褐煤成型的研究

由于褐煤具有含水率高，灰份大，易风化，发热值低等特点，使得成型难度很大．本文重点研究水份粒度、添加剂、成型压力等对褐煤成型的影响．最佳条件：粒度＜１ｍｍ，水份１４～１６％，压力＞５０Ｔｆ，添加剂１０～２０％．     

烧结法微晶玻璃装饰板材的力学性能研究

本文研究了烧结法微晶玻璃装饰板材的密度、抗折强度等力学性能,讨论了成分、结构对密度、抗折强度的影响.     

Modeling and economic analysis of CO<Subscript>2</Subscript> separation process with hollow fiber membrane modules

The main purpose of the study was to develop a model using ASPEN and Excel simulation method to establish optimum CO₂ separation process utilizing hollow fiber membrane modules to treat exhaust gas from LNG combustion. During the simulation, optimum conditions of each CO₂ separation scenario were determined while operating parameters of CO₂ separation process were varied. The characteristics of hollow fibers membrane were assigned as 60 GPU of permeability and 25 of selectivity for the simulation. The simulation results illustrated that 4 stage connection of membrane module is required in order to achieve over 99% of CO₂ purity and 90% of recovery rate. The resulted optimum design and operation parameters throughout the simulation were also correlated with the experimental data from the actual CO₂ separation facility which has a capacity of 1,000 Nm³/day located in the Korea Research Institute of Chemical Technology. Throughout the simulation, the operating parameters of minimum energy consumption were evaluated. Economic analysis of pilot scale of CO₂ separation plant was done with the comparison of energy cost of CO₂ recovery and equipment cost of the plant based on the simulation model. This work was presented at the 6 ^th Korea-China Workshop on Clean Energy Technology held at Busan, Korea, July 4–7, 2006.     

氟磺胺草醚的毒性研究

氟磺胺草醚大鼠经口ＬＤ５０为３１６０毫克／公斤（雄），２８７０毫克／公斤（雌）：小鼠经口ＬＤ５０ ４２２０毫克／公斤（雄），４３００毫克／公斤（雌）；大鼠经皮ＬＤ５０〈４６４０毫克／公斤，对家兔眼粘膜、皮肤无明显刺激作用，Ａｍｅｓ小鼠骨髓细胞微核试验和和小鼠精子畸形试验均为阴性，无致突变作用。     

In situ compatibilization of PP/EPDM blends during ultrasound aided extrusion

Blends of isotactic polypropylene (iPP) and uncured ethylene-propylene diene rubber (EPDM) of various concentrations were treated by high power ultrasonic waves during extrusion. Die pressure and power consumption were measured. The effects of different gap sizes, blend ratios and number of ultrasonic horns were investigated. The rheological properties, morphology and mechanical properties of the blends with and without ultrasonic treatment were studied. In situ compatibilization of the blends was observed as evident by their more stable morphology after annealing, improved mechanical properties and IR spectra. The obtained results indicated that ultrasonic treatment induced the thermo-mechanical degradations and led to the possibility of enhanced molecular transport and chemical reactions at the interfaces. Processing conditions were established for enhanced in situ compatibilization of the PP/EPDM blends.     

Tungsten Oxide Nanorods Array and Nanobundle Prepared by Using Chemical Vapor Deposition Technique

Tungsten oxide (WO₃) nanorods array prepared using chemical vapor deposition techniques was studied. The influence of oxygen gas concentration on the nanoscale tungsten oxide structure was observed; it was responsible for the stoichiometric and morphology variation from nanoscale particle to nanorods array. Experimental results also indicated that the deposition temperature was highly related to the morphology; the chemical structure, however, was stable. The evolution of the crystalline structure and surface morphology was analyzed by scanning electron microscopy, Raman spectra and X-ray diffraction approaches. The stoichiometric variation was indicated by energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy.     

Blends of poly(propylene) and polyacetal compatibilized by ethylene vinyl alcohol copolymers

Polymer blends of poly(propylene) (PP) and polyacetal (polyoxymethylene, POM) with ethylene vinyl alcohol (EVOH) copolymers were investigated by differential scanning calorimetry (DSC), rheological, tensile, and impact measurements, Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). The PP–POM–EVOH blends were extruded with a co‐rotating twin‐screw extruder. The ethylene group in the EVOH is partially miscible with PP, whereas the hydroxyl group in the EVOH can form hydrogen bonding with POM. The EVOH tends to reside along the interface, acting as a surfactant to reduce the interfacial tension and to increase the interfacial adhesion between the blends. Results from SEM and mechanical tests indicate that a small quantity of the EVOH copolymer or a smaller vinyl alcohol content in the EVOH copolymer results in a better compatibilized blend in terms of finer phase domains and better mechanical properties. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1471–1477, 2003     

基于循环维纳滤波的振动信号去噪算法研究

振动信号的去噪需要在滤除噪声的同时尽可能避免相位失真。传统的锐截止低通滤波器或FIR滤波器无法在去噪效果和线性相位之间取得平衡,难以满足振动信号的去噪需求。针对这一问题,将线性相位的维纳滤波算法引入到振动信号的去噪中,并结合振动信号的循环平稳特性,形成了振动信号的循环维纳滤波算法。文中以直接维纳滤波为基础对循环维纳滤波算法的原理进行了深入分析和仿真实现,并基于实测汽轮机振动信号对算法的去噪性能进行了讨论。理论分析及算法仿真表明,循环维纳滤波算法在保证线性相位的前提下有较好的去噪效果,能够解决传统去噪算法所存在的去噪效果与线性相位难以均衡的问题。     

BaTiO3系PTCR材料电学性能的复阻抗解析

采用复阻抗解析法研究了ＢａＴｉＯ３系ＰＴＣＲ材料晶粒、晶界的电学性能。结果表明：使用欧姆接触电极的ＰＴＣＲ材料等效电路的复阻抗为：晶粒电阻呈ＮＴＣ特性，而晶界电阻天Ｔ〈Ｔｃ时呈ＮＴＣ特性，Ｔ〉Ｔｃ时呈明显的ＰＴＣ特性；ＰＴＣ效应是一种晶界效应。