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11.
Junwei Fu Zhengbiao Zhang Zhenping Cheng Jian Zhu Wei Zhang Xiulin Zhu 《Polymer Bulletin》2008,61(3):287-297
A novel reversible addition-fragmentation chain transfer (RAFT) reagent bearing triphenylamine (TPA)
group, 4-diphenylamino-dithiobenzoic acid benzyl ester (DDABE), was designed and synthesized. It was used
in the RAFT polymerizations of styrene (St) and methyl acrylate (MA) to prepare end-functionalized polymers.
The results of the polymerization showed that the RAFT polymerizations could be well controlled using DDABE
as the RAFT agent. Number-average molecular weight (Mn,GPC) increased linearly
with monomer conversion, and molecular weight distributions were relatively narrow (PDI<
1.50). The results of chain-extension reaction, 1H NMR spectra and UV/Vis
spectra confirmed that most of the polymers chains were end-capped by the functional triphenylamine
(TPA) groups. The effect of feed molar ratios of St/DDABE/AIBN on polymerization was investigated. 相似文献
12.
Qingzhao Yao Yuming Zhou Yanqing Sun Xiaoyun Ye 《Journal of Inorganic and Organometallic Polymers and Materials》2008,18(4):477-484
TiO2 hybrid molecular imprinted polymer (MIP) for ethofumesate using methacrylic acid (MAA) as the functional monomer and silane
coupling agent 3-(trimethoxysilyl) propylmethacrylate (KH570) as organic–inorganic connective bridge was synthesized via photo-excitation
method. Hydrogen bond was proved to act between MAA and ethofumesate for pre- and post-polymerization binding properties as
testified by UV spectrometric method. KH570 modified TiO2 nanoparticles were prepared via sonochemical reaction, which can accelerate hydrolysis, increase collision chance for the
reactive system and improve the dispersion of the nanoparticles. Scanning electron microscope (SEM), transmission electron
microscope (TEM), binding and the adsorption kinetics experiments as well as thermogravimetric analysis (TGA) were employed
for characterization. The results indicated that the hybrid MIP revealed a larger surface area and more ordered imprinting
cavities with improved thermal stability compared to organic-only MIP. Furthermore, faster adsorption kinetics and enhancive
adsorption capacity were achieved, which made it promising in chemical sensor applications. 相似文献
13.
14.
15.
LaNiO3 was synthesized by sol-gel method in which lanthanum nitrate and nickel nitrate were used as start materials and citric acid was used as complex for gel formation.The precursor was dried and subsequently heated at elevated temperature to form the desired product.XRD analysis shows that pure LaNiO3 was synthesized.Electrical conductivity and electrochemical performance of the material were tested.The electrical conductivity decreases from 34.5that there are current peaks in the curve, which is the evidence of the electrochemical activity of LaNiO3. 相似文献
16.
17.
18.
Fanggao Chang Tao Li Yongxia Ge Zhenping Chen Zhongshi Liu Xiping Jing 《Journal of Materials Science》2007,42(17):7109-7115
DC resistivity, dielectric constant, dielectric loss and positron annihilation spectra of (Ba1−x
Ho
x
)TiO3 ceramics have been measured as a function of holmium concentration x. It has been found that the DC resistivity of (Ba1−x
Ho
x
)TiO3 is strongly dependent on the Ho content: it decreases three orders of magnitude and reaches a minimum at x = 0.4%. Doping with 0.6% holmium increases the permittivity of BaTiO3 by approximately three times (from ∼1,300 to ∼4,000), with only a slight increase in the corresponding dielectric loss. The
local electron density and defect concentration estimated using positron annihilation technique conforms well to the features
found in the dielectric and resistivity measurements. The results have been discussed in terms of a mixed compensation model. 相似文献
19.
WCDMA与GSM在空中接口上存在较大差异,WCDMA基于码分多址技术,GSM基于时分多址技术。GSM主要处理语音和低速数据,而WCDMA引入了多种速率的数据业务,根据业务的QoS进行资源控制和分配,因此在无线网络规划方法上,WCDMA与GSM存在较大差异。文章从容量规划、覆盖规划、蜂窝布局、规划流程、网络评估等方面对WCDMA与GSM的无线网络规划进行了比较和分析。 相似文献
20.
In this study, distribution and history of residual stresses in plaque-like geometries are simulated based on linear thermoviscoelastic
model, which helps to understand the mechanics and evolution of the residual stresses in the injection molding process. The
numerical calculation of direction, combined with the specified boundary conditions. Results show that the stress variation
across the thickness exhibits a high surface tensile value changing to a compressive peak value close to the surface, with
the core region experiencing a parabolic tensile peak. Residual stress distribution throughout the thickness is almost same
along the flowpath and the final residual stresses value near the gate is lower than the value near the end of flowpath. 相似文献