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131.
The effect of treatment with a zirconyl nitrate aqueous solution on the structure; the hydroxyl-layer constitution; and the adsorptive, acid, and catalytic properties of dealuminated zeolite Y was studied. The zeolite was prepared by boiling NH4Y in an ethylenediaminetetraacetic acid disodium salt solution followed by ion exchange with ammonium chloride and calcination in a 100% steam flow at 750°C. X-ray diffraction, IR spectroscopy, and DTA data show the formation of an ultrastable form of zeolite Y. The incorporation of zirconium in zeolite led to an increase in the proportion of strong acid sites, thus raising the yield of cracking products during n-hexane conversion tested on platinum-containing catalyst samples. 相似文献
132.
Tkachenko Yurii G. Britun Yurchenko Djema Z. Ochkas Larisa F. Bovkun Galina A. 《Powder Metallurgy and Metal Ceramics》2004,43(1-2):99-104
The influence which the composition of powder mixtures, the treatment conditions which the mixtures are subjected to, and the conditions under which the hot-pressed composite materials B4C – (5-10 mass%) calcium-silicon are fabricated exert on the structure, nature of failure, and mechanical properties of these materials is investigated. Optimum properties are possessed by material containing 10 mass% of addition. It is shown that the structure, morphology, and dispersivity, as well as the nature of the distribution of the components that are added to the composite material (secondary phase) vary as the temperature of hot pressing changes. Maximal mechanical characteristics of the composite material (σbend = 560 MPa, K 1c = 4.7 MPa·m1/2, HV = 37 GPa) are attained at hot-pressing temperatures in the range 2000-2100°C. 相似文献
133.
A fully-dense Cu-75 vol pct ZrW2O8 metal matrix composite was fabricated by hot isostatic pressing of Cu-coated ZrW2O8 particles. A small amount of the high-pressure γ-ZrW2O8 phase was created during the cooldown and depressurization following densification; near complete transformation to γ-ZrW2O8 was achieved by subsequent cold isostatic pressing. The thermal expansion behavior of the composite between 25°C and 325°C
was altered by the cold isostatic pressing treatment, and also depended on the length of time that had passed between thermal
cycles. The measured thermal expansion coefficients within specific temperature ranges varied from −6·10−6 K−1 to far above the thermal expansion coefficient of the copper matrix. The complex temperature-dependent expansion/contraction
behavior could be justified by considering the evolution of phase transformations taking place in the ZrW2O8 phase, which were observed by in-situ synchrotron X-ray diffraction measurements. 相似文献
134.
Z. P. Shul'man B. M. Khusid I. L. Ryklina É. A. Zal'tsgendler O. R. Dornyak É. V. Ivashkevich Z. A. Shabunina 《Journal of Engineering Physics and Thermophysics》1987,53(5):1285-1291
Dynamic processes are studied in media with softly and hardly internal destroyable configurations. A method is examined for the measurement of properties of media with spatial separation of the chemical transformation stages and thermal hydrodynamic measurements.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 53, No. 5, pp. 781–789, November, 1987. 相似文献
135.
N. V. Vostokov Yu. N. Drozdov Z. F. Krasil’nik O. A. Kuznetsov A. V. Novikov V. A. Perevoshchikov M. V. Shaleev 《Russian Microelectronics》2005,34(4):203-209
The results are presented of the fabrication of strain-relaxed graded Si1 − x
Gex/Si(001) buffer layers with a maximum Ge fraction of about 0.25 that have a low density of threading dislocations (<106 cm−2) and low surface roughness. The buffer layers are grown by atmospheric-pressure hydride CVD. It is found that chemical mechanical polishing can reduce their surface roughness to a level comparable with that of the original Si(001) substrates. It is shown that the polished buffer layers can serve as substrates for MBE-grown SiGe/Si heterostructures.__________Translated from Mikroelektronika, Vol. 34, No. 4, 2005, pp. 243–250.Original Russian Text Copyright © 2005 by Vostokov, Drozdov, Krasil’nik, Kuznetsov, Novikov, Perevoshchikov, Shaleev. 相似文献
136.
An innovative method for modelling biological processes under anaerobic conditions is presented and discussed. The method is based on titrimetric and off-gas measurements. Titrimetric data is recorded as the addition rate of hydroxyl ions or protons that is required to maintain pH in a bioreactor at a constant level. An off-gas analysis arrangement measures, among other things, the transfer rate of carbon dioxide. The integration of these signals results in a continuous signal which is solely related to the biological reactions. When coupled with a mathematical model of the biological reactions, the signal allows a detailed characterisation of these reactions, which would otherwise be difficult to achieve. Two applications of the method to the enhanced biological phosphorus removal processes are presented and discussed to demonstrate the principle and effectiveness of the method. 相似文献
137.
Nicolas Clauvelin Basile Audoly Sébastien Neukirch 《Scientific Modeling and Simulation》2007,14(1):95-101
The DNA molecule is modeled as an elastic rod with bending and twisting rigidities, subjected to external tension and twist applied at one end, the other end being clamped. We study the plectonemic equilibrium of such a rod, taking into account the impenetrability constraint. Numerical solutions of this boundary value problem have previously shown that purely elastic models can reproduce the supercoiling response of the DNA molecule. Using a variational approach, we derive analytical formulae for the elastic response of the filament, and extend former numerical results. 相似文献
138.
139.
140.
We show new upper bounds for problems in the W-hierarchy of fixed-parameter complexity. A crucial ingredient of our proofs
is an extension to the W-RAM model, which permits more-powerful operations but remains equivalent to the original. We use
the extended model to give new upper bounds for Subsetsum, Maximum Irredundant Set, and various problems concerning intersection
of finite-state machines. 相似文献