石灰石在煤气化过程中的催化和固硫作用

基于CaO在煤气化中的催化和固硫作用,以及石灰石加热分解的性质,石灰石有可能作为煤气化过程中的催化剂和固硫剂。本文根据国内外对石灰石在煤燃烧和煤气化中作用的研究,从石灰石结构、Ca/C,Ca/S,可能的反应机理等几个方面进行了介绍和分析,并指出需进一步研究的内容。     

Correlation of the reactivity,the active surface area and the total surface area of thin films of pyrolytic carbon

Using thin films of pyrolytic carbon the rate of the reaction with oxygen has been measured over the temperature range 625–740°C and at pressures of oxygen from 6–100 torr. The active surface area (ASA) of the films was measured from the total concentration of strongly-bound complexes with oxygen on the surface and the relative total surface area (TSA) was measured by low-temperature adsorption of nitrogen. A maximum in reactivity and in ASA was observed for films of average thickness of about 20 nm with a TSA of about 30 m² g^?1. At the maximum the ASA and TSA were essentially equal. The results are interpreted in terms of the mechanism of formation of pyrolytic carbon in the initial stages.     

纳米SiO2粉体的制备与研究

纳米SiO2粉体的制备是以硅酸钠和盐酸为原料，添加适宜的稳定剂(非离子表面活性剂)和分散剂，在适宜的pH值和温度下，采用化学沉淀法合成。研究表明，要得到性能优良纳米的SiO2粉体，最佳工艺条件为：温度20～40℃，pH=6，反应液质量浓度P1=20g／L，P2=1．20g／L，反应时间15min。结果表明：制备的纳米SiO2粒径30～50nm，比表面积大，分散性好，质量优良，可达到产业化的生产。     

HDPE新牌号树脂的研究

根据扬子石化公司开发HDPE新牌号产品的生产经验,从分子量及分子量分布与树脂性能的关系、密度对HDPE性能的影响、HDPE的共聚改性、HDPE的共混改性、添加剂与HDPE改性等5个方面讨论了HDPE新牌号产品开发的方法。     

Photopolymerization of methyl methacrylate initiated by benzophenone/aromatic tertiary amines

Summary The photopolymerization of methyl methacrylate initiated by benzophenone-tertiary aromatic amines was studied under irradiation at 365 nm. The initiating amino radicals were investigated with combined ESR and spin-trapping method. The rate of polymerization for different amines was found in the sequence of p-hydroxymethyl-N,N-dimethylaniline>N,N-dimmethyltoluidine>N,N-dimethylaniline>p-methyl-N,N-dihydroxyethylaniline. The influence of diphenylmethanol on the polymerization reveals the incapacity of the benzophenone ketyl radical to initiate, while the amino end-group was detected in the polymers. This end-group can interact with benzophenone again, leading to initiate further polymerization to give a copolymer.     

An NMR study of the dissociation of N,N′-(2-propyloximino)-4,4′-methylenebis(phenylcarbamate) and its crosslinking of polymers containing labile hydrogens. II

Nuclear magnetic resonance spectroscopy has been used to study the dissociation and reaction of N,N′-(2-propyloximino)-4,4′-methylenebis(phenylcarbamate), as a crosslinking agent for polymers containing labile hydrogens. The crosslinking of poly(acrylic acid), polyacrylamide, and poly(vinyl alcohol) was found to result upon heating each to 150°C for 10 min with this component at 2–10 wt %.     

Design of the low power wake-up receiver for internet of things communication

A wake-up receiver with high energy efficiency and low power consumption is proposed for solving the power consuming problems of wireless nodes communication in the Internet of Things. The proposed wake-up receiver based on the wake-up mechanism can effectively schedule the network nodes communication, and use the simple envelope detection structure to achieve frequency down-conversion, which can flexibly manage energy and reduce power consumption. Based on UMC 65nm CMOS process technology, the wake-up receiver is designed and simulated. The results show that it can achieve S₁₁ of -21dBm and a sensitivity of -75dBm at a data rate of 1Mb/s, when operating at the central frequency of 780MHz and input signal adopting an on-off keying (OOK) modulation, and the power consumption is 82μW at 1.2V voltage supply.     

音频大地电磁测深在某隧道工程中的应用

音频大地电磁(AMT)在隧道的工程地质勘察是一种非常有效的方法,它具有不受高阻屏蔽、轻便、探测深度相对较大等优点,在宏观上可以查明隧道地层岩性分界、地质构造及其赋水性。以某隧道音频大地电磁勘察为例,分别对AMT的采集手段、工频干扰去噪、静态校正、反演方法等关键技术问题进行分析,并结合实际资料对该工作区的地层分布、断层及其破碎带的赋水情况等进行分析和解释,在其应用中取得了理想的效果。     

On the Survivability of Self-repairing Control System for a Hybrid Underwater Vehicle

A hybrid remotely operated underwater vehicle （HROV） capable of working to the full ocean depth has been developed. In order for the vehicle to achieve a certain survivability level, a self-repairing control system （SRCS） has been designed. It consists of two basic technologies, fault diagnosis and isolation （FDI） and reconfigurable control. For F＇DI, a model-based hierarchical fault diagnosis system is designed for the HROV. Then, control strategies which reconfigure the control system at intervals according to information from the FDI system are presented. Combining the two technologies, it can obtain the fundamental frame of SRCS for the HROV. Considering the hazardous underwater environment at the limiting depth and the hybrid operating modes, an assessment of the HROV＇ s survivability is vitally needed before it enters operational service. This paper presents a new definition of survivability for underwater vehicles and develops a simple survivability model for the SRCS. As a result of survivability assessment for the SRCS, we are able to figure out the survivability of SRCS and make further optimization about it. The methodology developed herein is also applicable to other types of underwater vehicles.     

水平切片解释方法在焦作井田构造复杂区的应用

河南焦作某矿地处焦作煤田东部,该矿东三盘区地质构造复杂,主采的2号煤层底板与L_8灰岩平均间距仅20m,与奥灰顶界面平均间距约100m,因此断层的存在极易导通奥灰水,形成较大的水患事故。故查明区内构造分布情况十分必要。本文重点介绍了用三维地震常规解释方法结合偏移及方差数据体水平切片解释方法在构造复杂区的应用情况,具有一定的推广意义。