全文获取类型
收费全文 | 139篇 |
免费 | 8篇 |
专业分类
电工技术 | 2篇 |
综合类 | 1篇 |
化学工业 | 59篇 |
金属工艺 | 3篇 |
机械仪表 | 2篇 |
建筑科学 | 1篇 |
能源动力 | 7篇 |
轻工业 | 27篇 |
水利工程 | 1篇 |
无线电 | 5篇 |
一般工业技术 | 21篇 |
冶金工业 | 1篇 |
原子能技术 | 2篇 |
自动化技术 | 15篇 |
出版年
2023年 | 2篇 |
2022年 | 8篇 |
2021年 | 16篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 7篇 |
2017年 | 3篇 |
2016年 | 5篇 |
2015年 | 2篇 |
2014年 | 10篇 |
2013年 | 9篇 |
2012年 | 8篇 |
2011年 | 10篇 |
2010年 | 6篇 |
2009年 | 3篇 |
2008年 | 6篇 |
2007年 | 4篇 |
2006年 | 5篇 |
2005年 | 3篇 |
2004年 | 8篇 |
2003年 | 1篇 |
2002年 | 4篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1985年 | 1篇 |
1963年 | 1篇 |
排序方式: 共有147条查询结果,搜索用时 0 毫秒
11.
Il-Cheol Yi Yumi Ha Hakcheol Lee A. Zargaran Nack J. Kim 《Metals and Materials International》2017,23(2):283-289
The present study is aimed at improving the impact toughness of 5Mn-1Al-0.5Ti steel by incorporating ferrite-martensite dual phase microstructure by intercritical annealing. Although (8-12)Mn martensitic steels usually show very low impact toughness due to the occurrence of intergranular fracture, the martensitic structure of the present 5Mn-1Al-0.5Ti steel fails by transgranular cleavage fracture due to higher grain boundary strength than matrix strength incurred by reduced Mn content and segregation of Ti along grain boundaries. Nevertheless, it still shows very poor impact toughness at room temperature due to its coarse grain size. The application of intercritical annealing, i.e., formation of dual phase microstructure, is shown to significantly decrease ductile-to-brittle transition temperature (DBTT), with only a small degradation of tensile properties; however, microstructural examinations show that most of ferrite/martensite interfaces have a character of low angle boundaries and therefore such decrease in DBTT is not necessarily due to the formation of ferrite-martensite dual phase structure, but rather to the refinement of grain size by low temperature annealing. 相似文献
12.
Ill Yong Kim Ryota Iwatsuki Koichi Kikuta Yumi Morita Toshiki Miyazaki Chikara Ohtsuki 《Materials science & engineering. C, Materials for biological applications》2011,31(7):1472-1476
Osteoconductive materials with self-setting ability have received much attention because their properties allow developing injectable materials for bone defects. Thermosensitive hydrogel with ability of bone-like apatite formation in a body environment is a candidate of injectable bone fillers with osteoconductivity because the apatite formation on materials is an essential to show osteoconduction. The present study focused on the development of a thermosensitive hydrogel through modifications of the sulphonic groups of the polysaccharide, κ-carrageenan, with potassium chloride (KCl) and calcium chloride (CaCl2). We found that the gelation temperature of κ-carrageenan solutions increased with increasing amounts of K+ ions. Apatite formation was observed on the gel after exposure to simulated body fluid for 0.5 day when the gel was prepared with a molar ratio of Ca2+/sulfonic groups = 1.5. These results indicate that a thermosensitive κ-carrageenan hydrogel with apatite-forming ability was obtained through the incorporation of K+ and Ca2+ ions into the solution. 相似文献
13.
Shimizu T Miyahayashi Y Yokoo M Hoshino Y Sasada H Sato E 《Reproduction (Cambridge, England)》2004,128(5):537-543
Growth differentiation factor-9 (GDF-9) is a growth factor secreted by oocytes in growing ovarian follicles. To investigate the ovarian function of GDF-9 in pigs, we first cloned porcine GDF-9 complementary DNA (cDNA), and then injected its gene fragments into the ovary in gilts. Porcine GDF-9 has open reading frame (ORF) homologies of 81.4%, 84.6%, 84.2%, 72.7% and 72.6% with its human, bovine, ovine, rat and mouse counterparts respectively. Regarding the deduced amino-acid sequence of the mature protein, the corresponding homologies reach 92.1%, 97.8%, 97.0%, 89.6% and 88.1% respectively. To investigate the role of GDF-9 in early folliculogenesis, the ovaries of 2-month-old prepubertal gilts were injected with GDF-9 gene fragments. The injection of porcine GDF-9 gene fragments resulted in an increase in the number of primary, secondary and tertiary follicles, concomitant with a decrease in the number of primordial follicles. These results indicated that exogenous GDF-9 can promote early folliculogenesis in the porcine ovary, and that a technique for direct ovarian injection of GFD-9 gene fragments may contribute to a novel therapy for prevention and treatment of infertility associated with ovarian dysfunction. 相似文献
14.
Structural Distortion and Compositional Gradients Adjacent to Epitaxial LiMn2O4 Thin Film Interfaces
Xiang Gao Yumi H. Ikuhara Craig A. J. Fisher Hiroki Moriwake Akihide Kuwabara Hideki Oki Keiichi Kohama Ryuji Yoshida Rong Huang Yuichi Ikuhara 《Advanced Materials Interfaces》2014,1(8)
Thin film electrode materials are key components in the development of high rate, high capacity solid‐state Li‐ion batteries. Detailed knowledge of the epitaxial film/substrate(current‐collector) interface structures, which provides insights into epitaxial growth mechanisms and the effects of microstructure on electrochemical properties, is essential for efficient materials and device design. Here we report the epitaxial growth mechanism of a typical cathodic LiMn2O4 thin film by exploring the detailed structural and compositional variations in the vicinity of a film/substrate interface using state‐of‐the‐art scanning transmission electron microscopy. Direct observation of atom columns shows the epitaxial film forms an atomically flat and coherent heterointerface with the substrate, but that the crystal lattice is tetragonally distorted with a measurable compositional gradient from the interface to the crystal bulk. The growth mechanism is interpreted in terms of a combination of chemical and physicomechanical effects, namely a complex interplay between the internal Jahn‐Teller distortions induced by oxygen non‐stoichiometry and the lattice misfit strain. 相似文献
15.
Yuji Shimada Akio Sugihara Yumi Minamigawa Kenichi Higashiyama Kengo Akimoto Shigeaki Fujikawa Sadao Komemushi Yoshio Tominaga 《Journal of the American Oil Chemists' Society》1998,75(9):1213-1217
An attempt was made to enrich arachidonic acid (AA) from Mortierella single-cell oil, which had an AA content of 25%. The first step involved the hydrolysis of the oil with Pseudomonas sp. lipase. A mixture of 2.5 g oil, 2.5 g water, and 4000 units (U) Pseudomonas lipase was incubated at 40°C for 40 h with stirring at 500 rpm. The hydrolysis was 90% complete after 40 h, and the resulting free fatty acids (FFA) were extracted with n-hexane (AA content, 25%; recovery of AA, 91%). The second step involved the selective esterification of the fatty acids with lauryl alcohol and Candida rugosa lipase. A mixture of 3.5 g fatty acids/lauryl alcohol (1:1, mol/mol), 1.5 g water, and 1000 U Candida lipase was incubated at 30°C for 16 h with stirring at 500 rpm. Under these conditions, 55% of the fatty acids were esterified, and the AA content in the FFA fraction was raised to 51% with a 92% yield. The long-chain saturated fatty acids in the FFA fraction were eliminated as urea adducts. This procedure raised the AA content to 63%. To further elevate the AA content, the fatty acids were esterified again in the same manner with Candida lipase. The repeated esterification raised the AA content to 75% with a recovery of 71% of its initial content. 相似文献
16.
Yasuo Watanabe Masahiro Yamaguchi Yumi Sanemitsu Youichi Tamai 《Yeast (Chichester, England)》1991,7(6):599-606
Plasma membrane was isolated from the salt-tolerant yeast Zygosaccharomyces rouxii and from Saccharomyces cerevisiae. The ATPase in the plasma membrane of Z. rouxii cells was a typical proton-ATPase as judged by testing with various ATPase inhibitors. There were slight differences in the pH optima of activities and in the sensitivity to sodium chloride (NaCl) and potassium chloride (KCl) of the ATPase from Z. rouxii and S. cerevisiae. The specific ATPase activity from Z. rouxii was higher in cells grown in a medium containing 2 M-NaCl than in those not containing NaCl. No in vivo activation by incubation with glucose was observed in Z. rouxii cells and the specific ATPase activity was independent of the growth phase, unlike S. cerevisiae cells. 相似文献
17.
A new method for automated planning, refinement of skeletal plans, has been developed for the problem of experiment design in the domain of molecular biology. The method resulted from a study of the problem-solving behavior of scientists which showed that design usually consisted of look-up of abstracted plans followed by hierarchical plan-step refinement. The skeletal plan method has been implemented through two generations of problem-solving systems, the second generation involving a synthesis with the metaplanning approach of Stefik. 相似文献
18.
Izuru Miyazaki Yumi Masuoka Ayako Ohshima Naoko Takahashi Akitoshi Suzumura Shinya Moribe Hisaaki Takao Mitsutaro Umehara 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(25):2300298
Metal–organic frameworks (MOFs)/coordination polymers are promising materials for gas separation, fuel storage, catalysis, and biopharmaceuticals. However, most applied research on MOFs is limited to these functional materials thus far. This study focuses on the potential of MOFs as structural adhesives. A sintering technique is applied to a zeolitic imidazolate framework-67 (ZIF-67) gel that enables the joining of Cu substrates, resulting in a shear strength of over 30 MPa, which is comparable to that of conventional structural adhesives. Additionally, systematic experiments are performed to evaluate the effects of temperature and pressure on adhesion, indicating that the removal of excess 2-methylimidazole and the by-product (acetic acid) from the sintered material by vaporization results in a microstructure composed of large spherical ZIF-67 crystals that are densely aggregated, which is essential for achieving a high shear strength. 相似文献
19.
Larissa Stieven Montagna Thaís Larissa do Amaral Montanheiro Aline Chiodi Borges Cristiane Yumi Koga‐Ito Ana Paula Lemes Mirabel Cerqueira Rezende 《应用聚合物科学杂志》2017,134(4)
Biodegradable polymer nanocomposites are an essential alternative to minimize the generation of polymeric solid waste that shows short shelf life and difficult degradation. In this study, nanocomposites based on poly(3‐hydroxybutyrate‐co‐3‐hydroxyvalerate) (PHBV) were prepared by the incorporation of different contents, 0.25, 0.50, 0.75, and 1.00 wt % of graphite nanosheets (GNS), using a solution casting method. The investigation of the PHBV samples biodegradation was made using filamentous fungi (Penicillium funiculosum) in solid medium. Characterization of the material was performed by weight loss, differential scanning calorimetry, carbonyl index determined by Fourier transformed infrared spectroscopy, contact angle, roughness, and scanning electron microscopy. Results revealed that PHBV/GNS nanocomposites can be totally degraded in the presence of Penicillium funiculosum; however, it will be necessary high incubation period. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44234. 相似文献
20.