First-principles study of the tensile and fracture of the Al/TiN interface

Employing the density functional theory, we investigate the tensile and fracture processes of the Al/TiN(0 0 1) interface. The simulation presents directly the strain–stress relationship, the ideal tensile strength and the process of bond breaking of the system. Through the analysis of deformation, we find that the softer Al layers deform larger than the harder TiN layers during the tensile process. And fracture occurs between the interface and the sub-interface Al layers. In addition, the results show that during the tensile process, the ripple of the interfacial TiN layer decreases gradually with the increment of the strain. Charge transfer was detected from the Al to TiN layers near the interface area during the tensile process by means of charge density and density of states analyses. The charge transfer affects the fracture process. Compared to our previous study of the Al/TiN(1 1 1) interface, the Al/TiN(0 0 1) interface has smaller work of adhesion and larger tensile strength than the Al/TiN(1 1 1) interface. Our investigation shows that the fractures of the Al/TiN(0 0 1) and (1 1 1) interface systems both happen in the Al layers near the interface.     

A subunit interaction in chloroplast ATP synthase determined by genetic complementation between chloroplast and bacterial ATP synthase genes

F1F0-ATP synthases utilize protein conformational changes induced by a transmembrane proton gradient to synthesize ATP. The allosteric cooperativity of these multisubunit enzymes presumably requires numerous protein-protein interactions within the enzyme complex. To correlate known in vitro changes in subunit structure with in vivo allosteric interactions, we introduced the beta subunit of spinach chloroplast coupling factor 1 ATP into a bacterial F1 ATP synthase. A cloned atpB gene, encoding the complete chloroplast beta subunit, complemented a chromosomal deletion of the cognate uncD gene in Escherichia coli and was incorporated into a functional hybrid F1 ATP synthase. The cysteine residue at position 63 in chloroplast beta is known to be located at the interface between alpha and beta subunits and to be conformationally coupled, in vitro, to the nucleotide binding site > 40 A away. Enlarging the side chain of chloroplast coupling factor 1 beta residue 63 from Cys to Trp blocked ATP synthesis in vivo without significantly impairing ATPase activity or ADP binding in vitro. The in vivo coupling of nucleotide binding at catalytic sites to transmembrane proton movement may thus involve an interaction, via conformational changes, between the amino-terminal domains of the alpha and beta subunits.     

Relative Yield and Period of Individual Groups of Delayed Neutrons in 233U, 235U, and 239Pu Fission by Epithermal Neutrons

The relative yield of delayed neutrons and the half-life of their precursor nuclei in fissioning of ²³³U, ²³⁵U, and ²³⁹Pu by epithermal neutrons are measured on a setup which is based on a KG-2.5 electrostatic accelerator. The experimental samples are irradiated in a polyethylene cube, one face of which is irradiated by a neutron beam consisting of T(p, n)³He neutrons. A procedure is developed for averaging the group parameters of delayed neutrons from different series of measurements, taking account of their correlation. A comparative analysis of the data of this work and in ENDF/BVI in terms of the average half-life of the precursor nuclei of the delayed neutrons and using the dependence of the reactivity on the asymptotic period of the reactor is performed.It is shown that the data of this work agree, to within the uncertainty limits, with the recommended experimental data and differ substantially from the ENDF/BVI data.     

Application of MHD Effects in Electrolytes for Modeling Vortex Processes in Natural Phenomena and in Solving Engineering-Physical Problems

This paper gives an overview of the experimental results obtained by the method of MHD modeling in thin electrolyte layers and used to solve problems connected with the appearance of monotonic and vibrational instabilities. Primary consideration is given to the generation and interaction of transient vortex processes. As examples, the results of the investigations of flows in systems of two, three, and four vortices and periodic vortex structures, as well as of flows in the presence of obstacles of different permittivity modeling plants or technogenic screening devices intended to protect objects against pollution are presented. We consider the ways of using the results obtained in studying natural phenomena and in solving engineering-technical problems connected with mass and heat transfer and electrotransmission.     

An electrooptic intensity modulator with improved linearity

A highly linear electrooptic modulator has been designed, fabricated, and evaluated. The design of this modulator consists of only a simple modification to the directional coupler. Two-tone testing has demonstrated that, for an optical modulation depth of 30% per channel, the third-order intermodulation distortion is more than 30 dB lower than that of the conventional directional coupler or Mach-Zehnder modulators. This improvement was not observed to be accompanied by any increase in second harmonic distortion. Also included are results of two-tone computer simulations which predict the improvement in linearity of this device for a range of modulation depths.<>     

Circular core polarization-maintaining optical fibers withelliptical stress-induced cladding

The reproducible technology for producing high-birefringence fibers with stress-induced elliptical cladding and circular core is described. The authors have obtained fibers that have a birefringence of about (1-3) 10^-4, a mode coupling parameter of about (2-7) 10 ^-5 m^-1, and loss of less than 0.5 dB/km at 1.6 μm. The authors have found effects restricting the capability of test fibers to maintain the state of linear polarization     

Low cycle fatigue and creep behavior of recrystallized Molybdenum near room termperature

The deformation behavior of pure recrystallized molybdenum under cyclic and static loads was investigated in the temperature range between 30°C and 10O°C, for stress amplitudes between 100 MPa and 250 MPa and for static loads up to 200 MPa. The results show that in spite of the low test temperatures and stress levels the Mo material exhibits considerable plastic strains which depend sensitively on frequenez and small changes in temperature.The activation energy deduced for the static and dynamic deformation is less than 0.98 eV which indicates thermally activated processes, to be explained by a dislocation kink model as described in the literature. The low-temperature fatigue behavior appears strongly influenced by creep-fatigue interaction phenomena.     

用φ20mm离心萃取器两步法制取高纯钇

本文研究了中钇富镧稀土的氧化物溶液在环烷酸中的萃取行为，测定了镧钇组成、温度变化与分离系数的关系；在Ｐ＿（５０７）体系中研究了ｐＨ值与分配比的关系；提出用环烷酸、Ｐ＿（５０７）两种萃取剂制备高纯钇的工艺流程。用８４台φ２０ｍｍ离心萃取器进行了一个月的台架试验，结果证明两种萃取剂有很好的互补性，在满足钇的纯度要求下有较高收率。离心萃取器具有易分相、体系存留量少、液流密闭性好等优点，它更适宜于粘度大、级数多、产品纯度要求高的体系。     

Cytokines and PGE2 modulate the phagocytic function of the beta-glucan receptor in macrophages

Under serum-free conditions the beta-glucan receptor of mouse macrophages mediates phagocytosis of beta-1,3-D-glucan-coated microbeads (diameter 2 microns). IFN-gamma increases the phagocytic function of the beta-glucan receptor in a dose-dependent manner, giving the plateau level at 100 U/ml. Maximum activity appears 9 h after addition of IFN-gamma to the cells. The effect disappears within 24 h. The effect of IFN-gamma may be a result of augmented receptor synthesis since treatment with cycloheximide reduces the phagocytosis. IL-1 also increases the phagocytic function of the beta-glucan receptor giving a dose-dependent response and with the plateau level reached at 10 U/ml. Maximum activity is found 4 h after addition of IL-1 to macrophages. The effect disappears within 24 h. TNF does not alter the phagocytic function of the beta-glucan receptor, but TNF together with IL-1 prolongs the effect of IL-1. PGE2 reduces the phagocytic function of the beta-glucan receptor. Maximum reduction is achieved with 8 ng/ml. Time-course studies show the lowest phagocytic activity 9 h after addition of PGE2 to the cells.