣＶ为０．４７；Ｗａｒｄ’ｓ三角区ＭＰＤ为２．０１、ＣＶ为１．１４；大转子ＭＰＤ为１．６６、ＣＶ为０．７２。扫描图像由２位     

浅谈化工建设项目竣工预验收程序和内容

结合作者的实际工作 ,总结了对工程建设实施“三道质量控制工序”的经验 ,强调了过程质量控制的重要性 ,较为系统地介绍了化工建设项目预验收工作的程序和内容     

聚氨酯防水涂料及其市场发展概况

聚氨酯防水涂料是当今最有效的柔性防水材料之一，介绍了聚氨酯防水涂料的发展状况，并对其市场前景进行了展望。     

我国烧碱市场分析与展望

回顾了2005年我国烧碱的生产与市场消费情况,分析了2006年国内烧碱市场形势,对“十一五”期间我国烧碱市场总体趋势进行了展望。     

A spectroscopic study of the self-association and inter-molecular aggregation behaviour of pH-responsive poly(l-lysine iso-phthalamide)

The pH mediated intra-molecular association and inter-molecular aggregation of a range of amphiphilic poly(l-lysine iso-phthalamide) polymers have been investigated in aqueous solution over a range of pH values and concentrations. The desired functionality of these novel bioresponsive amphiphilic polymers was achieved by incorporating pendant hydrophilic carboxyl groups along the polymer backbone, via the l-lysine moiety, balanced by a degree of hydrophobicity introduced via the iso-phthaloyl moiety. Incorporation of low levels of bis-functional Cy3 (poly-Cy3) and/or Cy5 dye (poly-Cy3/5 or poly-Cy5) co-monomers in the responsive polymer backbone allowed detailed probing of the pH mediated hydrophobic association using a combination of optical spectroscopic techniques. Both steady-state fluorescence spectroscopy and fluorescence lifetime measurements of poly-Cy3 revealed a conformational transition at pH 4.5. Thus, below a critical pH the polymer collapsed into a compact globular structure (hypercoil) bringing the fluorophore molecules into close proximity with one another. This resulted in a dramatic reduction in fluorescence intensity and fluorescent lifetime in the single fluorophore systems (poly-Cy3) accompanied by a red shift in the maximum emission wavelength. Observed redshifts in the emission maxima and enhancements of fluorescent lifetimes with increasing polymer concentration suggested the formation of polymer aggregates. Fluorescence resonance energy transfer (FRET) was measured in mixtures of single fluorophore containing poly-Cy3 (donor) and poly-Cy5 (acceptor) and dual fluorophore containing poly-Cy3 (donor)/Cy5 (acceptor) in an effort to distinguish between intra-molecular versus inter-molecular association. The relevance of the results with respect to potential in vivo applications (drug delivery and biodiagnostics) is discussed.     

Catalytic activities and properties of mesoporous sulfated Al2O3–ZrO2

Mesoporous sulfated Al₂O₃–ZrO₂ (MSAZ) catalysts with large surface areas and pore volumes after calcination at high temperature (650 °C) and with higher Al₂O₃ content than 20wt% were successfully prepared from a template of block copolymer (P84). The MSAZ catalysts were characterized by X-ray diffraction (XRD), N₂ adsorption, transmission electron microscopy (TEM), ²⁷Al magic-angle spinning nuclear magnetic resonance (MAS NMR), thermogravimetric analysis (TG–DTG), temperature-programmed desorption of ammonia (NH₃-TPD) and infrared spectra (IR) of adsorbed pyridine. It is shown that the resulting mesostructured sulfated Al₂O₃–ZrO₂ samples have a well-developed textural mesoporosity. The number of acid sites present on MSAZ catalysts is higher than that on conventional sulfated zirconia, and the former catalysts are more active than the latter one for various acid-catalyzed reactions.     

Formation of Polymeric Lewis Acid–Lewis Base Complexes with Well-defined Organoboron Polymers

The binding of Lewis bases to organoboron polymeric Lewis acids has been studied and the parameters that determine the complexation equilibrium have been investigated, which include (i) the strength of the individual Lewis acids and Lewis bases, (ii) concentration, and (iii) temperature. While the strongly Lewis acidic borane polymers poly(4-bis(pentafluorophenyl)borylstyrene) (PS-BPf) and poly(4-(di-2-thienylboryl)styrene) (PS-BTh) form isolable complexes with strong Lewis bases such as 4-t-butylpyridine (^tPy), a temperature dependent equilibrium is established with weaker bases such as THF. Similarly, the weakly Lewis acidic boronate polymer poly(4-diethoxyborylstyrene) (PS-BOEt) undergoes a temperature dependent equilibrium with the strong Lewis base 4-dimethylaminopyridine (DMAP), while poly(4-pinacolatoborylstyrene) (PS-BPin) does not significantly bind to pyridine bases. Decomplexation of PS-BTh· ^t Py is achieved by treatment with the stronger Lewis acid, B(C₆F₅)₃, thereby confirming the reversible nature of the polymeric Lewis acid–base adducts. This paper is dedicated to Professor Ian Manners in gratitude of his guidance throughout the years and recognition of his scientific accomplishments     

Seasonal evolution of the interannual variability of chlorophyll-a concentration and its forcing factors in the northwestern Pacific from 1998 to 2010

The northwestern Pacific Ocean is a complex region with significant biological spatial variations on a seasonal timescale. To investigate the joint variation patterns on both seasonal and interannual timescales, a season-reliant empirical orthogonal function (S-EOF) analysis was applied to seasonal mean chlorophyll-a concentration (chl-a) anomalies in the northwestern Pacific Ocean during the period 1998–2010. The first two dominant modes accounted for nearly 31% of the total interannual variance, with the second S-EOF mode (S-EOF2) lagging behind the first S-EOF mode (S-EOF1) by one year. S-EOF1 featured a strong variation pattern to the north of 30° N, with maximum chl-a in winter and minimum chl-a in summer. However, S-EOF2 indicated an opposite seasonally evolving pattern compared with S-EOF1, with chl-a increasing along the Kuroshio and extension current from boreal winter to autumn. Both these modes revealed significant relationships with climate-related indices. The two modes corresponded to the central Pacific (CP) La Niña developing episodes and the turnaround from eastern Pacific (EP) La Niña to CP El Niño, respectively. Both modes were associated with the cold phase of the Pacific Decadal Oscillation, which played an important role in prolonging the impact of the El Niño/Southern Oscillation on chl-a seasonal evolution from 1998 to 2010. In addition, we discuss the possible factors dominating chl-a seasonal variation, in terms of the subregions of the northwestern Pacific Ocean. In the subtropical northwestern Pacific Ocean (15° N – 30° N), the chl-a growth was primarily nutrient-limited, whereas in the mid-latitude northwestern Pacific Ocean (35° N – 50° N), the chl-a growth was mainly light-limited.     

ZrO2载体催化剂的制作及特性探讨

选择有应用价值的CuO/ZrO2体系，通过大量试验寻找到了一种以ZrO2为载体的高比表面催化剂的制备方法。     

Relations between quantum correlations,purity and teleportation fidelity for the two-qubit Heisenberg XYZ system

Quantifying and understanding quantum correlations may give a direct reply for many issues regarding the interesting behaviors of quantum system. To explore the quantum correlations in quantum teleportation, we have used a two-qubit Heisenberg XYZ system with spin–orbit interaction as a quantum channel to teleport an unknown state. By using different measures and standard teleportation protocols, we have derived the analytical expressions for quantum discord, entanglement of formation, purity, and maximal teleportation fidelity of the system. We compare their different characteristics and analyze the relationships between these quantities.