最小通路法在通信保密装备可靠性建模中的应用

针对通信保密装备可靠性建模难度大的问题,提出了一种新的适用于复杂系统的可靠性建模方法一最小通路法。通过在系统拓扑结构图上搜索出所有能够使系统正常工作的最小通路,建立系统的可靠性模型。该方法基于广义的网络拓扑结构,因此网络的源节点和目标节点不必局限于严格的定义,可以随意指定,具有很大的灵活性。实例证明,该方法可行有效。     

AES中字节代换和列混合的硬件可逆设计

针对AES硬件实现占用大量资源的缺点,对其两个核心计算部件(字节代换和列混合)进行了硬件可逆设计.该设计采用模块复用技术,使字节代换及其逆变换模块最大限度地共享GF(2<'8>)域中的模逆运算单元,而使列混合及其逆变换模块最大限度地共享p(x)乘运算单元,以较小的硬件代价实现了字节代换模块和列混合模块的硬件可逆设计.最后在Xilinx的FPGAVirtexE xev2000e-6上进行了仿真验证,实验结果表明,与其他同类设计相比,新设计方案明显减少了硬件开销.     

Field-Induced Multiscale Polarization Configuration Transitions of Mesentropic Lead-Free Piezoceramics Achieving Giant Energy Harvesting Performance

The development of high-performance (K,Na)NbO₃ (KNN)-based lead-free piezoceramics for next-generation electronic devices is crucial for achieving environmentally sustainable society. However, despite recent improvements in piezoelectric coefficients, correlating their properties to underlying multiscale structures remains a key issue for high-performance KNN-based ceramics with complex phase boundaries. Here, this study proposes a medium-entropy strategy to design “local polymorphic distortion” in conjunction with the construction of uniformly oversize grains in the newly developed KNN solid-solution, resulting in a novel large-size hierarchical domain architecture (≈0.7 µm wide). Such a structure not only facilitates polarization rotation but also ensures a large residual polarization, which significantly improves the piezoelectricity (≈3.2 times) and obtains a giant energy harvesting performance (W_out = 2.44 mW, P_D = 35.32 µW mm⁻³, outperforming most lead-free piezoceramics). This study confirms the coexistence of multiphase through the atomic-resolution polarization features and analyzes the domain/phase transition mechanisms using in situ electric field structural characterizations, revealing that the electric field induces highly effective multiscale polarization configuration transitions based on T–O–R sequential phase transitions. This study demonstrates a new strategy for designing high-performance piezoceramics and facilitates the development of lead-free piezoceramic materials in energy harvesting applications.     

A Dilute Fluorinated Phosphate Electrolyte Enables 4.9 V-Class Potassium Ion Full Batteries

Potassium ion batteries using graphite anode and high-voltage cathodes are considered to be optimizing candidates for large-scale energy storage. However, the lack of suitable electrolytes significantly hinders the development of high-voltage potassium ion batteries. Herein, a dilute (0.8 m ) fluorinated phosphate electrolyte is proposed, which exhibits extraordinary compatibility with both graphite anode and high-voltage cathodes. The phosphate solvent, tris(2,2,2-trifluoroethyl) phosphate (TFP), has weak solvating ability, which not only allows the formation of robust anion-derived solid electrolyte interphase on graphite anode but also effectively suppresses the corrosion of Al current collector at high voltage. Meanwhile, the high oxidative stability of fluorinated TFP solvent enables stable ultrahigh-voltage (4.95 V) cycling of a potassium vanadium fluorophosphate (KVPO₄F) cathode. Using TFP-based electrolyte, the 4.9 V-class potassium ion full cell based on graphite anode and KVPO₄F cathode shows rather remarkable cycling performance with a high capacity retention of 87.2% after 200 cycles. This study provides a route to develop dilute electrolytes for high-voltage potassium ion batteries, by utilizing solvents with both weak solvating ability and high oxidative stability.     

Effect of Sintering Temperature on Magnetic and Electrical Properties of GdBaCo<Subscript>2</Subscript><Emphasis Type="Italic">O</Emphasis><Subscript>5 + <Emphasis Type="Italic">δ</Emphasis></Subscript>

In this study, we report the results of an investigation into the sintering temperature dependence of magnetic and transport properties for GdBaCo₂ O _{5 + δ} synthesized through a sol-gel method. The lowering of sintering temperature leads to the increase of oxygen content and the reduction of grain size. The increase of oxygen content results in the enhancement of magnetic interactions and the weakening of Coulomb repulsion effect, while the reduction of grain size improves the magnetoresistance effect. Metal-insulator transition accompanied with spin-state transition is observed in all samples.     

Walnut-inspired microsized porous silicon/graphene core–shell composites for high-performance lithium-ion battery anodes

Silicon is considered an exceptionally promising alternative to the most commonly used material, graphite, as an anode for next-generation lithium-ion batteries, as it has high energy density owing to its high theoretical capacity and abundant storage. Here, microsized walnut-like porous silicon/reduced graphene oxide (P-Si/rGO) core–shell composites are successfully prepared via in situ reduction followed by a dealloying process. The composites show specific capacities of more than 2,100 mAh·g^?1 at a current density of 1,000 mA·g^?1, 1,600 mAh·g^?1 at 2,000 mA·g^?1, 1,500 mAh·g^?1 at 3,000 mA·g^?1, 1,200 mAh·g^?1 at 4,000 mA·g^?1, and 950 mAh·g^?1 at 5,000 mA·g^?1, and maintain a value of 1,258 mAh·g^?1 after 300 cycles at a current density of 1,000 mA·g^?1. Their excellent rate performance and cycling stability can be attributed to the unique structural design: 1) The graphene shell dramatically improves the conductivity and stabilizes the solid–electrolyte interface layers; 2) the inner porous structure supplies sufficient space for silicon expansion; 3) the nanostructure of silicon can prevent the pulverization resulting from volume expansion stress. Notably, this in situ reduction method can be applied as a universal formula to coat graphene on almost all types of metals and alloys of various sizes, shapes, and compositions without adding any reagents to afford energy storage materials, graphene-based catalytic materials, graphene-enhanced composites, etc.

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采用变回水温度控制策略的空气源热泵空调系统研究

为了提高空气源热泵空调系统运行性能,研究了一套采用变回水温度控制策略的空气源热泵机组的制冷性能。实验研究表明,变回水温度工况可满足室内冷负荷需求。与传统采用定12℃回水温度的空气源热泵空调系统相比,COP更高,耗电量更小,是一种高效节能的空气源热泵空调系统控制方法。此外,所建立的Dymola模型从理论上验证了实验结果,在此基础上模拟实际空调系统的能耗,模拟结果表明,COP由3.99提高至4.39,提高了10%。