Resistance of Mo-bearing stainless steels and Mo-bearing stainless-steel coating to naphthenic acid corrosion and erosion-corrosion

Naphthenic acid corrosion (NAC) and erosion-corrosion (NAEC) behavior of Mo-bearing (0-7.0 wt.%) stainless steels have been investigated in laboratory to evaluate the essential role of Mo on their NAC and NAEC resistance. The NAC and NAEC resistance of a high-velocity-oxygen-fuel (HVOF) thermal sprayed Mo-bearing stainless-steel coating was also investigated in both laboratory and an oil refinery. It was found that increasing the Mo content remarkably enhanced the NAC and NAEC resistance of stainless steels. The Mo-rich areas or phases in the steels played an importance role in resisting the NAEC. The HVOF coating showed excellent NAC and NAEC resistance in laboratory tests. The 700-day field test in an oil refinery revealed that the coating can effectively prevent the carbon-steel substrate from erosion-corrosion during long-term exposure in oil-refining environment. The corresponding NAC and NAEC mechanisms of the stainless steels and the beneficial role of Mo were discussed by taking account of inherent susceptibility of metal elements to corrosion, possible effects of Mo on surface films, and Mo-induced change in microstructure and microhardness.     

Numerical simulation of gas metal arc welding temperature field

The infrared camera is used to investigate the temperature field of gas metal arc welding.The results show that the temperature distribution of weld pool and adjacent area appears cone shape.A new heat source model combined by Gaussian distribution heat source of the arc and conical distribution heat source of the droplet is set up based on the experimental results, and with the combined boundary conditions,the temperature field of gas metal arc welding is simulated using finite element method.According to the comparison between the results of experiment and simulation in temperature field shows that the new combined heat source model is more accurate and effective than the Gauss heat source model.     

Size and pressure effects on solid transition temperatures of ZrO2

Transition temperatures between tetragonal and monoclinic polymorphs of ZrO₂ nanoparticles, thin films and nanostructured materials are calculated by considering energetic contributions of surface (interface) energy and surface stress on total Gibbs free energy. The transition temperatures drop as the size of the nanocrystals decreases, which is consistent with available results.     

焊接工艺参数对奥氏体不锈钢焊接接头腐蚀行为的影响

通过草酸腐蚀和硫酸-硫酸铁腐蚀实验，研究了奥氏体不锈钢焊接接头腐蚀与焊接热输入的关系。结果表明，随着焊接线能量的增加，其焊接接头腐蚀越严重。随着焊接线能量的增大，腐蚀率增大且有加速趋势。     

棒材无模拉伸温度场及温度梯度

采用有限元法对棒材无模拉伸温度场进行了研究,利用有限元分析软件对变形区温度场进行了数值模拟,分析了温度场及温度梯度的影响因素及影响规律,确定了变形区温度梯度分布规律。拉伸件轴向温度梯度dT/dz与其轴向坐标z之间呈线性关系,这就使得轴向各断面的平均变形抗力分布均匀,从而保证拉伸过程稳定进行。     

骨髓成骨细胞在碱热处理的磷灰石涂层钛表面的分化增殖研究

为了研究骨髓基质细胞转化的成骨细胞在碱热处理的涂层磷灰石钛表面的分化增殖，将钛片经过碱热处理后，浸泡于与类似体液的环境进行表面磷灰石涂层。应用骨髓成骨细胞作为实验工具，观察体外细胞在处理的涂层钛片上的生长，碱性磷酸酶以及降钙素的分泌。在早期，有磷灰石涂层的钛片成骨细胞黏附高于对照组；在晚期，两组之间没有明显差异；成骨细胞分化的标志——碱性磷酸酶活性和降钙素的表达，磷灰石涂层组都明显高于对照组。研究表明：碱热处理的磷灰石涂层钛能够促进成骨细胞黏附，有利于细胞向成骨分化。     

板料拉深成形过程中的变压边力技术

压边力是板料成形过程中的重要参数之一。在概述压边力在生产中的主要用途和意义的基础上，从压边力的加载模式、理论模型、实验研究变压边力技术与拉延筋、人工智能技术的交叉应用等方面，比较全面的综述了压边力技术的研究现状及存在问题，并探讨压边力技术的研究方向。     

残余奥氏体对20Mn2SiVB钢的疲劳裂纹扩展的影响

研究了残余奥氏体对20Mn2SiVB钢疲劳裂纹扩展的影响。结果表明,在贝氏体铁索体中有残余奥氏体膜的存在,残余奥氏体膜可起到提高断裂韧性的作用;在应力强度因子较高的范围内,疲劳裂纹扩展速率受钢的断裂韧性影响,断裂韧性高,裂纹扩展速率低。     

Al-Li合金回归机制的计算机模拟

基于离散格点形式的微扩散方程(Langevin方程),对Al-Li合金在回归过程中δ-Al_3Li相溶解进行了原子层面计算机模拟,分析了析出相在回归过程中原子图像和序参数的演化,进而探讨了Al-Li合金的回归机制.首次探明Al-Li合金的回归过程有序相演化序列为化学计量比δ′相→非化学计量比有序相→无序基体,并论证了亚稳区合金的回归过程更趋向于失稳区合金时效过程的逆过程;失稳区合金的回归过程更趋向于亚稳区合金时效过程的逆过程.     

用偏钛酸作原料制备纳米TiO2粉末以及颗粒相结构与光催化性能关系的研究

米用常温氨水水解TiOSO4过程中加入自制的表面活性剂制备了超细纳米TiO2粉末,用XRD,TEM和比表面仪对不同煅烧温度下的纳米TiO2粉末结构、粒径大小和比表面等进行了表征,研究了纳米TiO2粉末对甲基橙的光催化降解能力。研究表明煅烧温度在400℃～800℃时得到的纳米TiO2粉末呈锐钛矿结构,粒径约为5．5nm～9．6nm,比表面积高达189．45m^2/g;在850℃煅烧后所得的纳米TiO2粉末为锐钛矿与金红石型混晶结构;在l100℃时得到的纳米TiO2粉末为金红石型纳米TiO2粉末,同时微粒出现团聚且粒径变大。光催化实验表明：纳米TiO2粉末的光催化活性与煅烧温度密切相关,850℃煅烧1．5h所制得的混晶结构纳米TiO2粉末表现出较高的光催化活性。与国产商品纳米锐钛矿型TiO2相比,其降解甲基橙的速率约为国产商品纳米TiO2的1倍。