Electrochemical performance of nanocrystalline Li3V2(PO4)3/carbon composite material synthesized by a novel sol–gel method

A novel sol–gel method based on V₂O₅·nH₂O hydro-gel was developed to synthesize nanocrystalline Li₃V₂(PO₄)₃/carbon composite material. In this route, V₂O₅·nH₂O hydro-gel, NH₄H₂PO₄, Li₂CO₃ and high-surface-area carbon were used as starting materials to prepare precursor, and the Li₃V₂(PO₄)₃/carbon was obtained by sintering precursor at 750 °C for 4 h in flowing argon. The sol–gel synthesis ensures homogeneity of the precursors and improved reactivity. The sample was characterized by XRD, SEM and TEM. X-ray diffraction results show Li₃V₂(PO₄)₃ sample is monoclinic structure with the space group of P2₁/n. The TEM image indicates that the Li₃V₂(PO₄)₃ particles modified by conductive carbon are about 70 nm in diameter. The Li₃V₂(PO₄)₃/carbon system showed that the discharge capacities in the first and 50th cycle are about 155.3 and 143.6 mAh/g, respectively, in the range of 3.0–4.8 V. The sol–gel method is fit for the preparation of Li₃V₂(PO₄)₃/carbon composite material which may offer some favorable properties for commercial application.     

乙环唑的合成研究

介绍了以2,4-二氯苯乙酮为原料通过催化溴化、缩合反应、与三氮唑钠反应制得原药,原药含量达到92%以上.并对合成条件进行了研究,取得了较为满意的结果.     

水文监测在未来科技城海绵城市建设示范区中的作用

评价海绵城市建设效果的主要标准是径流系数考核.水文监测与服务是海绵城市建设的重要组成部分,通过雨量、水位及流量等数据的实时采集和径流系数的计算,为海绵城市建设提供完善的专业分析和预测预报服务,为海绵城市建设方案的制定、绩效评价与考核提供科学依据.     

粉煤灰制备絮凝剂的研究

通过高温焙烧、酸浸、碱溶等制备过程,用粉煤灰制取聚硅酸铝铁絮凝剂.用分光光度计法测其浊度去除率,在焙烧温度为800℃时,粉煤灰制取的聚硅酸铝铁絮凝剂的浊度去除率最大,达到了65%左右.     

A fundamental study on the control of the HCCI combustion and emissions by fuel design concept combined with controllable EGR. Part 1. The basic characteristics of HCCI combustion

This article investigates the basic combustion parameters including start of the ignition timing, burn duration, cycle-to-cycle variation, and carbon monoxide (CO), unburned hydrocarbon (UHC), and nitric oxide (NO_x) emissions of homogeneous charge compression ignition (HCCI) engines fueled with primary reference fuels (PRFs) and their mixtures. Two primary reference fuels, n-heptane and iso-octane, and their blends with RON25, RON50, RON75, and RON90 were evaluated. The experimental results show that, in the first-stage combustion, the start of ignition retards, the maximum heat release rate decreases, and the pressure rising and the temperature rising during the first-stage combustion decrease with the increase of the research octane number (RON). Furthermore, the cumulative heat release in the first-stage combustion is strongly dependent on the concentration of n-heptane in the mixture. The start of ignition of the second-stage combustion is linear with the start of ignition of the first-stage. The combustion duration of the second-stage combustion decreases with the increase of the equivalence ration and the decrease of the octane number. The cycle-to-cycle variation improved with the decrease of the octane number.     

差压法测定低浓度BOD5水样准确度差的原因浅析

通过与标准稀释法的比对实验,分析了差压法测定低浓度BOD5样品时精密度和准确度差的原因,并予以讨论.     

广角摄像机在机器人视觉定位中的应用

为了保证广角摄像机在现代机器人视觉定位应用中的准确性,以广角摄像机像素坐标的反畸变过程为研究对象,提出一种在畸变对应表的基础上使用中心迭代法以及区域插值法确定物体实际位置的方法。通过实验证明了该方法能够测量物体的位置,其精度能够满足工业使用要求。     

基于非线性关联维特征提取的机械自动化监测系统

提取天然气压缩机故障状态下振动信号的故障特征是设计机械自动化检测系统的核心技术。提出一种基于非线性关联维特征提取的机械自动化监测系统设计方法,在故障诊断原理基础上,进行故障振动信号时间序列分析,设计故障振动信号相空间重构方法,改进了相空间重构最佳时延和嵌入维数参数计算的关键技术,通过提取关联维故障特征,在Simulink平台上设计了自动化监测系统。系统实验结果表明,该算法和系统能使各类故障状态下提取的关联维特征的标准差显著性降低,特征分布聚类能力明显提高,系统能有效检测各类故障,实现了机械设备的自动化监测,在自动化故障诊断仪表设计等领域具有较好的工程实践价值。     

改进的细菌觅食优化算法

细菌觅食优化算法是一种受大肠杆菌觅食现象启发产生的一种群体进化算法,该算法具有良好的全局优化能力,鲁棒性强,算法简单等优点,但其也存在易早熟,收敛速度慢等缺点. 根据其缺点,提出了一种改进的细菌觅食优化算法,改进后的算法收敛速度加快,在一定程度上避免了易早熟的缺点. 将原算法和改进算法应用于PID参数的在线自整定,通过matlab仿真实验证明了算法改进后的优越性.     

基于S3C2440嵌入式视频传输系统的研究与设计

如今嵌入式和视频行业发展的如火如荼,视频传输也得到了很好的发展,而很多视频传输设备都比较昂贵且移动不灵活.鉴于此,设计出了以S3C2440为核心芯片,并在此基础上结合linux环境下的GStreamer流媒体框架的视频传输系统,系统采用无线的传输方式.经过对系统测试,此系统能流畅的播放传输的视频并且移动灵活,达到预期目标,并且该系统简洁、成本低具备实际的应用前景.