新型不锈钢化学抛光剂工艺研究

叙述了一般不锈钢化学抛光溶液的基本类型和在实际应用中存在的问题。着重论述MW－6不锈钢化学抛光剂的工艺研究过程、工艺条件、质量指标及检测方法，同时介绍了它与传统不锈钢化学抛光剂的比较，经验价值，表面质量控制，应用领域及应用前景。     

Study on esterification of acrylic phenolic resin by maleic anhydride and photocrosslinking properties of the alkali‐soluble product

An alkali‐soluble, photocrosslinkable polymer was synthesized by esterification of OH groups of acrylic phenolic resin with maleic anhydride. The OH groups were formed by the ring‐opening reaction of epoxy groups of epoxy phenolic resin with acrylic acid. The esterification conditions were studied. The results showed that it is better to use tetramethyl ammonium bromide as catalyst than N,N‐dimethylbenzylamine. The conversion of maleic anhydride in acetone can reach about 80% at 56°C for 4 h. The purified product was characterized by IR, DSC, and TGA. The product containing acrylate and maleic acid monoester groups, above a certain content, can be dissolved in 1% Na₂CO₃ solution. The photocrosslinkable properties of the product were investigated through selection of photoinitiator, accelarator, crosslinkable diluent monomer, etc. The acrylate and maleic acid monoester group‐containing phenolic resin exhibited very good photocrosslinking behavior, since it contains double bonds from both acrylate groups and maleic acid monoester groups. The activity of photoinitiator decreases in the order: isopropylthioanthraquinone > benzoin ethyl ether (BE) > anthraquinone (AQ) > benzophenone > Michel ketone (MK) > 2,2‐diethoxyacetophenone. The combination of some photoinitiators showed synergistic effects. The order of increasing activity for the accelerator is as follows: MK > ethyl p‐(dimethylamino)benzoate > N,N‐dimethylaniline > triethanolamine. The optimum diluent monomer is trimethylolpropane trimethacrylate. The gel content of the mixture of the resin and trimethylolpropane trimethacrylate could reach 85% using the combined photoinitiators of BE and AQ under UV exposure for 120 s. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 1607–1614, 2005     

提高φ5m×11.5m生料磨产量的措施

针对粘土资源枯竭问题,江苏巨龙水泥集团实施了以粉煤灰和硅石代替粘土的技改工程。但改造后因原料的变更,导致入房物料易磨性变差而影响了φ5m×11.5m生料磨的产质量,并进一步影响察系统的运行。因此该厂在工艺分析的基础上,采取了调整钢球级配、用高铬球替代合金刚球、改造选粉机、加强石灰石二破的管理和减少系统是否是“漏风”等技术措施,效果显著。改造后的生料磨台时产量比调整前提高了12t/h,且节电效果显著。     

Modeling the curing kinetics for a modified bismaleimide resin using isothermal DSC

The kinetics of curing for a modified bismaleimide (BMI) resin was investigated to ascertain a suitable cure model for the material. The resin system used in this study was composed of 4,4′‐bismaleimidodiphenylmethane (BMIM) and 0,0′‐diallyl bisphenol A (DABPA, DABA). The BMIM was the base monomer and the DABPA was the modified agent. A series of isothermal DSC runs provided information about the kinetics of cure in the temperature range 170–220°C. Regardless of the different temperatures, the shape of the conversion curves was similar, and this modified BMI resin system underwent an nth‐order cure reaction. Kinetic parameters of this BMI resin system, including the reaction model, activation energy, and frequency factor, were calculated. From the experimental data, it was found that the cure kinetics of this resin system can be characterized by a first‐order kinetic model. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 3338–3342, 2004     

Phase Relations in the System Al2O3–B2O3–Nd2O3

The phase relations at a temperature below "subsolidus" in the system Al₂O₃–B₂O₃–Nd₂O₃ are reported. Specimens were prepared from various compositions of Al₂O₃, B₂O₃, and Nd₂O₃ of purity 99.5%, 99.99%, and 99.9%, respectively, and fired at 1100°C. There are six binary compounds and one ternary compound in this system. The ternary compound, NdAl₃(BO₃)₄ (NAB), has a phase transition at 950°C ± 15°C. The high-temperature form of NAB has a second harmonic generation (SHG) efficiency of KH₂PO₄ (KDP) of the order of magnitude of the form which has been used as a good self-activated laser material, and the low-temperature form of NAB has no SHG efficiency.     

Surface Modification of Titania Nanoparticles Using Ultrathin Ceramic Films

Surface modification of titania nanoparticles was achieved by coating them with ultrathin alumina films using atomic layer deposition. The coating process was performed in a fluidized bed reactor at low pressure and under mechanical vibration. Films were deposited using self-limiting, sequential surface reactions of trimethylaluminum and water. The composition of alumina-coated particles was verified using infrared spectroscopy. The deposited films had an average growth rate of 0.2 nm/coating cycle and were highly uniform and conformal as demonstrated by transmission electron microscopy and X-ray spectroscopy. Deposited alumina films were amorphous as verified through X-ray diffraction and high-resolution electron microscopy. The coating process did not promote particle sintering as validated via particle size and surface area analysis.     

Engineering proteins, subcloning and hyperexpressing oxidoreductase genes

A very efficient system for subcloning and studying proteinsequences, combining previously established elements for hyperexpression,replication and screening, was used to hyperproduce and characterizeseven different products. It expedited the cloning of genes,in a multipurpose recombinant DNA construct, for all the requirementsto study and engineer proteins with a strain of Escherichiacoli. Genes encoding six heme proteins and a flavoprotein havebeen subcloned and expressed to 13–30% of the total cellprotein, greatly facilitating purification and analyses. Threeof the heme proteins and the flavoprotein incorporated prostheticgroups in E.coli, and exhibited the expected activities. Fourof the enzymes have been purified to homogeneity and two ofthese crystallized for X-ray diffraction analysis. A rapid muta-genesisprotocol, based on polymerase chain reactions, was successfullyapplied to clone derivatives of one of these enzymes, cytochromec peroxidase. Thus, this system fulfills all criteria for engineeringproteins in an efficient and concerted manner.     

Preparation and properties of T300 carbon fiber‐reinforced thermoplastic polyimide composites

In this study, a series of T300 carbon fiber‐reinforced polyimide (CFRPI) composites were prepared by laminating premolding polyimide (PI) films with unidirectional carbon fiber (CF) layers. On the basis of PI systems design, the effect of CF volume fraction, processing conditions, and PI molecular structure on the properties of CFRPI composites was studied in detail. In addition, two kinds of nano‐particles, including carbon nano‐tube (CNT) and SiO₂ were filled into the premolding PI films with different concentrations. And the effect of nano‐particles on the properties of CFRPI composites was also investigated. The surface characteristic of T300 CF was measured by X‐ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). The properties of premolding PI film and CFRPI composites were measured by dynamic mechanical analysis (DMTA), SANS testing machine, scanning electron microscopy (SEM), and so forth. These experimental results showed that the properties of CFRPI composites were mainly affected by the premolding PI film and molding condition. The change of CF volume fraction from 55% to 65% took little effect on the mechanical properties of CFRPI composites. In addition, the incorporation of nano‐particle SiO₂ could further improve the properties of CFRPI composites, but CNT hardly improved the properties of CFRPI composites. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 646–654, 2006     

IT治理与站点内容战略控制机制研究

信息可以改变竞争环境的本质与结构,作为现代信息媒介的网站则可作为一种战略工具。会计准则制定者与监管者鼓励企业在其治理机制中植入以互联网为基础的信息披露政策,但关于站点信息披露的战略控制知识还不完善。描述了IT治理因素及其与网站信息披露相关的战略控制机制,并评估这些因素与机制之间的内在关系,给出了一个基于IT治理、战略管理与基于网站的公司报告文化的概念框架。     

千年前的求爱诗：震旦之恋·扶桑之情——《关雎》与《天皇御制歌》之比较研究

从主题、内容、形式结构、语言特色、视点、表现手法、诗歌风格等方面比较<关雎>与<天皇御制歌>的异同,探寻产生其异同的原因以及由此给日本文学发展带来的影响.