不同形貌Ga2O3纳米材料可控合成工艺研究

通过研究基片种类、加热温度、保温时间、冷却速度及是否加入催化剂等不同工艺参数对低维Ga2O3，纳米材料形貌的影响，确定出合成5种不同形貌β-Ga2O3纳米材料的工艺条件。场发射扫描电镜（FE-SEM）表明5种不同形貌α-Ga2O3纳米材料分别为纳米线、纳米棒、纳米带、纳米环及纳米片。X射线衍射（X-ray）分析结果表明不同形貌纳米材料均为晶格常数日=1．223nm，b=0．304nm，c=0．58nm，a=90°，β=103．7°，γ=90°的单斜晶系β-Ga2O3晶体。     

混粉电火花镜面加工技术及应用

利用自行研制的混粉电火花镜面加工装置，对混粉电火花镜面加工影响因素，加工表面性能等进行了深入研究，找出了粉末特性，工件材料，粉末浓度及放电参数等对混粉电火花镜面加工的影响规律，给出了合理的混粉电火花镜面加工工艺条件，以文中确定的加工工艺条件对铸造和压铸模具进行混粉电火花镜面加工，结果表明，该技术能提高模具制造质量，降低工人劳动强度，缩短模具制造周期。     

两性聚丙烯酰胺的合成方法及应用进展

结合国内外研究情况，从技术路线和实施方法两个角度着重阐述了制备两性聚丙烯酰胺的方法，同时简单介绍了其应用情况，并对今后的研究工作提出了一些建议。     

氟化铝生产废水处理工艺的研究

对氟化铝生产废水的处理方法进行了研究。结果表明，一级中和沉淀法和二级中和二级沉淀法均不宜用于氟化铝生产废水的结果，理想的处理方法是碱过量中和酸回调法，辅加氯化钙的石灰乳中和法也可考虑采用。     

碱式硫酸镁晶须的合成及应用

以一定浓度的MgSO4和NaOH溶液为原料,在常温下混合,在160℃,0.5 MPa的条件下用水热法反应8 h,制备出增强阻燃材料MgSO4.5Mg(OH)2.3H2O型碱式硫酸镁晶须(MOS),探讨了反应条件对产物形貌、结构及组成的影响,初步确立了制备MOS的工艺条件。经过对复合材料的拉伸性能测试得出结论,采用MOS填充改性的聚丙烯,优于市售纳米氢氧化镁和阻燃级氢氧化镁。     

CB20砖和硅莫砖在我厂回转窑上的应用

浩良河水泥厂1995年6月投产的φ3.95m×560m新型干法回转窑生产线,设计产量2000t/d,经技改后目前产量最高达到2400t/d,运行效益良好。在回转窑节能提产的过程中,窑衬也经过了不断的     

N－甲基氧化吗啉的合成研究

以吗啉为原料分二步合成Ｎ－甲基氧化吗啉，讨论了温度、催化剂、时间等因素对反应结果的影响，并提出处理未反应的双氧水的有效方法。     

气刀操作条件对聚丙烯密相脉冲气力输送行为的影响

在一管线水平长１９ｍ、垂直长１１ｍ、内径５０ｍｍ的密相脉冲气力输送实验台上进行了气刀操作条件对管道输送行为影响的实验研究．结果表明：气刀操作条件对管道输送气速、输送能力、固气比、能耗等均有明显影响．确定最佳的气刀操作条件需综合考虑发送压力、输送结构、物料物性等因素．     

Structural and transport effects of doping perfluorosulfonic acid polymers with the heteropoly acids, H3PW12O40 or H4SiW12O40

A perfluorosulfonic acid (PFSA) polymer with pendant side chain -O(CF₂)₄SO₃H was doped with the heteropoly acids (HPAs), H₃PW₁₂O₄₀ and H₄SiW₁₂O₄₀. Infrared spectroscopy revealed a strong interaction between the HPA and the PFSA ionomer. Modes associated with the peripheral bonds of the HPA were shifted to lower wave numbers when doped into PFSA membranes. Small-angle X-ray scattering (SAXS) measurements showed the presence of large crystallites of HPA in the membrane with d spacings of ca. 10 Å, close to the lattice spacing observed in bulk HPA crystals. Under wet conditions the HPA was more dispersed and constrained the size of the sulfonic acid clusters to 20 Å at a 5 wt% HPA doping level, the same as in the vacuum treated ionomer samples. Under conditions of minimum hydration the HPA decreased the E_a for the self-diffusion of water from 27 to 15 kJ mol⁻¹. The reverse trend was seen under 100% RH conditions. Proton conductivity measurements showed improved proton conductivity of the HPA doped PFSAs at a constant dew point of 80 °C for all temperatures up to 120 °C and at all relative hummidities up to 80%. The activation energy for proton conduction generally was lower than for the undoped materials at RH ≤80%. Significantly the E_a was 1/2 that of the undoped material at RHs of 40 and 60%. A practical proton conductivity of 113 mS cm⁻¹ was observed at 100 °C and 80% RH.     

EFFECT OF OPERATING TEMPERATURE AND PRESSURE ON THE TRANSITION FROM BUBBLING TO TURBULENT FLUIDIZATION

Experiments have been carried out to investigate the effects of operating temperature(50 to 500℃)andpressure(1×10~5 to 8×10~5 Pa)on the transition from bubbling to turbulent fluidization by computer analysisof the pressure fluctuation in dense phase.In order to reveal the influence of particle properties on the tran-sition process,eight kinds of particles were employed.A empirical correlaton which takes into accountthe effects of temperature and pressure is recommended for the prediction of transition velocity