降低汽油烯烃含量裂化催化剂LBO-12的研制与开发

探讨了催化裂化过程降低汽油烯烃的反应原理，研究了催化剂各组分对裂化汽油性质影响的规律性，围绕提高氢转移活性，提出制备降烯烃裂化催化剂的技术路线，并研制开发了新型LBO-12降烯烃催化剂，固定流化床反应器对中试样品的评价和工业应用结果表明，该催化剂在不损失汽油辛烷值的前提下，降低催化裂化汽油烯烃能力较强，并具有较高的水热活性稳定性和良好的抗重金属污染特性。     

Photocatalytic degradation of 2,2‐bis(4‐hydroxy‐3‐methylphenyl) propane (BPP) based on molecular recognition interaction

BACKGROUND: Endocrine disruptors in the aquatic environment and their potential adverse effects are currently issues of concern. One of these endocrine disruptors is 2,2‐bis(4‐hydroxy‐3‐methylphenyl)propane (BPP). In this work the molecular recognition interaction of BPP with β‐cyclodextrin (β‐CD) was studied using IR spectroscopy and steady state fluorescence spectroscopy, and the photocatalytic degradation behaviour of BPP based on molecular recognition interaction was investigated in a TiO₂/UV–visible (λ_max = 365 nm) system. This might provide a new method for the treatment of some organic pollutants in wastewater. RESULTS: β‐CD reacts with BPP to form a 1:1 inclusion complex, the formation constant of which is 4.94 × 10³ L mol^?1. The photodegradation rate constant of BPP after molecular recognition by β‐CD showed a 1.42‐fold increase in the TiO₂/UV–visible (λ_max = 365 nm) system. The photodegradation of BPP depended on the concentration of β‐CD, the pH value, the gaseous medium and the initial concentration of BPP. The photodegradation efficiency of BPP with molecular recognition was higher than that without molecular recognition. After 100 min of irradiation the mineralisation efficiency of BPP after molecular recognition by β‐CD reached 94.8%, whereas the mineralisation efficiency of BPP before molecular recognition by β‐CD was only 40.6%. CONCLUSION: The photocatalytic degradation of BPP after molecular recognition by β‐CD can be enhanced in the TiO₂/UV‐visible (λ_max = 365 nm) system. This enhancement is dependent on the enhancement of the adsorption of BPP, the moderate inclusion depth of BPP in the β‐CD cavity and the increase in the frontier electron density of BPP after molecular recognition. Copyright © 2008 Society of Chemical Industry     

DCA-112催化裂化抑焦剂的工业应用

针对改善催化裂化反应微环境研制开发的DCA - 112催化裂化抑焦剂 ,具有抑制生焦、改善产品分布、应用流程简单、加注方便等特点 ,经中石化长炼分公司 1Mt/a重油催化装置工业应用表明 ,在相近的工艺条件下 ,掺渣比提高 4 13个质量百分点 ,总液收提高 1 0 2个质量百分点。     

羊二庄油田二断块NgI3小层低阻油层识别

在精细地层对比的基础上 ,细分目的层段。利用 40多口井的测井数据 ,建立了纯水层以及NgI3潜力层的“RT -RXO”与“RT -AC”关系图版 ,消除了钻井液侵入对冲洗带电阻率和地层电阻率的影响 ,并以此为油层复查的标准 ,识别出 3个潜力层。经补孔证实 ,消除钻井液侵入的影响可以识别出电阻率值在 3Ω·m以上的薄油层。     

电冰箱节能潜力的研究

本文首先简要讨论了一些用于电冰箱的节能措施。然后通过ERA软件及自行编制的软件计算了使用这些措施后电冰箱的能耗情况。为了分析这些措施的可行性。继而进行了回收期和生命周期成本计算。分析结果表明，这些节方法不仅技术上能够实现，而且在经济上也具有可操作性。     

A Study of the Compatibility Between Asphalt and SBS

In this article, the compatibilities between different components of a base asphalt and styrene butadiene styrene (SBS) have been analyzed from microscopic structures. Specifically, the asphalt was separated into three components: saturates, aromatics, and resins, by Solvent Recycled Absorption Chromatography Separation Technology (SRACST). The compatibilities between these different components and the polymer were compared with the help of Fluorescence Microscope (FM) with which the existing state of the polymer SBS in these different components could be examined obviously. The modified effects indicated that aromatics could cause SBS swollen and, resins dissolved SBS better than saturates, though both the two components could partially dissolve SBS and the two mixtures presented two immiscible phase systems. In order to further investigate the compatibility between aromatics and SBS, from macroscopic properties, an additive rich in aromatics was added to the SBS/asphalt mixture, and the result was satisfactory.     

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豫西地区中、下二叠统太原组、山西组、上石盒子组及下石盒子组煤成气资源丰富，但成煤环境纵向发育与横向变化较大，规律难于把握。因此，开展煤成气源岩沉积环境研究有利于该区煤成气资源的勘探与开发及合理的利用。通过露头、钻井、地震资料及分析、测试资料的综合研究认为：本区中、下二叠统主要沉积了一套浅海碳酸盐岩，海湾-泻湖、潮坪、沼泽、障壁岛(砂质滩、坝)及三角洲相陆源碎屑岩和煤层。从总的沉积特征来看，下二叠统太原组、山西组基本上发育滨、浅海相碳酸盐岩、陆源碎屑岩和煤的混合沉积。上二叠统上、下石盒子组则以海陆交互相陆源碎屑沉积为主，三角洲及三角洲平原沼泽十分发育；沉积环境具有自下而上，自南东向北西方向由海相逐步过渡为陆相的基本特点。其煤成气源岩沉积环境以早二叠世山西期潮坪、泻湖过渡带之滨岸沼泽环境为最佳，其次为中二叠世下石盒子期三角洲平原沉积之平原沼泽环境。     

Application-specific instruction set processor for SoC implementation of modern signal processing algorithms

A novel application-specific instruction set processor (ASIP) for use in the construction of modern signal processing systems is presented. This is a flexible device that can be used in the construction of array processor systems for the real-time implementation of functions such as singular-value decomposition (SVD) and QR decomposition (QRD), as well as other important matrix computations. It uses a coordinate rotation digital computer (CORDIC) module to perform arithmetic operations and several approaches are adopted to achieve high performance including pipelining of the micro-rotations, the use of parallel instructions and a dual-bus architecture. In addition, a novel method for scale factor correction is presented which only needs to be applied once at the end of the computation. This also reduces computation time and enhances performance. Methods are described which allow this processor to be used in reduced dimension (i.e., folded) array processor structures that allow tradeoffs between hardware and performance. The net result is a flexible matrix computational processing element (PE) whose functionality can be changed under program control for use in a wider range of scenarios than previous work. Details are presented of the results of a design study, which considers the application of this decomposition PE architecture in a combined SVD/QRD system and demonstrates that a combination of high performance and efficient silicon implementation are achievable.     

扫描近场光学显微镜及其在生物微结构探测上的应用

扫描近场光学显微镜（ＳＮＯＭ）可探测生物体亚波长水平的光学特性，以接近分子水平的分辨率在生物微结构成象、探测和修饰等多方面有巨大的潜力。本文对ＳＮＯＭ的技术方法及其近期的的生物学应用进行了介绍。