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701.
Cobalt(II) sites in ferrierites are already well-known from their catalytic activity, their speciation and properties, however, the knowledge are far from completeness. The following paper presents the first in literature combined QM/MM study to elucidate the structure of these sites. With this end force-field parameters describing Co interactions with ionic shells in zeolite have been tested and the cell size for various Al distributions and Co positioning has been determined. Oxide-type Buckingham parameters are shown to perform better than the carbonate ones. Moreover, Co(II) ions stability in α and β sites with various Al distribution indicates at T1T1 Al substitution in β-site as that the preferred Co(II) siting. DFT results show that the quartet spin state of Co(II) is more stable than the doublet one. 相似文献
702.
703.
The Judd–Ofelt (J–O) theory has had a remarkable success in the characterization of radiative transitions in lanthanide doped solids. The purpose of this paper is to review the applications of the J–O theory to the Pr3+ and Sm3+ ions and to use this system as an occasion to appraise its validity and to clarify its limits. In this paper we dwell at length on the absorption and luminescence measurements of two glass samples doped with Pr3+ and Sm3+, because they are basic for the J–O treatment. The results obtained for the J–O theory application to phosphate glasses doped with Pr3+ and Sm3+ present two undesirable outcomes: (1) a positive value of parameter Ω2 and (2) large uncertainties with which the three Judd–Ofelt parameters were obtained. The validity of the J–O theory for intensity analysis was also tested for Sm3+ doped in phosphate glass. The resulting Ω2 was much lower than Ω4. The first set parameters were obtained using all the levels for which fexp. was available. The second set parameter values were evaluated without the 6F1/2 and 6H15/2 levels. The Ω2,4,6 values given in these two sets clearly suggest that particular care should be taken while evaluating the Judd–Ofelt parameters as well as when these parameters are compared to other systems due to their strong dependence on the nature of levels. 相似文献
704.
The paper addresses the issue of decision-making support for small and medium-size enterprises operating within a virtual
project-driven enterprise environment. The problem considered here can be defined in terms of finding a feasible schedule
that satisfies the constraints imposed by the work-order duration, the price, and the time-constrained resource availability.
The problem belongs to the class of multi-mode case problems of project scheduling, where finding a feasible solution is NP-hard.
A heuristic method for process planning and scheduling is proposed. The method is based on a critical path approach and the
branch and bound search scheme. It has been implemented in a web-enabled interactive software package, and is illustrated
using the example of a virtual construction enterprise.
Received: February 2005 / Accepted: January 2006 相似文献
705.
Magnetic contactless detection of stress distribution and assembly defects in constructional steel element 总被引:3,自引:0,他引:3
Zbigniew H. urek 《NDT & E International》2005,38(7):589-595
The paper describes contactless stress measurement in a fit joint. The stress was investigated on the basis of changes in material's magnetisation. The level of magnetic leakage field changes due to mechanical stress is low. The stress measurements are determined by material's magnetoelastic sensitivity. This sensitivity must be ascertained. The magnetising field intensity is selected with high accuracy in the range where material's magnetoelastic sensitivity is greatest.The fit joint was executed with tolerance kept within planned limits. The elastic deformation of the ring's material at the lateral surface was measured with a strain gauge. At the last stage, the analytic and numerical calculations of the fit joint were compared to the magnetic field measurement results. The experiment has proven that it is possible to carry out contactless magnetic tests in constructional steel characterised by low magnetoelastic sensitivity. 相似文献
706.
Thickness effects of water overlayer on its explosive evaporation at heated metal surfaces 总被引:1,自引:0,他引:1
Yusheng Dou Leonid V. Zhigilei Zbigniew Postawa Nicholas Winograd Barbara J. Garrison 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2001,180(1-4):105-111
Molecular dynamics (MD) simulations have been employed to investigate the effect of the thickness of a water overlayer on the character of its ejection from a heated Au surface. The simulations are performed for five systems differing in the thickness of the water overlayer which was adsorbed on a metal substrate heated to 1000 K. For each system, an explosive evaporation occurs in the part of the water film adjacent to the metal surface and the upper part of the film is pushed off by the generated force. The average maximum temperature of the water film decreases as the film thickness increases. In contrast, the temperature achieved by the fast cooling due to the explosive evaporation shows an inverse trend. The significance of these model calculations to matrix-assisted laser desorption and ionization (MALDI) mass spectrometry is discussed. 相似文献
707.
708.
Several poly(ethylene) samples with a broad range of morphologies were studied in this work using nanoindentations. The samples had degrees of crystallinity ranging from 30 to 100% while their Young's modulus ranged from few tens of MPa up to several GPa. Experimental conditions for the correct evaluation of Young's modulus were at first identified, choosing a suitable loading rate in order to minimize viscoelastic effects on the unloading. The force curves, i.e., plots of applied load vs. penetration depth, were then analyzed following two common procedures available in the literature. None of these procedures leads to satisfying results when compared to other experimental techniques. However, it was found that a recently proposed correction factor to the Oliver and Pharr procedure allows to evaluate reliably Young's modulus of the poly(ethylene) samples exhibiting very different, fine-tuned morphologies. 相似文献
709.
Poland is one of the biggest producers of hard coal in the world and uses its domestic coal for electricity and heat generation: 42 million tons for electricity and heat production in power industry, and about 8–10 million tons used by small district-heating stations annually. Changes in demand for coal, destined for heat generation, result from the changes in the forecast structure of energy carriers to be used by local heating stations and the new emission standards coming, this year, into effect in Poland. To meet the regulations, the heat generators have to keep to environmental requirements. The cheapest solution is to burn the compliance coal. The comparison of the forecasts for coal demand and supply and the possibility of adjusting quantitative and qualitative requirements of the smaller coal consumers points out that it would be possible, when the market rules, to heal the situation between coal producers and coal consumers in Poland. 相似文献
710.
Katarzyna Zauska-Ogryzek Pawe Marzda Paula Wrblewska-uczka Magdalena Florek-uszczki Zbigniew Plewa Hubert Bojar Dorota Zolkowska Jarogniew J. uszczki 《International journal of molecular sciences》2021,22(11)
Combination therapy with two or three antiseizure medications (ASMs) is sometimes a preferred method of treatment in epilepsy patients. (1) Background: To detect the most beneficial combination among three ASMs, a screen test evaluating in vivo interactions with respect to their anticonvulsant properties, was conducted on albino Swiss mice; (2) Methods: Classification of interactions among lacosamide (LCM) and selected second-generation ASMs (lamotrigine (LTG), pregabalin (PGB), oxcarbazepine (OXC), and topiramate (TPM)) was based on the isobolographic analysis in the mouse maximal electroshock-induced seizure (MES) model. Interactions among LCM and second-generation ASMs were visualized using a polygonogram; (3) Results: In the mouse MES model, synergy was observed for the combinations of LCM + TPM + PGB and LCM + OXC + PGB. Additivity was reported for the other combinations tested i.e., LCM + LTG + TPM, LCM + LTG + PGB, LCM + LTG + OXC, and LCM + OXC + TPM in this seizure model. No adverse effects associated with triple ASM combinations, containing LCM and second-generation ASMs were observed in mice; (4) Conclusions: The combination of LCM + TPM + PGB was the most beneficial combination among the tested in this study, offering synergistic suppression of tonic-clonic seizures in mice subjected to the MES model. Both the isobolographic analysis and polygonogram method can be recommended for experimental epileptology when classifying interactions among the ASMs. 相似文献