EDTA modified glassy carbon electrode: Preparation and characterization

EDTA-phenoxyamide modified glassy carbon electrode (EDTA-GC) was prepared at a glassy carbon electrode by surface synthesis. In the first step, nitrophenyl was grafted to the glassy carbon (GC) surface via the electrochemical reduction of its tetraflouroborate diazonium salt. In the second step, nitrophenyl-modified electrode (NP-GC) was subjected to the cathodic potential scan to reduce the nitro to amine group. p-Aminophenyl modified glassy carbon electrode (AP-GC) was dipped into a EDTA solution containing 1-ethyl-3(3-(dimethlyamino)propyl)-carbodiimide (EDC) as an activating agent. Thus formed ((2-anilino-2-oxoethyl){2-[bis(carboxymethyl)amino]-ethyl}amino)acetic acid modified GC electrode was denoted as EDTA-GC and characterized by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), ellipsometry and X-ray photoelectron spectroscopy (XPS). Complexation of the EDTA-GC surface with Pb²⁺ ions was investigated if this electrode could be used as a metal sensor.     

Nitrate Ion Sensing Properties of Peripheral 3,4,5-Trimethoxyphenoxy and Chlorine Substituted Metallo and Metal-free Phthalocyanines

Journal of Inorganic and Organometallic Polymers and Materials - The purpose of this study is to investigate the capability of novel peripheral metal-free and metallo (2H, Fe, Co, Zn) mono nuclear...     

XRF and Raman Characterization of Antimonite

Abstract

Two type Antimonite (stibnite) ore samples were analyzed by polarized energy dispersive X-ray fluorescence (PEDXRF) spectrometry and by confocal Raman spectrometry (CRS) in this study. The samples were collected from two different localities (?zmir-Ödemi? and Bursa-Uluda? zones from Turkey) according to the sampling methods. The first locality hosted within the metamorphic basement and the second locality hosted within the felsic intrusive rock units. The goal of this paper is to compare two different stibnite samples from various regions through PEDXRF and CRS with the optical characteristic features under the ore microscope. Ore microscopy studies reveal that the ?zmir-Ödemi? stibnite is associated mainly with calcite and the Bursa-Uluda? stibnite is associated with celestite and quartz as gangue minerals. Two different colored species were observed in the stibnite of the studied samples. Ore microscopy results, CRS with the PEDXRF results show that the stibnites from the two different localities have different mineral associations, different chemical compositions, and different physical properties.     

Fabrication of calix[4]pyrrole nanofilms at the glassy carbon surface and their characterization by spectroscopic, optic and electrochemical methods

meso-Octamethylcalix[4]pyrrole (CP) and meso-heptaethylcalix[4]pyrrole-meso-4-aminophenyl (4APCP) modified glassy carbon (GC) electrodes were prepared by the electrochemical oxidation in acetonitrile solution. Binding of the calix[4]pyrroles with the glassy carbon surface was investigated that it is through the etheric linkage revealed from the reflection-absorption infrared spectroscopy (RAIRS). Surface films of CP and 4APCP were investigated by cyclic voltammetry (CV), ellipsometry, X-ray photoelectron spectroscopy, RAIRS and the contact angle measurements. The thicknesses of the films were determined by ellipsometry which confirmed that the film was multilayer and homogeneous over the surface. Ellipsometric measurements also provided that the CP and 4APCP film thicknesses were 2.49 nm and 4.58 nm for 6 CV cycle modification, corresponding to 66 μF/cm² and 106 μF/cm² capacitances obtained by CV. The wetting behavior was examined by contact angle measurements and found that the hydrophobicity of the GC-4APCP surface was higher than that of GC-CP, probably due to the aromatic meso substituent present in the former.     

Understanding the advisor–advisee relationship via scholarly data analysis

Advisor–advisee relationship is important in academic networks due to its universality and necessity. Despite the increasing desire to analyze the career of newcomers, however, the outcomes of different collaboration patterns between advisors and advisees remain unknown. The purpose of this paper is to find out the correlation between advisors’ academic characteristics and advisees’ academic performance in Computer Science. Employing both quantitative and qualitative analysis, we find that with the increase of advisors’ academic age, advisees’ performance experiences an initial growth, follows a sustaining stage, and finally ends up with a declining trend. We also discover the phenomenon that accomplished advisors can bring up skilled advisees. We explore the conclusion from two aspects: (1) Advisees mentored by advisors with high academic level have better academic performance than the rest; (2) Advisors with high academic level can raise their advisees’ h-index ranking. This work provides new insights on promoting our understanding of the relationship between advisors’ academic characteristics and advisees’ performance, as well as on advisor choosing.     

Semianalytical solution of unsteady quasi-one-dimensional cavitating nozzle flows

Unsteady quasi-one-dimensional bubbly cavitating nozzle flows are considered by employing a homogeneous bubbly liquid flow model, where the nonlinear dynamics of cavitating bubbles is described by a modified Rayleigh–Plesset equation. The model equations are uncoupled by scale separation leading to two evolution equations, one for the flow speed and the other for the bubble radius. The initial-boundary value problem of the evolution equations is then formulated and a semianalytical solution is constructed. The solution for the mixture pressure, the mixture density, and the void fraction are then explicitly related to the solution of the evolution equations. In particular, a relation independent of flow dimensionality is established between the mixture pressure, the void fraction, and the flow dilation for unsteady bubbly cavitating flows in the model considered. The steady-state compressible and incompressible limits of the solution are also discussed. The solution algorithm is first validated against the numerical solution of Preston et al. [Phys Fluids 14:300–311, 2002] for an essentially quasi-one-dimensional nozzle. Results obtained for a two-dimensional nozzle seem to be in good agreement with the mean pressure measurements at the nozzle wall for attached cavitation sheets despite the observed two-dimensional cavitation structures.     

Effect of MgF<Subscript>2</Subscript> on hot pressed hydroxylapatite and monoclinic zirconia composites

Hydroxylapatite (HA) has been widely used in biomedical applications because of its excellent biocompatibility in the human body. A total of 25 wt% monoclinic (m) zirconia–HA composites (with and without 5 wt% MgF₂) were synthesized to investigate their mechanical properties and phase stability. In HA–m-ZrO₂ composites, HA and m-ZrO₂ reacted to form CaZrO₃ when there was no F⁻ present in the composite and m-ZrO₂ partially transformed to tetragonal ZrO₂. When MgF₂ was added into the system, it improved the thermal stability of the phases, densification, hardness, and fracture toughness of the composites and it caused the m-ZrO₂ to transform completely to t-ZrO₂ by incorporating the Mg²⁺ ions present in MgF₂ in the ZrO₂. Moreover, the stability of HA was improved by incorporating the F⁻ ions from MgF₂ in place of OH⁻ ions in HA. Substitution of OH⁻ by F⁻ ions was verified by the change in HA’s hexagonal lattice parameters. A fracture toughness of 2.0 MPa√m was calculated for the composite containing MgF₂.