Quasicrystals as cluster aggregates

Quasicrystals are solids that exhibit symmetries long thought forbidden in nature. Since their discovery in a rapidly solidified Al-Mn alloy in 1984, the central issue in the field has been to understand why they form. Are they energetically stable compounds or stabilized by entropy? In recent years, major strides have been made in determining atomic structure, largely by direct imaging using advanced electron microscopy. One system is now known to be energetically stabilized, and quasicrystals are therefore firmly established as a new physical state of matter. They represent a unique packing of atomic clusters some tens of atoms in size, with substantial localized fluctuations, referred to as phasons. Understanding phasons may in future allow their unique macroscopic properties to be tailored for useful materials applications.     

Trench filling characteristics of low stress TEOS/ozone oxide deposited by PECVD and SACVD

In this paper low stress silicon oxide was deposited with tetraethylorthosilicate (TEOS, Si(OC₂H₅)₄)/ozone by plasma enhanced chemical vapor deposition (PECVD) and sub-atmospheric chemical vapor deposition (SACVD) for deep trench filling. Two kinds of PECVD oxide were fabricated: Coil antenna inductively coupled plasma (ICP) oxide and parallel plates capacitive coupled plasma (CCP) oxide. Adding ozone into the deposition process enhances the trench filling capability. Oxide filling in a deep trench (5 m wide, 52 m deep) was carried out using the SACVD process, which gave excellent conformal step coverage. However, the coil antenna ICP oxide was suitable as a sealing material. The effects of argon ion sputtering and magnetic field in the PECVD for the trench filling are discussed in this paper. Because the low temperature processes of PECVD and SACVD, the thermal residual stress was reduced and a low stress film of 85 MPa compression is available.This work is supported by a Grant-in-Aid (No. 13305010) from Japanese Ministry of Education, Culture, Sports, Science and Technology. A part of this work has been performed in Venture Business Laboratory, Tohoku University.     

Speech recognition using pulse-coupled neural networks with a radial basis function

We have developed a novel pulse-coupled neural network (PCNN) for speech recognition. One of the advantages of the PCNN is in its biologically based neural dynamic structure using feedback connections. To recall the memorized pattern, a radial basis function (RBF) is incorporated into the proposed PCNN. Simulation results show that the PCNN with a RBF can be useful for phoneme recognition. This work was presented in part at the 7th International Symposium on Artificial Life and Robotics, Oita, Japan, January 16–18, 2002     

Dependence of Superconducting Critical Temperature of A15-Type V3Ga on Composition

The composition dependence of the superconducting critical temperature T _c has been investigated for A15-type V₃Ga compounds. The T _c is determined by the specific heat and the magnetic flux transmission ratio through the sample and discussed in terms of the powder X-ray diffraction. The long-range order parameter and the lattice parameter of V₃Ga are evaluated quantitatively by the Rietveld method at each composition, which is evaluated exactly by the electron probe microanalysis (EPMA) measurements. The well-ordered homogeneous alloying structures. V _1–x Ga _x compounds are found to have nearly the same T _c as that for the stoichiometric composition between 0.23<0.25.     

Ho arrangement in the Zn6Mg3Ho icosahedral quasicrystal studied by atomic-resolution Z-contrast STEM

The atomic structure of the Zn6Mg3Ho icosahedral quasicrystal has been studied by high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) with Z-contrast (Z: atomic number). We demonstrate that in particular Z-contrast imaging is quite powerful for specifying heavy atom positions in the quasicrystalline compound, as shown by a comparison with high-resolution phase-contrast imaging. It is confirmed that the observed Z-contrast images are fairly well explained by the projected potential of only the Ho atomic arrangement, which was recently proposed by X-ray diffraction analysis; Ho occupies an even-body-center site of the 3-dimensional Penrose lattice. Consequently, the present direct structural observation strongly supports the validity of the proposed Ho site.     

Stability of SrZr0.9Yb0.1O3−α protonic conductor in atmosphere containing nitrogen oxides (NOx)

The stability of the SrZr_0.9Yb_0.1O_3– protonic conductor in an atmosphere containing nitrogen oxides (NO _x ) was investigated. When a fine powder of SrZr_0.9Yb_0.1O_3– with a specific surface area of about 50 m²/g was annealed at 440 °C in He gas containing 8% O₂ and 0.1% NO, the formation of Sr(NO₃)₂ was observed by IR measurement, ion-chromatography analysis and ICP analysis. The formation mechanism of Sr(NO₃)₂ was examined by considering the thermodynamic equilibrium. Based on the results of the thermodynamic calculation, H₂O dissolved into SrZr_0.9Yb_0.1O_3– was estimated to play an important role in the reaction for the formation of Sr(NO₃)₂ between SrZr_0.9Yb_0.1O_3– and NO _x .     

On Active Noise Control Systems With Online Acoustic Feedback Path Modeling

The presence of strong acoustic feedback degrades the convergence speed of the active noise control (ANC) filter, and in the worst case the ANC system may become unstable. A fixed feedback neutralization filter, obtained offline, can be used to neutralize the acoustic feedback. The feedback path, however, may be time varying, and we may need continual adjustments during online operation of the ANC system. This paper proposes a new method for online modeling of the acoustic feedback path in ANC systems. The proposed method uses three adaptive filters; a noise control filter, a feedback path modeling (FBPM) filter, and an adaptive noise cancelation (ADNC) filter. The objective of ADNC filter is to remove the disturbance from the desired response of FBPM filter. In comparison with the existing method, which works only for predictable noise sources, the proposed method can work, as well, with the broadband noise sources. The computer simulations are carried out for narrowband (predictable) (case I) and broadband (random) noise sources (case II). It is demonstrated that the proposed method performs better than the existing method in both cases     

Cover Picture: Assembly and Photoinduced Organization of Mono‐ and Oligopeptide Molecules Containing an Azobenzene Moiety (Adv. Funct. Mater. 9/2007)

An illustration of the phototriggered organization and dispersion of tri‐peptide‐substituted azobenzene derivatives, as reported on p. 1507 by Yoko Matsuzawa and co‐workers. The tri‐peptide units form a beta‐sheet structure through hydrogen bonding to assemble a fibrous network system. Cis–trans photoisomerization of the azobenzene moiety leads to a large polarity change of the component molecule to break and re‐form hydrogen bonds between the tri‐peptide units. Assembled systems consisting of an azobenzene moiety as the photofunctional component and valyl units as the network backbone are investigated. The molecular ordering of these assemblies is examined by spectroscopy and theoretical calculations. The number of valyl units greatly influences the molecular order in the organized systems. Only N‐(L ‐valyl‐L ‐valyl‐L ‐valyl)azobenzene‐4‐carboxamide ( 3 ) forms a complete β‐sheet structure in this artificial assembly. Upon photoirradiation, the azobenzene moieties isomerize completely, revealing the reversibility in the structural organization through the flexibility of the β‐sheet network in this system.     

A solution to SLAM problems by simultaneous estimation of kinematic parameters including sensor mounting offset with an augmented UKF

Accurate localization is required for autonomous robots to navigate in cluttered environments safely. Therefore, Extended Kalman Filter (EKF) and Unscented Kalman Filter (UKF), which incorporate probabilistic concepts as localization methods, have been researched up to now. It should be noted, however, that the errors of kinematic parameters such as wheel diameter, tread, and mounting sensor offset are not enough considered in conventional works. We propose an Augmented UKF-SLAM (AUKF-SLAM), which is an extension of the UKF-SLAM and can estimate the kinematic parameters including a sensor mounting offset together with the localization and mapping. The UKF-SLAM and the AUKF-SLAM are compared through some simulations to show that the proposed AUKF-SLAM is more accurate than the UKF-SLAM. Furthermore, localization experiments with only odometry are conducted using a real robot. The experimental results show to demonstrate that the localization using kinematic parameters estimated by the AUKF-SLAM is more accurate than that using values measured by hand in advance. Through some experimental verifications in an elevator hall, cluttered rooms, and a long distance corridor, it is confirmed that the proposed AUKF-SLAM which simultaneously estimates the effective kinematic parameters largely contributes to the total accuracy improvement of SLAM.     

Rapid erasing of wettability patterns based on TiO2-PDMS composite films

TiO₂-polydimethylsiloxane (TiO₂-PDMS) composite films are prepared using the sol–gel method from a Ti(OBu)₄–benzoylacetone solution containing PDMS. The prepared films are cured by irradiation with ultraviolet (UV) light. Structural changes in the films after UV irradiation are confirmed by UV–vis absorption experiments, which show that an absorption band characteristic of the benzoylacetonate chelate rings disappears. This finding is ascribed to structural changes associated with the dissociation of the chelate rings. The IR spectra of the thin films exhibit a broad absorption band after UV irradiation, indicating that a Ti–O–Ti network forms in the thin film. Contact angles are measured for the TiO₂-PDMS thin films, showing wettability conversion from hydrophobic to superhydrophilic states by irradiation with oxygen plasma for 1 s. This phenomenon is explained by XPS experiments which reveal that the number of carbon atoms decreases, whereas the number of oxygen atoms increases on the surface of the TiO₂-PDMS composite films. Finally, hydrophobic–superhydrophilic patterns are fabricated based on a patterned TiO₂-PDMS composite film. The film displays a rapid change to superhydrophilicity over the whole film surface upon plasma irradiation for 1 s, which means that the wettability patterns are rapidly erasable.