依托山水田园，打造门户主轴——昆明新机场高速公路沿线景观规划设计概述

通过对昆明新机场高速公路沿线现状景观作深入细致的分析，从而形成全新道路景观分区并且明确各区设计定位，依据各区定位进行全面设计，点、线、面结合，因地制宜，突出特色；依托昆明自然山水田园风光，打造云南特色景观门户主轴。     

Ti matrix syntactic foam fabricated by powder metallurgy: Particle breakage and elastic modulus

Titanium matrix syntactic foams have potential for orthopedic applications because of their good biocompatibility, corrosion resistance and ability of varying the elastic modulus. This paper studies the fabrication of Ti matrix syntactic foams embedded with ceramic microspheres (CMs) by a powder metallurgy method. The percentage of the crushed CMs during compaction was measured by the volume measurement and water absorption methods, and the elastic modulus of the Ti matrix syntactic foam was measured by compression tests. The effects of the Ti volume percentage and the compaction pressure on the percentage of crushed CMs and the elastic modulus were studied. For a given Ti volume percentage, the percentage of crushed CMs increases with increasing compaction pressure; for a given compaction pressure, the percentage of crushed CMs decreases with increasing Ti volume percentage. At a compaction pressure lower than 100 MPa, the elastic modulus increases with increasing Ti volume percentage and compaction pressure; at a compaction pressure above 100 MPa, further increases in Ti volume percentage and compaction pressure decrease the elastic modulus.     

松辽盆地长岭断陷火山岩天然气藏分布规律与控制因素

摘要：在长岭断陷火成岩天然气成藏条件以及各成藏要素时空配置关系综合分析的基础上,讨论了天然气富集规律及主控因素。研究表明,长岭断陷烃类气藏主要分布在凹陷中部低凸起带腰英台、达尔罕构造及东部斜坡带双龙构造,其中营城组爆发相凝灰岩和溢流相流纹岩为最有利的储集层。控制天然气富集的因素主要包括：①断陷层深部烃源岩的分布范围宏观上控制油气分布;②火山岩体及其有利的储集相带控制气藏的形成与分布;③深大断裂是油气形成的重要条件;④良好的盖层和侧向遮挡条件决定了纵向上油气的分布;⑤在基底断裂沟通良好的前提下,早期充注的烃类与晚期CO2形成有机-无机混源气藏;⑥大型继承性古隆起（古斜坡）、地层超覆尖灭、火山岩体形成的复合圈闭是最有利目标区。     

太阳能吸收式制冷机中弦月形通道热虹吸溶液提升管的研究

对弦月形通道热虹吸溶液提升管内传热及流动性能进行了分析与讨论，并对多种特殊设计的弦月形截面提升管在模拟实验台上进行了溶液提升效能实验。实验结果表明，弦月形通道提升管能较好地改善该类制冷机中热虹吸泵的热性能，具有起动温度低、运行温度范围大及对系统绝对压力要求不高等显著特点。介绍了不同通道面积条件下，运行温度与溶液提升量、冷剂水产量的关系，对影响提升管效能的其它因素也进行了分析及讨论。     

阳离子易染共聚酯的热性能研究

在半连续大装置上合成了含第三单体间笨二甲酸乙二脂-5-磺酸钠(SIPE),第四单体聚乙二醇(PEG)的阳离子易染共聚酯(ECDP);采用热失重分析、差示扫描量热法对ECDP的热性能进行了研究,并对ECDP切片干燥和熔融过程的特性粘数降进行了测试.结果表明:随行PEG含量的增加,ECDP的热分解温度下降,玻璃化转变温度相...     

The coupling of metallophthalocyanine with carbon nanotubes to produce a nanomaterial-based catalyst for reaction-controlled interfacial catalysis

A nanomaterial-based metallophthalocyanine catalyst (CoTAPc-MWCNTs) was prepared by covalently immobilizing cobalt tetraaminophthalocyanine (CoTAPc) on multiwalled carbon nanotubes (MWCNTs). The decomposition reaction of H₂O₂ was chosen to investigate the coupled catalytic performance. The results of electron paramagnetic resonance and online electrochemical experiments indicated that the catalytic mechanism of CoTAPc-MWCNTs is different from that of cobalt phthalocyanine molecular catalysts. The catalytic pathway of CoTAPc-MWCNTs involves the following steps: first, electron transfer from CoTAPc to H₂O₂ occurs through the coordination between the central cobalt ion and H₂O₂, reducing H₂O₂ to H₂O; second, electrons are transferred from MWCNTs to the oxidized CoTAPc, forming hole-doped MWCNTs; finally, hole-doped MWCNTs accept electrons from H₂O₂, oxidizing H₂O₂ to O₂. When using N,N-diethyl-1,4-phenylenediamine as a chromogenic substance, one obtained a quantitative estimate of holes injected in MWCNTs, corresponding to 1 hole for about 55 carbon atoms. Furthermore, CoTAPc-MWCNTs exhibit very unusual characteristics of controlled catalysis due to the special hydrophobic surface of the MWCNTs, and can be used as an interfacial catalyst for the determination of H₂O₂ concentration.     

High-power splitting of expanded graphite to produce few-layer graphene sheets

Few-layer graphene sheets were prepared by splitting expanded graphite using high-power sonication. Atomic-level calibrated scanning transmission electron microscopy was used to obtain efficient layer statistics, enabling optimization of the experimental conditions. This resulted in a two-step splitting mechanism in which the mean number of layers was first reduced to less than 20 by heating to 1100 °C and then to a few-layer region by a 5-min 10⁴ W L⁻¹ – power-density sonication. Raman spectroscopic analysis confirms the above mechanism and demonstrates that the sheets are largely free of defects and functional groups.     

剑麻纤维素微晶(壳聚糖/聚对苯乙烯磺酸钠)层层自组装及其复合材料的热性能和阻燃性能

采用层层自组装法,在剑麻纤维素微晶(SFCM)表面交替吸附壳聚糖(CH)和聚对苯乙烯磺酸钠(PSS)构筑CH/PSS阻燃涂层,采用Zeta电位、热重分析、场发射扫描电镜、垂直燃烧测试和燃烧量热等手段对复合材料的结构和性能进行表征。结果表明,CH/PSS涂层已经成功包覆在SFCM表面;随着吸附CH/PSS层数增加,复合材料的初始分解温度由302℃降低至237℃,残炭率由4.76%提高至27.34%;与纯SFCM相比,SFCM(CH/PSS)5点燃时间延长了1倍,残炭率提高到35.3%,最大热释放速率峰值(pkHRR)和热释放总量(Total HR)分别减少了87%和51.6%,说明构筑的自组装涂层明显提高了SFCM的阻燃性能。     

荞麦源降血糖糖肽结构表征及酶抑制动力学

为实现荞麦蛋白资源高值化利用,从6个菌株中筛选出植物乳杆菌和嗜热链球菌作为发酵菌株,制备α-葡萄糖苷酶抑制糖肽(α-GIG)。采用单因素实验确定优化中心点,然后做响应面试验优化发酵工艺。通过Sephadex G-25和反向高效液相色谱法(RP-HPLC)对发酵液进行分离纯化,制备α-GIG。采用β-消除反应方法确定α-GIG中糖肽键类型,红外光谱扫描法测定二级结构。采用Lineweaver-Burk作图法探究酶抑制动力学,确定α-GIG对α-葡萄糖苷酶的抑制作用类型。结果表明:在料液比1∶14.8、pH 7.5、接种量2%、发酵2.8 d条件下,发酵产物对α-葡萄糖苷酶抑制率达70.83%。发酵液经Sephadex G-25分离得到I1,I2,I3 3个组分,其中I2对α-葡萄糖苷酶抑制作用较强,IC50达1.72 mg/mL。经RP-HPLC进一步分离纯化I2,得到α-GIG,其纯度为94.17%。红外光谱扫描确定α-GIG的二级结构为:β-折叠占70.51%,α-螺旋占18.95%,β-转角占10.54%。α-GIG中糖肽键类型为O-糖肽键。酶抑制动力学研究表明,α-GIG对α-葡萄糖苷酶的抑制作用类型为混合型非竞争性抑制。α-GIG具有开发为天然α-葡萄糖苷酶抑制剂的潜力。     

动态硫化乙烯-乙酸乙烯酯共聚物/苯乙烯-丁二烯-苯乙烯嵌段共聚物复合改性沥青的性能

用乙烯-乙酸乙烯酯共聚物(EVA)和苯乙烯-丁二烯-苯乙烯嵌段共聚物(SBS)复合改性沥青,研究了EVA/SBS复合改性沥青动态硫化前后的软化点、针入度(25 ℃)、延度(5 ℃)及贮存稳定性,并用应变控制流变仪与光学显微镜分析了复合改性沥青的动态力学性能和相态结构.结果表明,动态硫化处理后,EVA/SBS复合改性沥青的延度和针入度下降,而软化点提高;随着硫黄用量的增加,EVA/SBS复合改性沥青的高温贮存稳定性提高,温度敏感性降低;随着EVA用量的增加,EVA/SBS复合改性沥青的高温贮存稳定性先提高后降低;当EVA质量分数为3%、硫黄质量分数为3%时,其对沥青的改性效果最佳;改性剂微粒与沥青的相容性和稳定性明显改善.