Electrochemical behavior of magnesium alloys AZ91D,AZCe2, and AZLa1 in chloride and sulfate solutions

The influence of Cl⁻ and SO₄²⁻ on the electrochemical behavior of AZ91D, AZCe2, and AZLa1 was studied. For all alloys, there was a current plateau in the anodic polarization curves in Na₂SO₄ solutions. In 0.5% NaCl solution, there was a small current plateau, whereas there was none in the 3.5% and 5% NaCl solutions. This indicated that SO₄²⁻ is less aggressive than Cl⁻. The range of the current plateau decreased with increasing SO₄²⁻ concentration. For all alloys, the high frequency capacitive loop in the Nyquist plots decreased with increasing concentration consistent with the decrease in corrosion resistance with increasing Cl⁻ and SO₄²⁻ concentration.     

ZrO2颗粒对Si3N4/SiO2陶瓷复合材料性能的影响

通过加入ZrO2颗粒作为增强相,利用ZrO2的相变微裂纹增韧来改善Si2M4/SiO2陶瓷材料的力学性能.当ZrO2含量为15%时,材料的抗弯强度最高,达194.8 MPa.     

因势利导 疏管结合——淄博市“美食街”地段影响流动商贩分布的因素研究

该文从实地调查淄博市“美食街”地段中的流动商贩入手,对流动商贩的经营商品和辅助工具的种类、地段中的用地性质、消费者购买路线、地段中的道路宽度四个影响流动商贩分布的因素进行了研究和分析,从而寻找和总结出流动商贩存在的必要性以及其在哪些层面影响了我们的城市,以便对流动商贩提出合理的规划布局原则和人性化的管理建议。     

基于战略的企业项目组合设计与管理

在知识经济飞速发展的今天,创新将逐渐成为整个社会创造财富的主要方式。随着企业创新数量的增加,企业必须对各种创新采用基于战略的项目组合管理方法,从企业战略的角度对备选项目进行选择,并对多个项目进行组合管理。在这一过程中,企业应当综合地分析企业的战略发展需要与企业能力,包括资金能力、技术能力等,以企业长期价值最大化为目标对企业的项目组合进行设计,并制定计划,依靠主动出击来实现企业的项目组合管理。     

Impulse response solution to the three-dimensional vector radiative transfer equation in atmosphere-ocean systems. I. Monte Carlo method

We have developed a powerful 3D Monte Carlo code, as part of the Radiance in a Dynamic Ocean (RaDyO) project, which can compute the complete effective Mueller matrix at any detector position in a completely inhomogeneous turbid medium, in particular, a coupled atmosphere-ocean system. The light source can be either passive or active. If the light source is a beam of light, the effective Mueller matrix can be viewed as the complete impulse response Green matrix for the turbid medium. The impulse response Green matrix gives us an insightful way to see how each region of a turbid medium affects every other region. The present code is validated with the multicomponent approach for a plane-parallel system and the spherical harmonic discrete ordinate method for the 3D scalar radiative transfer system. Furthermore, the impulse response relation for a box-type cloud model is studied. This 3D Monte Carlo code will be used to generate impulse response Green matrices for the atmosphere and ocean, which act as inputs to a hybrid matrix operator-Monte Carlo method. The hybrid matrix operator-Monte Carlo method will be presented in part II of this paper.     

Substrate effect on in-plane dielectric and microwave properties of Ba(Sn0.15Ti0.85)O3 thin films

The microstructure and in-plane dielectric and microwave properties of Barium tin titanate Ba(Sn_0.15Ti_0.85)O₃ (BTS) thin films grown on (1 0 0) LaAlO₃ and (1 0 0) MgO single-crystal substrates through sol–gel process were investigated. X-ray diffraction and field emission scanning electron microscopy were used to characterize crystal structure of phases and microstructure of the thin films, respectively. Microwave properties of the films were measured from 1 to 10 GHz by the interdigital capacitor configuration. The obvious differences in the dielectric and microwave properties are attributed to the stress in the films, which result from the lattice mismatch and difference in the thermal expansion coefficients between the film and substrates. This work clearly reveals the highly promising potential of BTS films for application in tunable microwave devices.     

电泳涂料的国内相关专利分析

文章论述了电泳涂料的机理及组分构成,分析了国内电泳涂料相关专利的分布及发展情况,并对今后发展的方向及趋势进行了展望。     

双层桨搅拌槽内部流场的实验研究

运用计算流体动力学（CFD）方法对双层桨搅拌槽内部流场进行数值模拟。考察了流体在不同桨叶类型、不同桨叶间距对搅拌槽内宏观流动场的影响。研究发现：流体在桨叶间距为150 mm的双层桨内部流场流动效果好。在此间距的基础上得出流体在六圆盘上斜叶桨的搅拌槽内比六圆盘直叶桨搅拌槽内混合效果好。     

盐酸洛哌丁胺的合成及成盐工艺研究

目的:研究盐酸洛哌丁胺、一种用于治疗骨质疏松症药物的关键中间体的制备方法。方法:以2,2-二苯基-γ-丁内酯为起始原料,经开环、SN2取代、酰氯化、季铵化、缩合和成盐制得。结果:当反应温度为25℃,反应时间为24 h,开环和SN2取代的产率为81%。第二步反应,当n(SOCl2):n(2,2-苯基-4-溴丁酸)=2:1、反应温度为回流时,HPLC显示2,2-苯基-4-溴丁酰氯(4)的含量为97.25%。第三步反应,当n(4):n(Na2CO3):n(二甲胺)的投料比为1.0:1.2:1.5,反应温度为0～5℃,关键中间体二甲基-(四氢-3,3-二苯基-2-呋喃叉基)溴化铵(5)的产率由文献报导的50%提高到68%。第四步洛哌丁胺游离碱的制备,较好的投料比为n(7’):n(Na2CO3):n(羟基哌啶)=1.0:1.2:1.1,收率为85%。最后一步成盐,在无水乙醇中调节pH为3左右,收率为89.6%。整个合成步骤(包括精制)的收率为34%,HPLC检测纯度达99.86%。其结构经IR、1H-NMR、13C-NMR和MS表征确认。结论:本制备方法克服了文献所报道的制备工艺的缺点,与现有技术相比,本发明后处理更简单,更适合工业化生产。     

丁基橡胶发展现状及发展建议

2003-2009年我国丁基橡胶需求量平均增长速率超过25%,自给率不到20%。2010年浙江信汇5万t装置投产,在一定程度将缓解市场供需矛盾,但市场缺口依然很大,预计到2014年,国内丁基橡胶总需求量达35万t。文章分析了我国丁基橡胶发展现状并提出了发展建议。