Secondary Aluminum Production Waste — A Raw Material for the Refractory Industry

Secondary aluminum waste products, and processes that occur during heating and mineral formation on introducing fine periclase powder into the composition of waste products are studied. It is demonstrated that secondary aluminum production waste may be used as a raw material for synthesizing aluminomagnesia spinels. Translated from Novye Ogneupory, No. 6, pp. 15–18, June 2008.     

Influence of the preparation conditions on the size and morphology of nanocrystalline lanthanum orthoferrite

Nanocrystalline LaFeO₃ is prepared by the dehydration of coprecipitated lanthanum and iron(III) hydroxides. It is shown that the behavior of the samples during heating and the size distribution of LaFeO₃ nanocrystals can be considerably different depending on the scheme used for coprecipitation of lanthanum and iron hydroxides; independently of the method employed for coprecipitation of the initial compounds, sintering of the samples at 950°C leads to the formation of lanthanum orthoferrite crystals up to 100 nm in size.     

Generalized model of the formulation of the required composition of pitch-coke mixtures

Known methods of calculating the required compositions of pitch-coke mixtures in producing large graphitized electrodes are not widely used [1, 2]. This may be attributed to the multivariance of the problem, the probabilistic character of the technological operations, the lack of well-founded optimization criteria, and the sensitivity of the characteristics of the product to variation in the parameters of the initial materials and their ratios in the mixture. The only means of solving the problem is physical modeling, taking account of current computer capabilities.     

Testing a new composition of periclase spinel objects

On the basis of periclase powder (70%) and aluminomagnesia spinel (30%), synthesized from secondary aluminum production waste and caustic magnesite, test objects are produced of periclase spinel composition satisfying the requirements of GOST 1579-006-00190495-98. The articles are successfully tested in the working layer for lining tunnel furnace cars of OAO Kombinat Magnezit. __________ Translated from Novye Ogneupory, No. 8, pp. 16–17, August 2008.     

Heating furnace monolithic refractory lining

Contemporary solutions are presented for completion of a monolithic refractory lining for a heating furnace using products produced by OOO Keralit. __________ Translated from Novye Ogneupory, No. 3, pp. 80–83, March 2008.     

Granular-structure chromium-bearing refractories: Properties and uses

Results are presented on the corrosion resistance of chromium-bearing refractories of granular structure acted on by corrosive molten slags, metals, and glasses. It is possible to recommend these refractories to customers for particular conditions of use. Chromium-bearing refractories increase the working lives of furnaces considerably. __________ Translated from Novye Ogneupory, No. 1, pp. 55–61, January, 2008.     

Formation of the complex oxide NaNdTiO<Subscript>4</Subscript>

The processes of phase formation in the Na₂CO₃-TiO₂ and Na₂CO₃-TiO₂-Nd₂O₃ systems are investigated in the temperature range 600–900°C. The high-temperature solid-phase reactions underlying the process of formation of complex oxide NaNdTiO4 are studied. It is established that the synthesis of the NaNdTiO₄ compound occurs through the reaction of the intermediate product Na₈Ti₅O₁₄ with neodymium oxide in the temperature range 720–780°C. The optimum method is proposed for synthesizing NaNdTiO₄, which makes it possible to reduce the temperature of the synthesis, to avoid the formation of impurities, and to obtain the product in a finely dispersed state.     

Dynamic modes of Ti combustion in a coflow of N<Subscript>2</Subscript>-Ar mixture

Combustion of bulk density Ti powder (containing 20 wt % TiN as a diluent) in a coflow of N₂-Ar mixture was investigated upon variation in the nitrogen content of the gaseous mixture. The obtained data are believed to open up new horizons for fabrication of layered and composite ceramics by infiltration-mediated combustion.